Skip to main content
Log in

Kinetic model of mutual effect of the components on the viscosity of binary mixtures

  • Published:
Journal of Friction and Wear Aims and scope Submit manuscript

Abstract

A kinetic model describing the temperature dependence of the viscous flow of multicomponent liquids over the whole range of compositions is suggested. It takes into account the mutual influence of component molecules—either increasing or decreasing the activation energy of viscous jump of each other, which formally is equivalent to catalysis. The quantitative possibilities of the model are shown using liquid binary systems characterized by strong intermolecular interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gatchek, E., Vyazkost’ zhidkostei (Viscosity of Liquids), M.-L.: Obshchestvennoe nauch.-tekhn. izd., 1935.

    Google Scholar 

  2. Landau, L.D. and Lifshits, E.M., Gidrodinamika (Hydrodynamics), M.: Nauka, 1988.

    Google Scholar 

  3. Bulgarevich, S.B., Kuzharov, A.S., Kuzharov, A.A., and Shapkina, G.P., Molecular Mechanisms of Self-Organization in Friction. Part III. Hypotetical Mechanisms of Decreasing Viscosity of Liquid Structured in a Hydrodynamic Gap, Tren. Iznos, 2001, vol. 22, no. 3, pp. 289–294.

    Google Scholar 

  4. Daniels, F. and Olberti, R., Fizicheskaya khimiya (Physical Chemistry), M.: Mir, 1978, pp. 340–342.

    Google Scholar 

  5. Melvin-Hughes, E.A., Fizicheskaya khimiya (Physical Chemistry), M.: Izd. inostr. lit., 1962.

    Google Scholar 

  6. Mooney, D.A., Muller-Plathe, F., and Kremer, K. Simulation Studies for Liquid Phenol: Properties Evaluated and Tested over a Range of Temperatures, Chem. Phys. Lett., 1998 vol. 294, nos. 1–3, pp. 135–142.

    Article  ADS  Google Scholar 

  7. Duan, Yuan-Yuan, Shi, Lin, Han, Li-Zhong, and Zhu, Ning-Shen, Viscosity of Saturated Liquid Trifluoroiodomethane from 253 to 338 K, Fluid Phase Equilibrium, 1999, vol. 162, nos. 1–2, pp. 303–312.

    Article  Google Scholar 

  8. Harris, K.R. and Newitt, P.J., Diffusion and Structure in Water-Alcohol Mixtures: Water + Tret-Butyl Alcohol (2-Methyl-2-Propanol), J. Phys. Chem. Ser. A, 1999, vol. 103, no. 33, pp. 6508–6513.

    Article  Google Scholar 

  9. Aralaguppi, M.I., Jadar, S.V., and Aminabhavi, T.M. Density, Refractive Index, Viscosity, and Speed of Sound in Binary Mixtures of Cyclohexanone with Hexane, Heptane, Octane, Nanane, Decane, Dodecane and 2,2,4-Trimethylpentane, J. Chem. Eng. Data, 1999, vol. 44, no. 3, pp. 435–440.

    Article  Google Scholar 

  10. Aminabhavi, T.M. and Banerjee, K., Density, Viscosity, Refractive Index, and Speed of Sound in Binary Mixtures of 1-Chloronaphthalene with Benzene, Methylbenzene, 1,4-Dimethylbenzene, 1,3,5-Trimethylbenzene and Methoxybenzene at 298.15, 303.15 and 308.15 K, J. Chem. and Eng. Data, 1999, vol. 44, no. 3, pp. 547–542.

    Article  Google Scholar 

  11. Luk’yanchikova, I.A., Nikiforov, M.Yu., and Al’per, G.K., Viscosity of Binary Solutions Based on Alcohols, Carbohydrates, and Their Halogenated, in Trudy instituta khimii nevodnykh rastvorov RAN (Proc. of Institute of Chemistry of Non-Aqueous Solutions of RAS), Ivanovo: 1997.

  12. Trusov, N.V., Dmitriev, N.M., and Grin’, G.I., The Empirical Model for Determining Density and Viscosity of Hydrocyanic Acid, Izv. Vuzov. Khim. Khim. Tekhnol., 1996, vol. 39, no. 6, pp. 14–17.

    Google Scholar 

  13. Mustafaev, M.R., Viscosity of Some Perfluorcabons over a Wide Range of State Parameters, Teplofiz. Vys. Temp., 1996, vol. 34, no. 6, pp. 882–886.

    MathSciNet  Google Scholar 

  14. Ignatov, V.A., Zavisimost’ vyazkosti individual’nykh veshchestv i rastvorov ot temperatury i davleniya, Radiokhimiya, 1990, vol. 32, no. 2, pp. 20–24.

    Google Scholar 

  15. Klimenko, E.T., Dependence of the Viscosity of Mineral Oil Solutions on Temperature and Concentration, Zh. Fiz. Khim., 1992, vol. 66, no. 8, pp. 2068–2075.

    Google Scholar 

  16. Aleksandrov, V.V., Uvarova, O.N., Berezhnaya, T.A., Shikhova, T.M., and Berezhnoi, D.V., Tezisy dokl. 8 vsesoyuznogo soveshchaniya po fiziko-khimicheskomu analizu (Abstracts of Papers of 8th All-Union Meeting on Phyisico-Chemical Analysis), Saratov: 1991, Part 2.

  17. Sovelji, M. and Jakonic, J., Viscosities and Excess Molar Volumes of Binary Liquid Mixtures Containing Aliphatic Alcohols at Several Temperatures, J. Serb. Chem. Soc., 1998, vol. 63, no. 12, pp. 1001–1009.

    Google Scholar 

  18. Weng, Wen-Lu, Densities and Viscosities for Binary Mixtures of Anisole with 2-Butanol, 2-Methyl-1-Propanol, and 2-Methyl-2-Propanol, J. Chem. Eng. Data, 1999, vol. 44, no. 4, pp. 788–791.

    Article  Google Scholar 

  19. Avtomyan, E.G. and Fedotova, T.N., On Interaction of Thermodynamic and Viscous Properties in Binary Organic Liquids, Zh. Fiz. Khim., 1992, vol. 66, no. 7, pp. 1774–1752.

    Google Scholar 

  20. Abramzon, A.A., Variation of Conformation of Aliphatic Molecule Chain in Solutions at Viscous Flow of Liquid, Zh. Fiz. Khim., 1996, vol. 70, no. 3, pp. 508–511.

    Google Scholar 

  21. Trostina, V.A., Thermodynamic Characteristics of Viscous-Elastic Flow of n-Alkylpenyl Ethers of n-Alkyloxybenzoic Acid, Tezisy dokl. 2 vsesoyuznoi konf. Khim. i primenenie nevodnykh rastvorov (Abstracts of Papers of Chem and Application of Non-Aqueous Solutions 2nd All-Union Conf.), Khar’kov, 1989, vol. 1.

  22. Gorbachev, M.Yu., Bersuker, I.B., and Dimoglo, A.S., Dependences of Viscosity of Organically Non-Associated Liquids on Structural and Conformation Characteristics of Molecules, Teor. Exp. Khim., 1989, vol. 25, no. 5, pp. 563–567.

    Google Scholar 

  23. Syrnikov, Yu.P., Penkina, N.V., Kiselev, M.G., and Pukhovskii, Yu.P., General Dependences of temperature-Conformation Variations of the Viscosity of Binary System Solutions, Zh. Fiz. Khim., 1992, vol. 66, no. 1, pp. 185–189.

    Google Scholar 

  24. Martens, L.K., Spravochnik fizicheskikh, khimicheskikh I tekhnologicheskikh velichin (Reference Book on Physical, Chemical, and technological Values), Moscow: Sovetskaya entsiklopediya, 1933.

    Google Scholar 

  25. Rabinovich, V.A. and Khavin, Z.Ya., Kratkii khimicheskii spravochnik (Brief Chemical Reference Book), M.: Khimiya, 1978.

    Google Scholar 

  26. Goronovskii, I.N., Nazarenko, Yu.P., and Nekryach, E.F., Kratkii spravochnik po khimii (A Brief Reference Book on Chemistry), Kiev, Naukova dumka, 1974.

    Google Scholar 

  27. Panchenkov, G.M. and Lebedev, V.P., Khimicheskaya kinetika i kataliz (Chemical Kinetics and Catalysis), Moscow, Khimiya, 1974.

    Google Scholar 

  28. Morrison, R. and Boyd, R., Organicheskaya khimiya (Organic Chemistry), M.: Mir, 1974.

    Google Scholar 

  29. Garkunov, D.N., Kragel’skii, I.V., and Polyakov, A.A., Izbiratel’nyi perenos v uzlakh treniya (Selective Transfer in Friction Units), M.: Transport, 1969.

    Google Scholar 

  30. Burlakova, V.E., Triboelektrokhimiya effekta bezyznosnosti (Triboelectrochemistry of Wearlessness Effect), Rostov-on-Don: Izd.-vo DGTU, 2005.

    Google Scholar 

  31. Trenie, iznashivanie i smazka: spravochnik (Friction, Wear, and Lubrication: reference Book), Kragel’skii, I.V. and Alisin, V.V., Eds., M.: Mashinostroenie, 1978, vol. 1.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. B. Bulgarevich.

Additional information

Original Russian Text © S.B. Bulgarevich, V.I. Kolesnikov, I.N. Shcherbakov, M.V. Boiko, E.E. Akimova, 2009, published in Trenie i Iznos, 2009, Vol. 30, No. 2, pp. 113–121.

About this article

Cite this article

Bulgarevich, S.B., Kolesnikov, V.I., Shcherbakov, I.N. et al. Kinetic model of mutual effect of the components on the viscosity of binary mixtures. J. Frict. Wear 30, 80–86 (2009). https://doi.org/10.3103/S1068366609020020

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068366609020020

Key words

Navigation