Abstract
SiO2-P2O5 films doped with CdSe have been prepared and investigated for temperature sensors applications. The films have been synthesized by sol-gel method, spin coating technique, the deposition being made on glass substrates. The sols have been prepared from tetraethylorthosilicate (TEOS) and phosphoric acid as precursors for SiO2 and P2O5, respectively, together with ethanol and water as reaction environment and a hydrolysis reagent, respectively. The films have been deposited at three rotation rates: 1000, 2000 and 3000 rpm, starting on the first day after the sol preparation moment and going on, four days consecutively, and then on the eighth day. We have analyzed the influence of the rotation rate and the time elapsed since the sol preparation till the deposition moment on the structural properties of the doped films. The films deposited at each rotation rate have been annealed at 200, 300, 350, 400, and 550°C in order to investigate the structural modifications noticed during the formation process of silicophosphate network.
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Dai, Q., Li, D., Chen, H., Kan, S., Li, H., Gao, S., Hou, Y., Liu, B., and Zou, G., Colloidal CdSe nanocrystals synthesized in noncoordinating solvents with the addition of a secondary ligand: exceptional growth kinetics, J. Phys. Chem., Ser. B., 2006, vol. 110, pp. 16508–16513.
Chan, E.M., Alivisatos, A.P., and Mathies, R.A., High-temperature microfluidic synthesis of CdSe nanocrystals in nanoliter droplets, J. Am. Chem. Soc., 2005, vol. 127, pp. 13854–13861.
Hankare, P.P., Delekar, S.D., Asabe, M.R., Chate, P.A., Bhuse, V.M., Khomane, A.S., Garadkar, K.M., and Sarwade, B.D., Synthesis of cadmium selenide thin films at low-temperature by simple chemical route and their characterization, J. Phys. Chem. Solids, 2006, vol. 67, pp. 2506–2511.
Klimov, V.I., Mikhailovsky, A.A., Xu, S., Malko, A., Hollingsworth, J.A., Leatherdale, C.A., Eisler, H.-J., and Bawendi, M.G., Optical gain and stimulated emission in nanocrystal quantum dots, Science, 2000, vol. 290, pp. 314–317.
Mattousi, H., Mauro, J.M., Goldman, E.R., Anderson, G.P., Sundar, V.C., Mikulec, F.V., and Bawendi, M.G., Self-assembly of CdSe-ZnS quantum dot bioconjugates using an engineered recombinant protein, J. Amer. Chem. Soc., 2000, vol. 122, pp. 12142–12150.
Khong Cat Cuong, Trinh Duc Thien, Pham Thu Nga, Nguyen Van Minh, and Nguyen Van Hung, Sol-gel synthesis and particle size characterization of CdSe quantum dots, VNU J. Sci., Ser. Math.-Phys., 2009, vol. 25, pp. 207–211.
Nogami, M. and Nagasaka, K., CdS-microcrystal-doped silica glass prepared by the sol-gel process, J. Non-Cryst. Solids, 1990, vol. 122, pp. 101–109.
Torruellas, W.E., Weller-Brophy, L.A., Zanoni, R., and Stegeman, G.I., Preparation and characterization of SiO2-TiO2 optical thin film by sol-gel method, Appl. Phys. Lett., 1991, vol. 58, no. 11, pp. 1128–1130.
Jyothy, P.V., Arun Kumar, K.V., Karthika, S., Rajesh, R., and Unnikrishnan, N.V., Dielectric and AC conductivity studies of CdSe nanocrystals doped sol-gel silica matrices, J. Alloys Compd., 2010, vol. 493, pp. 223–226.
Elisa, M., Sava, B.A., Volceanov, A., Monteiro, R.C.C., Alves, E., Franco, N., Costa Oliveira, F.A., Fernandes H., and Ferro, M.C., Structural and thermal characterization of SiO2-P2O5 sol-gel powders upon annealing at high temperatures, J. Non-Cryst. Solids, 2010, vol. 356, pp. 495–501.
Vasiliu, I.C., Gartner, M., Anastasescu, M., Todan, L., Predoanǎ, L., Elişa, M., Negrilǎ, C., Ungureanu, F., Logofǎtu, C., Moldovan, A., Bîrjega, R., and Zaharescu, M., Structural and optical properties of the SiO2-P2O5 films obtained by sol-gel method, Thin Solid Films, 2007, vol. 515, no. 16, pp. 6601–6605.
Sava, B.A., Elisa, M., Vasiliu, I.C., Nastase, F., Simon, S., Investigations on sol-gel process and structural characterization of SiO2-P2O5 powders, J. Non-Cryst. Solids, 2012, vol. 358, no. 21, pp. 2877–2885.
Kalampounias and Angelos, G., IR and Raman spectroscopic studies of sol-gel derived alkaline-earth silicate glasses, Bull. Mater. Sci., 2011, vol. 34, no. 2, pp. 299–303.
Aguiar, H., Serra, J., González, P., and León, B., Structural study of sol-gel silicate glasses by IR and Raman spectroscopies, J. Non-Cryst. Solids, 2009, vol. 355, pp. 475–480.
Battisha, Inas and El Nahrawy, Amany, Physical properties of nano-composite silica-phosphate thin film prepared by sol gel technique, New J. Glass Ceramics, 2012, vol. 2, pp. 17–22.
Wageh, S., Eid, A.S., El-Rabaie, S., and Higazy, A.A., CdSe nanocrystals in novel phosphate glass matrix, Phys., Ser. E, 2008, vol. 40, no. 10, pp. 3049–3054.
Moreau, Florian, Durán, Alicia, and Munoz, Francisco, Structure and properties of high Li2O-containing aluminophosphate glasses, J. Europ. Ceramic Soc., 2009, vol. 29, pp. 1895–1902.
Massiot, Ph., Centeno, M.A., Carrizossa, I., and Odriozola, J.A., Thermal evolution of phosphosilicate solids (SIPO), J. Non-Cryst. Solids, 2001, vol. 292, pp. 158–166.
D’Apuzzo, M., Aronne, A., Esposito, S., and Pernice, P., Sol-gel synthesis of humidity-sensitive P2O5-SiO2 amorphous films, J. Sol-Gel Sci. Techn., 2000, vol. 17, pp. 247–254.
Gonzalez, P., Serra, J., Liste, S., Chiussi, S., Leon, B., and Perez-Amor, M., Raman spectroscopic study of bioactive silica based glasses, J. Non-Cryst. Solids, 2003, vol. 320, pp. 92–99.
Li Yahua, Ashton Brian, and Jackson Stuart, D., Raman oscillation on a new vibrational mode setup in phosphosilicate binary glass systems, Opt. Express, 2005, vol. 13, no. 4, pp. 1172–1177.
Tanaka Akinori, Onari Seinosuke, and Arai Toshihiro, Raman scattering from CdSe microcrystals embedded in a germanate glass matrix, Phys. Rev., Ser. B, 1992, vol. 45, no. 12, pp. 6587–6592.
Sutan Kissinger, N.J., Jayachandran, M., Perumal, K., and Sanjeeviraja, C., Structural and optical properties of electron beam evaporated CdSe thin films, Bull. Mater. Sci., 2007, vol. 30, no. 6, pp. 547–551.
Kandasamy, K., Singh, H.B., and Kulshreshtha, S.K., Synthesis and characterization of CdS and CdSe nanoparticles prepared from novel intramolecularly stabilized single-source precursors, J. Chem. Sci., 2009, vol. 121, no. 3, pp. 293–296.
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Feraru, I., Vasiliu, I.C., Iordanescu, R. et al. Structural characterization of CdSe-doped Sol-Gel silicophosphate films. Surf. Engin. Appl.Electrochem. 49, 493–499 (2013). https://doi.org/10.3103/S1068375513060069
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DOI: https://doi.org/10.3103/S1068375513060069