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Influence of Nickel Sulfate Additives to Electrolytes Subjected to Microarc Oxidation on the Structure, Composition, and Properties of Coatings Formed on Titanium

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Abstract

The influence of nickel sulfate additives to acid and basic electrolytes for microarc oxidation on the structure, composition, and properties of coatings formed on VT1-0 titanium were studied to produce poorly soluble titanium anodes. We established the possibility of incorporating nickel (nickel oxide) into the composition of coatings. X-ray diffraction analysis showed that the coatings contained nickel oxide β-NiO with a cubic lattice, TiO2 in the form of rutile, and SiO2 in the form of high-temperature β-cristobalite. The maximum thickness and nickel content in the surface layer and the minimum values of both the anodic dissolution currents and the electrical strength were obtained for the coatings formed in silicate-alkali (3 g/L KOH + 4.5 g/L Na2SiO3) electrolyte with the addition of 1 g/L of nickel sulfate NiSO4.

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References

  1. Bairachnii, B.I., Kovaleva, A.A., Voronina, E.V., and Kovalenko, Yu.I., Visn. Nats. Tekh. Univ., KhPI, 2013, no. 64, pp. 8–12.

    Google Scholar 

  2. Damaskin, B.B., Petrii, O.A., and Tsirlina, G.A., Elektrokhimiya (Electrochemistry), Moscow: Khimiya, 2006.

    Google Scholar 

  3. Gaidukova, A.M., Brodskii, V.A., and Kolesnikov, V.A., Usp. Khim. Khim. Tekhnol., 2013, vol. 27, no. 7, pp. 11–17.

    Google Scholar 

  4. West, A., Solid State Chemistry and Its Applications, New York: Wiley, 1987.

    Google Scholar 

  5. Brusentsov, Yu.A. and Minaev, A.M., Osnovy fiziki i tekhnologii oksidnykh poluprovodnikov (Physics and Technology of Oxide Semiconductors), Tambov: Tambovsk. Gos. Tekh. Univ., 2002.

    Google Scholar 

  6. Sokolovskaya, E.M., Obshchaya khimiya (General Chemistry), Moscow: Mosk. Gos. Univ., 1989.

    Google Scholar 

  7. Pak, V.N., Formus, D.V., and Shilov, S.M., Russ. J. Gen. Chem., 2013, vol. 83, no. 4, pp. 633–635.

    Article  Google Scholar 

  8. Apelfeld, A.V., Belkin, P.N., Borisov, A.M., Vasin, V.A., et al., Sovrmennye tekhnologii modifikatsii poverkhnosti materialov i naneseniya zashchitnykh pokrytii. Tom 1. Mikrodugovoe oksidirovanie (Modern Technologies for Modification of Surface of Materials and Deposition of Protective Coatings, Vol. 1: Microarc Oxidation), Moscow: Renome, 2017.

    Google Scholar 

  9. Borisov, A.M., Krit, B.L., Lyudin, V.B., Morozova, N.V., et al., Surf. Eng. Appl. Electrochem., 2016, vol. 52, no. 1, pp. 50–78.

    Article  Google Scholar 

  10. Rudnev, V.S., Tyrina, L.M., Lukiyanchuk, I.V., Yarovaya, T.P., et al., Surf. Coat. Technol., 2011, vol. 206, pp. 417–424.

    Article  Google Scholar 

  11. Rogov, A.B., Slonova, A.I., and Shayapov, V.R., Appl. Surf. Sci., 2012, 261, pp. 647–652.

    Google Scholar 

  12. Lukiyanchuk, I.V., Rudnev, V.S., Chernykh, I.V., Malyshev, I.V., et al., Surf. Coat. Technol., 2013, vol. 231, pp. 433–438.

    Article  Google Scholar 

  13. Gerasimov, M.V., Zheltukhin, R.V., Zhukov, S.V., Zalavutdinov, R.Kh., et al., Korroz.: Mater., Zashch., 2014, no. 10, pp. 41–48.

    Google Scholar 

  14. Lukiyanchuk, I.V., Rudnev, V.S., Tyrina, L.M., and Chernykh, I.V., Appl. Surf. Sci., 2014, vol. 315, pp. 481–489.

    Article  Google Scholar 

  15. Lukiyanchuk, I.V., Chernykh, I.V., Rudnev, V.S., Tyrina, L.M., et al., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 3, pp. 448–457.

    Article  Google Scholar 

  16. Gerasimov, M.V., Bogdashkina, N.V., Zalavutdinov, R.Kh., Kasatkina, I.V., et al., Korroz.: Mater., Zashch., 2017, no. 2, pp. 33–36.

    Google Scholar 

  17. Khimicheskaya entsiklopediya (Chemical Encyclopedia), Moscow: Bol’shaya Rossiiskaya Entsiklopediya, 1992, vol. 3.

  18. Apelfeld, A.V., Ashmarin, A.A., Borisov, A.M., Vinogradov, A.V., et al., Surf. Coat. Technol., 2017, vol. 328, pp. 513–517.

    Article  Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Cheistry and Electrochemistry, Russian Academy of Science, Moscow, 119071, Russia

    N. L. Bogdashkina, M. V. Gerasimov, R. Kh. Zalavutdinov, I. V. Kasatkina & A. I. Shcherbakov

  2. Moscow Aviation Institute (National Research University) (MAI), Moscow, 109383, Russia

    B. L. Krit, V. B. Lyudin, I. D. Fedichkin & A. V. Apelfeld

Authors
  1. N. L. Bogdashkina
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  2. M. V. Gerasimov
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  3. R. Kh. Zalavutdinov
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  4. I. V. Kasatkina
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  5. B. L. Krit
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  6. V. B. Lyudin
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  7. I. D. Fedichkin
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  8. A. I. Shcherbakov
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  9. A. V. Apelfeld
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Corresponding author

Correspondence to N. L. Bogdashkina.

Additional information

Original Russian Text © N.L. Bogdashkina, M.V. Gerasimov, R.Kh. Zalavutdinov, I.V. Kasatkina, B.L. Krit, V.B. Lyudin, I.D. Fedichkin, A.I. Shcherbakov, A.V. Apelfeld, 2018, published in Elektronnaya Obrabotka Materialov, 2017, No. 5, pp. 8–14.

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Bogdashkina, N.L., Gerasimov, M.V., Zalavutdinov, R.K. et al. Influence of Nickel Sulfate Additives to Electrolytes Subjected to Microarc Oxidation on the Structure, Composition, and Properties of Coatings Formed on Titanium. Surf. Engin. Appl.Electrochem. 54, 331–337 (2018). https://doi.org/10.3103/S106837551804004X

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  • DOI: https://doi.org/10.3103/S106837551804004X

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