Abstract
Test results of the dispersive, rheological, and surface active characteristics of aqueous emulsions of the oxyethylated stearic acid derivatives (Stearox-6) and aqueous binary compositions modified by PEG–Stearox-6 are presented. Both synergism and antagonism of the dispersion effect of components being incorporated into the aqueous binary compositions (ABC) during the process of abrasive machining of steel 45 are established. The value of synergism regarding the dispersion action of ABC components is defined by the possibility to form intermolecular complexes between the molecules of amine-based oligomers of different molecular weight (MW) and Stearox-6, and antagonism is determined by their competitive adsorption at the as-formed surface of steel.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Smazochno-okhlazhdayushchie tekhnologicheskie sredstva dlya obrabotki metallov rezaniem: Spravochnik (Lubrication-Cooling Technological Means for Metal Processing by Cutting: A Handbook), Entelis, S.G. and Berliner, E.M., Eds., Moscow: Mashinostroenie, 1995.
Logvinenko, P.N., Boyko, V.V., and Riabov, S.V., Preparation of amine-containing oligomers by modification of polyethylene glycols and the properties of their aqueous solutions, Materialy IX mezhdunarodnoi konferentsii po khimii i fiziko-khimii oligomerov “Oligomery–2005,” 13–16 sentyabrya 2005 g., Tezisy dokladov (Proc. IX Int. Conf. On chemistry and Physical-Chemistry of Oligomers “Oligomers–2005,” September 13–16, 2005, Abstracts of Papers), Odessa, 2005, p. 161.
Gorokhovskii, G.A., Poverkhnostnoe dispergirovanie dinamicheski kontaktiruyushchikh polimerov i metallov (Surface Dispersion of Dynamically Contacting Polymers and Metals) Kiev: Naukova Dumka, 1972.
Logvinenko, P.N., Ryabov, S.V., Shevchenko, V.V., and Dmitrieva, T.V., Water-based polymer-oligomer dispersers for abrasive machining of metals, J. Frict. Wear, 1999, vol. 20, no. 4, pp. 71–76.
Fainerman, A.E., Lipatov, Yu.S., Kulik, L.N., and Vologina, L.I., Simple method of determination of surface tension and edge angles of liquid moistening, Kolloidn. Zh., 1970, vol. 32, no. 4, pp. 620–623.
Malinovskii, G.T., Maslyanye smazochno-okhlazhdayushchie zhidkosti dlya obrabotki metallov rezaniem (Oil Lubrication-Cooling Liquids for Metal Processing by Cutting), Moscow: Khimiya, 1993.
Young, T., An essay on the cohesion of fluids, Philos. Trans. R. Soc. London, 1805, vol. 95, pp. 65–87.
Rebinder, P.A. and Shchukin, E.V., Poverkhnostnye yavleniya v dispersnykh sistemakh (Surface Phenomena in Dispersed Systems), Rebinder, P.A., Ed., Moscow: Nauka, 1989.
Artemov, A.V., Vainshtein, E.F., Seleznev, V.A., et al., Effect of polymer chain length on the catalytic activity of cobalt ions in complexes with polyethylene glycol, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1984, vol. 27, no. 1, pp. 64–68.
Joppien, G.R., Charakterisierung von Adsorptionsschichten linearer Polyester und Polyäther und ihrer gegenseitigen Wechselwirkung an der Oberfläche von wasserfreiem, pyrogenem TiO2, Angew. Makromol. Chem., 1978, vol. 70, pp. 199–204.
Logvinenko, P.N., Bryuzgina, N.A., Dmitrieva, T.V., Shrubovich, V.A., Chevchenko, V.V., Fainerman, A.E., and Protasova, N.V., Dispersing and lubricating properties of aqueous solutions of bianker oligomeric surfactants, Probl. Tertya Znoshuv., 1989, no. 37, pp. 71–78.
Logvinenko, P.N., Riabov, S.V., Karsim, L.O., and Glieva, G.E., Dispersion media based on water-soluble binary compositions of PEG-nonionic surface-active substances for abrasive metalworking, J. Frict. Wear, 2015, vol. 36, no. 2, pp. 144–148.
Bekturov, E.A. and Bakauova, Z.Kh., Sinteticheskie vodorastvorimye polimery v rastvorakh (Synthetic Water-Soluble Polymers in Solutions), Alma-Ata: Nauka, 1981.
Deryagin, B.V. and Churaev, N.V., Smachivayushchie plenki (Wetting Films), Moscow: Nauka, 1984.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by E. Grishina
About this article
Cite this article
Logvinenko, P.N., Dmitrieva, T.V., Boyko, V.V. et al. Dispersion Media Based on Aqueous Binary Compositions Modified by PEG-Stearox-6 for Abrasive Metalworking. J. Frict. Wear 39, 512–516 (2018). https://doi.org/10.3103/S1068366618060077
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068366618060077