Abstract
The spectra and photoluminescence kinetics of Er3+ ions embedded in amorphous fluorine- and chlorine-doped silica matrices synthesized by surface-plasma chemical vapor deposition were investigated at 27–300 K. Luminescence was excited with an Ar+ laser at a wavelength of 514.5 nm and with a diode laser at a wavelength of 975 nm. Narrow and well-expressed components of Stark sublevels with a small contribution of inhomogeneous broadening intrinsic to Er3+ ions in crystalline rather than amorphous matrices were revealed and identified in photoluminescence spectra. The structure of Stark sublevels was well-resolved at low temperatures. The presence of the well-resolved Stark structure in spectra was indicative of stable anion complex formation in Er3+ environment presumably associated with halogen incorporation. This environment was formed at a stage of the low-temperature plasma-chemical synthesis and was destroyed at glass fusion.
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References
K. M. Golant, “Defects in SiO2 and Related Dielectrics: Science and Technology,” in NATO Science Series II: Mathematical and Physical Chemistry, Ed. by G. Pacchioni, L. Skuja, and D. L. Griscom (Kluwer Academic Publ., Dordrecht, 2000). Vol. 2, p. 427.
A.V. Kholodkov and K. M. Golant, “Er3+ Ions Luminescence in Non-Fused Silicate Glasses Fabricated by SPCVD,” Opt. Mater. 27, 1178 (2005).
A.V. Kholodkov and K. M. Golant, “Er3+ Ion Photoluminescence in Silicate Glasses Obtained by Plasma-Chemical Deposition in a Low-Pressure Microwave Discharge,” Tech. Phys. 50(6), 719 (2005).
A.V. Kholodkov and K. M. Golant, OFC’2004 on CDROM (Opt. Soc. Amer., Washington, D.C., 2004).
N.V. Nikonorov, A.K. Przhevuskii, and A.V. Chukharev, “Characterization of Non-Linear Upconversion Quenching in Er-Doped Glasses: Modeling and Experiment,” J. Non-Cryst. Solids. 324, 92 (2003).
S. Shen and A. Jha, “The Influence of F−-Ion Doping on the Fluorescence (4 I 13/2→4 I 15/2) Line Shape Broadening in Er3+-Doped Oxyfluoride Silicate Glasses,” Opt. Mater. 25, 321 (2004).
E. M. Dianov, K.M. Golant, V. I. Karpov, R.R. Khrapko, A. S. Kurkov, V.N. Protopopov, S. L. Semenov, and A.G. Shebuniaev, “Application of Reduced-Pressure Plasma CVD Technology to the Fabrication of Er-Doped Optical Fibers,” Opt. Mater. 3(3), 181 (1994).
D. Pavy, M. Moisan, S. Saada, P. Chollet, P. Leprince, and J. Marrec, “Fabrication of Optical Fiber Preforms by a New Surface-Plasma CVD Process,” in Proceedings of the 12th European Conference on Optical Communication (Barcelona, 1986), p. 19.
S. Tanabe, “Spectroscopic Studies on Multiphonon Processes in Erbium Doped Fluoride and Oxide Glasses,” J. Non-Cryst. Solids. 256–257, 282 (1999).
C. Li, C. Wyon, and R. Moncorge, “Spectroscopic Properties and Fluorescence Dynamics of Er3+ and Yb3+ in Y2SiO5,” IEEE J. Quantum Electron. 28(4), 1209 (1992).
L. Fornasiero, K. Petermann, E. Heumann, and G. Huber, “Spectroscopic Properties and Laser Emission of Er3+ in Scandium Silicates Near 1.5 µm,” Opt. Mater. 10, 9 (1998).
Y. Kawamoto, R. Kanno, and J. Qiu, “Upconversion Luminescence of Er3+ in Transparent SiO2-PbF2-ErF3 Glass Ceramics,” J. Mater. Sci. 33, 63 (1998).
Y. Wang and J. Ohwaki, “New Transparent Vitrocermics Codoped with Er3+ and Yb3+ for Efficient Frequency Upconversion,” Appl. Phys. Lett. 63(24), 3268 (1993).
Y.V. Orlovskii, T. T. Basiev, K.K. Pukhov, I. N. Vorobiev, A.G. Papashvili, F. Pelle, and V.V. Osiko, “Multiphonon Relaxation of mid-IR Transitions of Rare-Earth Ions in the Crystals with Fluorite Structure,” J. Lumin. 94–95, 791 (2001).
H. Sun, J. Yang, L. Zhang, J. Zhang, L. Hu, and Z. Jiang, “Composition Dependent Frequency Upconversion Luminescence in Er3+-Doped Oxychloride Germanate Glasses,” Solid State Commun. 133, 753 (2005).
F. Goutaland, P. Jander,W.S. Brocklesby, and G. Dai, “Crystallization Effects on Rare Earth Dopants in Oxyfluoride Glass Ceramics,” Opt. Mater. 22, 383 (2003).
X. Qiao, X. Fan, J. Wang, and M. Wang, “Luminescence Behavior of Er3+ Ions in Glass-Ceramics Containing CaF2 Nanocrystals,” J. Non-Cryst. Solids. 351, 357 (2005).
Y. D. Huang, M. Mortier, and F. Auzel, “Stark Level Analysis for Er3+-Doped ZBLAN Glass,” Opt. Mater. 17, 501 (2001).
S. Hubert, D. Meichenin, B.W. Zhou, and F. Auzel, “Emission Properties, Oscillator Strengths and Laser Parameters of Er3+ in LiYF4 at 2.7 µm,” J. Lumin. 50, 7 (1991).
H. Muller-Bunz, T. Schleid, “Er4F2[Si2O7] [SiO4]: the First Rare-Earth Fluoride Silicate with Two Different Silicate Anions,” Z. Anorg.Allg.Chem. B. 627, 218 (2001).
C. Russel and R. Keding, “A New Explanation for the Induction Period Observed During Nucleation of Lithium Disilicate Glass,” J. Non-Cryst. Solids. 328, 174 (2003).
V. M. Fokin, E. D. Zanotto, and J.W.P. Schmelser, “Homogeneous Nucleation Versus Glass Transition Temperature of Silicate Glasses,” J. Non-Cryst. Solids. 321, 52 (2003).
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Kholodkov, A.V., Golant, K.M. & Iskhakova, L.D. Peculiarities of Er3+ photoluminescence in halogen-doped amorphous silica. Phys. Wave Phen. 17, 155–164 (2009). https://doi.org/10.3103/S1541308X09030017
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DOI: https://doi.org/10.3103/S1541308X09030017