Skip to main content
SpringerLink
Log in

Investigation of electrolytic tin-nickel alloys as anode materials for lithium-ion batteries

  • Published:
Surface Engineering and Applied Electrochemistry Aims and scope Submit manuscript

Abstract

Electrolytic deposits of tin-nickel alloys as anodes for lithium-ion batteries were investigated by potentiodynamic and galvanostatic cycling methods in solutions of ethylene carbonate, dimethyl carbonate, and LiClO4 (1 mol/L). It has been shown that the deposits of tin-nickel alloys obtained from alkaline tartrate-trilonate electrolytes in the first cycles are characterized by a high specific capacity of up to 700 mA h/g, which decreases to 500 mA h/g during the cycling. The tin-nickel alloys obtained are able to ensure high charge-discharge current densities without mechanical destruction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Advances in Lithium-Ion Batteries, Schalkwijk, W.A. and Scrosati, B., Eds., New York: Kluwer Academic, 2002.

    Google Scholar 

  2. Kamali, A.R., and Fray, D.J., Tin-based materials as advanced anode materials for lithium ion batteries. A review. Rev. Adv. Mater. Sci., 2011, vol. 27, pp. 14–24.

    Google Scholar 

  3. Amadei, I., Panero, S., Scrosati, B., Cocco, G., and Schiffini, L., The Ni3Sn4 intermetalic as novel electrode in lithium cells, J. Power Sources, 2005, vol. 143, pp. 227–230.

    Article  Google Scholar 

  4. Dong, Q.F., Wu, C.S., Jin, M.G., Huang, Z.C., Zheng, M.S., You, J.K., and Lin, Z.G., Preparàtion and performance of nickel-tin alloys used as anodes for lithium-ion battery, Solid State Ionics, 2004, vol. 167, pp. 49–54.

    Article  Google Scholar 

  5. Sakaguchi, H., Toda, T., Nagao, Y., and Esaka, T., Anode properties of lithium storage alloy electrodes prepared by gas-deposition sensors and displays: principles, materials and processing, Electrochem. Solid-State Lett., 2007, vol. 10, no. 11, pp. 146–149.

    Article  Google Scholar 

  6. Hadsoun, J., Pacero, S., and Scrosati, B., Electrodeposited Ni-Sn intermetallic electrodes for advanced lithium ion batteries, J. Power Sources, 2006, vol. 160, no. 2, pp. 1336–1341.

    Article  Google Scholar 

  7. Huang, L., Wei, H.B., Ke, F-Sh., Fan, X-Y., Li, J-T., and Sun, Sh-G, Electrodeposition and lithium stîrage performance of three-dimension porous reticular Sn-Ni alloy electrodes, Electrochim. Acta, 2009, vol. 54, pp. 2693–2698.

    Article  Google Scholar 

  8. Globa, N.I., Prisyazhnyi, V.D., Nikitenko, V.N., and Kublanovskii, V.S., Electrolytic tin-nickel alloys as anodic materials of lithium-ion batteries, Dopovidi Nats. Akad. Nauk Ukrainy, 2013, no. 4, 101–106.

    Google Scholar 

  9. Orekhova, V.V. and Andryushchenko, F. K., Poliligandnye elektrolity v gal’vanostegii (Polyligand Electrolytes in Electroplating), Khar’kov: Vysshaya shkola, 1979.

    Google Scholar 

  10. Kublanovsky, V.S. and Nikitenko, V.N. Electrochemical properties of palladium(II) trans- and cis-diglycinate complexes, Electrochim. Acta, 2011, vol. 56, pp. 2110–2115.

    Article  Google Scholar 

  11. Mukaibo, H., Sumi, T., Momma, T., and Osaka, T., Electrodeposited Sn-Ni alloy film as a high capacity anode material for lithium-ion secondary batteries, Electrochem. Solid-State Lett., 2003, vol. 6, no. 10, pp. A218–A220.

    Article  Google Scholar 

  12. Hassoun, J., Elia, G.A., Panero, S., and Scrosati, B., A high capacity template-electroplated Ni-Sn intermetallic electrode for lithium ion battery, J. Power Sources, 2011, vol. 196, pp. 7767–7770.

    Article  Google Scholar 

  13. Nishikawa, Dokko, K., Kinoshita, K., Woo, S-W., and Kanamura, K., Three-dimensionally ordered macroporous Ni-Sn anode for lithium batteries, J. Power Sources, 2009, vol. 189, pp. 726–729.

    Article  Google Scholar 

  14. Kublanovsky, V., Bersirova, O., Yapontseva, Yu., Cesiulis, H., and Podlaha-Murphy, E., Cobalt-molybdenum-phosphorus alloys: electroplating and corrosion properties, Prot. Met. Phys. Chem. Surf., 2009, vol. 45, no. 5, pp. 588–594.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Inter-Agency Department of Electrochemical Energy Systems, National Academy of Sciences of Ukraine, bulv. Vernadskogo 38a, Kiev, 03680, Ukraine

    N. I. Globa & V. D. Prisyazhnyi

  2. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Palladina 32/34, Kiev, 03680, Ukraine

    V. S. Kublanovsky & V. N. Nikitenko

Authors
  1. N. I. Globa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. D. Prisyazhnyi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. S. Kublanovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Nikitenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. I. Globa.

Additional information

Original Russian Text © N.I. Globa, V.D. Prisyazhnyi, V.S. Kublanovsky, V.N. Nikitenko, 2014, published in Elektronnaya Obrabotka Materialov, 2014, No. 3, pp. 87–91.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Globa, N.I., Prisyazhnyi, V.D., Kublanovsky, V.S. et al. Investigation of electrolytic tin-nickel alloys as anode materials for lithium-ion batteries. Surf. Engin. Appl.Electrochem. 50, 280–284 (2014). https://doi.org/10.3103/S1068375514030041

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068375514030041

Keywords

Search

Navigation