Electronic Materials Letters

, Volume 6, Issue 3, pp 103–106

Structure and properties of borophosphate glasses

  • Nam-Jin Kim
  • Sang-Hyeok Im
  • Dong-Hwan Kim
  • Duck-Ki Yoon
  • Bong-Ki Ryu
Article
  • 116 Downloads

Abstract

Glasses in the system xB2O3−(60−x)P2O5−40Na2O (x = 0 mol. %, 10 mol. %, 20 mol. %, 30 mol. %, 40 mol. %) were prepared and characterized by measuring their density (ρ), molar volume (VM), glass transition/ softening temperature (Tg/Td), thermal expansion coefficient (α) and chemical durability (DR). All of these values were found to vary with the B2O3 content of the glasses. The results were interpreted on the basis of the structural data. The Raman and infrared spectra confirmed these structural changes.

Keywords

borophosphate glasses thermophysical properties chemical durability glass structure 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Y. S. Kim, K. H. Lee, T. H. Kim, Y. J. Jung, and B. K. Ryu, Electron. Mater. Lett. 4, 1 (2008).Google Scholar
  2. 2.
    H. Takebe, T. Harada, and M. Kuwabara, J. Non-Cryst. Solids 352, 709 (2006).CrossRefGoogle Scholar
  3. 3.
    J. F. Ducel and J. J. Videau, Mater. Lett. 13, 271 (1992).CrossRefGoogle Scholar
  4. 4.
    R. K. Brow and D. R. Tallant, J. Non-Cryst. Solids 222, 396 (1997).Google Scholar
  5. 5.
    L. Koudelka, J. Non-Cryst. Solids 695, 293 (2001).Google Scholar
  6. 6.
    A. Magistris, G. Chiodelli, and M. Duclot, Solid State Ionics 611, 9 (1983).Google Scholar
  7. 7.
    A. Marotta, A. Buri, F. Branda, P. Pernice, and A. Aronne, J. Non-Cryst. Solids 593, 95 (1987).Google Scholar
  8. 8.
    S. Elbers, W. Strojek, L. Koudelka, and H. Eckert, Solid State Nucl. Magn. Reson. 27, 65 (2005).CrossRefGoogle Scholar
  9. 9.
    N.J. Kim, Y. H. La, S. H. Im, W.-T. Han, and B. K. Ryu, Electron. Mater. Lett. 5, 4 (2009).Google Scholar
  10. 10.
    D. R. Lide (ed.), CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, (2001).Google Scholar
  11. 11.
    Y. S. Bobovich, Opt. Spektrosk. 13, 459 (1962).Google Scholar
  12. 12.
    S. Agathopoulos, D. U. Tulyaganov, J. M. G. Ventura, S. Kannan, A. Saranti, M. A. Karakassides, and J. M. F. Ferriera, J. Non-Cryst. Solids 352, 322 (2006).CrossRefGoogle Scholar
  13. 13.
    R. K. Brow, D. R. Tallant, S. T. Myers, and C. C. Phifer, J. Non-Cryst. Solids 191, 45 (1995).CrossRefGoogle Scholar
  14. 14.
    J. J. Hudgens, R. K. Brow, D. R. Tallant, and S. W. Martin, J. Non-Cryst. Solids 223, 21 (1998).CrossRefGoogle Scholar

Copyright information

© The Korean Institute of Metals and Materials and Springer 2010

Authors and Affiliations

  • Nam-Jin Kim
    • 1
  • Sang-Hyeok Im
    • 1
  • Dong-Hwan Kim
    • 1
  • Duck-Ki Yoon
    • 2
  • Bong-Ki Ryu
    • 1
  1. 1.Division of Materials Science and EngineeringPusan National UniversityBusanKorea
  2. 2.R&D CenterJeong Kwna Co., LTDYangsan, GyeongnamKorea

Personalised recommendations