Abstract
Investigations of the defect structure of a gradient-activated stoichiometric LiNbO3:Mg2+, Cr3+ crystal, in which the chromium concentration has a constant value of 0.1 at. % along the crystal growth axis, and the magnesium concentration changes smoothly from 5.5 to 2.0 al. %. The threshold concentration of Mg2+ ions (2.35 at. %) in these crystals with a concentration width of change in the center composition (Cr optical center and its nearest neighbors) of 0.09 at. % Mg2+ ions is established..
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S. D. Ivanov and E. G. Kostsov, “Thermal Detectors of Uncooled Multi-Element Infrared Imaging Arrays. I. Thermally Insulated Elements,” Avtometriya 51 (6), 79–88 (2015) [Optoelectron., Instrum. Data Process. 51 (6), 601–608 (2015)].
G. Corradi H. Sothe, J.-M. Spaeth, and K. Polgar, “Electron Spin Resonance and Electron-Nuclear Double-Resonance Investigation of a New Cr3+ Defect on an Nb Site in LiNbO3:Mg:Cr,” J. Phys. Condens. Matter. 3 (12), 1901–1908 (1991).
E. Camarillo, J. Tocho, T. Vergara, et al., “Optical Bands of Cr3+ Induced by Mg2+ Ions in LiNbO3:Cr, Mg,” Phys. Rev. B 45 (9), 4600–4604 (1992).
A. Martin, F. J. Lopez, and F. Agullo-Lopez, “Cr3+ in Pure and Mg-Doped LiNbO3: Analysis of the EPR and Optical Spectra,” J. Phys. Condens. Matter. 4 (3), 847–853 (1992).
F. Jaque, J. Garcia-Solé, E. Camarillo, et al., “Detection of Cr3+ Sites in LiNbO3:MgO, Cr3+ and LiNbO3:Cr3+,” Phys. Rev. B 47 (9), 5432–5434 (1993).
G. A. Torchia, J. A. Sanz-Garcia, F. J. López, et al., “Compositional Effect on Cr3+ Site Distribution in MgO or ZnO Codoped LiNbO3:Cr Congruent and Stoichiometric Crystals,” J. Phys. Condens. Matter. 10 (21), L341–L345 (1998).
A. Kamínska, J. E. Dmochowski, A. Suchocki, et al., “Luminescence of LiNbO3:MgO, Cr Crystals under High Pressure,” Phys. Rev. B 60 (1), 7707–7710 (1999).
F. Lhommé, P. Bourson, K. Polgarb, et al., “Study of the Luminescence Spectra of LiNbO3:Cr3+:Mg2+: Effect of the Concentration of Mg2+,” Radiation Effects and Defects in Solids 150 (1–4), 265–269 (1999).
G. Malovichko, V. Grachev, E. Kokanyan, and O. Schirmer, “Axial and Low-Symmetry Centers of Trivalent Impurities in Lithium Niobate: Chromium in Congruent and Stoichiometric Crystals,” Phys. Rev. B 59 (14), 9113–9125 (1999).
G. M. Salley, S. A. Basun, A. A. Kaplyanskii, et al., “Chromium Centers in Stoichiometric LiNbO3,” J. Luminescence 87–89, 1133–1135 (2000).
A. Kamínska, A. Suchocki, M. Grinberg, et al., “High-Pressure Spectroscopy of LiNbO3:MgO, Cr3+ Crystals,” J. Luminescence 87–89, 571–573 (2000).
T. P. J. Han, F. Jaque, V. Bermudez, and E. Dieguez, “Luminescence of the Cr3+ R-Lines in Pure and MgO Co-Doped Near Stoichiometric LiNbO3:Cr Crystals,” Chem. Phys. Lett. 369 (Is. 5–6), 519–524 (2003).
V. V. Galutskiy, E. V. Stroganova, and V. I. Vatlina, “Growth of Single Crystal with a Gradient of Concentration of Impurities by the Czochralski Method using Additional Liquid Charging,” J. Crystal Growth 311 (4), 1190–1194 (2009).
V. V. Galutskii, E. V. Stroganova, and N. A. Yakovenko, “Spectral Separation of Cr3+ Optical Centers in Stoichiometric Magnesium-Doped Lithium Niobate Crystals,” Optika Spektroskop. 110 (3), 436–442 (2011).
G. A. Torchia, O. Martinez Matosa, P. Vaveliuk, and J. O. Tochob, “Influence of the Electron-Lattice Coupling for Cr3+ Ions in Nb5+ Site into Congruent Co-Doped LiNbO3:Cr3+:ZnO Crystal,” Solid State Commun. 127 (8), 535–539 (2003).
M. N. Palatnikov, V. A. Sandler, N. V. Sidorov, et al., “Spontaneous Unipolarity and Anomalies of Dielectric and Piezoelectric Properties and Conductivity of Initially Multidomain Heavily Doped Crystals of LiNbO3:Zn,” Fiz. Tverd. Tela 57 (8), 1515–1520 (2015).
N. V. Sidorov, T. R. Volk, B. N. Mavrin, and V. T. Kalinnikov, Lithium Niobate: Defects, Photorefraction, Vibrational Spectrum, and Polaritons (Nauka, Moscow, 2003) [in Russian].
F. Lhommé, P. Bourson, G. Boulon, et al., “Comparative Analysis of the Cr3+ Centre Spectroscopic Properties in LiNbO3 Crystals from Congruent to Nearly Stoichiometric Compositions,” Eur. Phys. J. AP 20 (1), 29–40 (2002).
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Original Russian Text © E.V. Stroganova, V.V. Galutskii, K.V. Sudarikov, D.A. Rasseikin, N.A. Yakovenko, 2016, published in Avtometriya, 2016, Vol. 52, No. 2, pp. 73–80.
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Stroganova, E.V., Galutskii, V.V., Sudarikov, K.V. et al. Determination of the center composition of gradient-activated lithium niobate crystals doped with magnesium and chromium. Optoelectron.Instrument.Proc. 52, 167–173 (2016). https://doi.org/10.3103/S8756699016020096
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DOI: https://doi.org/10.3103/S8756699016020096