Abstract
When interstitial clay, which is the waste from shale combustion, is fired at 250°C, the decomposition of organic matter results in the emission of H2, CO, SO3, and CO2 from the ceramic samples. At 350–550°C, the content of oxidant (oxygen) and neutral gas (nitrogen) is markedly less. At 550–750°C, no sharp decrease in their content is observed. At 750–1000°C, the decrease is slight. At 1000°C, mainly CO is formed. At 1050°C, the fired sample contains practically no organic compounds. More complex compounds (anorthite, diopside) are formed, with increase in the mechanical strength.
REFERENCES
Morev, A.A., Ilyasov, V.N., Ilyasov, S.V., Ilyasov, V.S., Mrakin, A.N., and Selivanov, A.A., Prospects of using fuel shales and products of their heat treatmnet in road construction, Mezhdunarodnyi Zh. Prikl. Fundam. Issled., 2016, nos. 3–4, pp. 529–532.
Nazarenko, M.Yu., Bazhin, V.Yu., Saltykova, S.N., and Sharikov, F.Yu., Change in composition and properties of fuel shales during heat treatment, Coke Chem., 2014, vol. 57, no. 10, pp. 413–416. https://doi.org/10.3103/s1068364x14100068
Zhang, Yu., Zhao, M., Linghu, R., Wang, C., and Zhang, S., Comparative kinetics of coal and oil shale pyrolysis in a micro fluidized bed reaction analyzer, Carbon Resour. Convers., 2019, vol. 2, no. 3, pp. 217–224. https://doi.org/10.1016/j.crcon.2019.10.001
Gornaev, N.A., Nikishin, V.E., Evteeva, S.M., and Nikiforova, L.V., Road construction materials from shales of the Volga Region, Materialy mezhdunarodnoi nauchnoi konferentsii Goryuchie slantsy — al’ternativnyi istochnik topliva i syr’ya, Fundamental’nye issledovaniya. Opyt i perspektivy (Proc. Int. Sci. Conf. on Fuel Shales As an Alternative Source of Fuel and Initial Product, Fundamental Studies: Experience and Prospects), Saratov: Saratovsk. Gos. Tekh. Univ., 2007, pp. 157–160.
Il’yasov, V.N., Shaftless ecologically safe extraction of fuel shales, Materialy mezhdunarodnoi nauchnoi konferentsii Goryuchie slantsy — al’ternativnyi istochnik topliva i syr’ya, Fundamental’nye issledovaniya. Opyt i perspektivy (Proc. Int. Sci. Conf. on Fuel Shales As an Alternative Source of Fuel and Initial Product, Fundamental Studies: Experience and Prospects), Saratov: Saratovsk. Gos. Tekh. Univ., 2007, pp. 131–137.
Savel’ev, V.V., Surkov, V.G., and Golovko, A.K., The yield and composition of the liquid product after mechanical destruction and thermolysis oil shales, Mezhdunar. Zh. Prikl. Fundam. Issled., 2014, no. 12-2, pp. 180–184.
Savel’ev, V.V., Golovko, A.K., and Kam’yanov, V.F., Effect of conditions of preliminary mechanoactivation of fuel shales on the yield and composition of products at their aquathermolysis, Izv. Tomsk. Politekh. Univ., 2013, vol. 323, no. 3, pp. 52–59.
Abdrakhimov, V.Z., Roshchupkina, I.Yu., and Abdrakhimova, E.S., Combustion of carbon in the firing of ceramic heat insulation based on fuel-shale wastes, Coke Chem., 2012, vol. 55, no. 11, pp. 432–437. https://doi.org/10.3103/s1068364x12110026
Abdrakhimov, V.Z., Combustion kinetics of organic components in firing porous aggregates based on ash and shale clay, Coke Chem., 2023, vol. 66, no. 3, pp. 135–143. https://doi.org/10.3103/S1068364X23700655
Abdrakhimov, V.Z., Influence of ash and slag on the characteristics of heat insulation based on metallurgical waste, Coke Chem., 2023, vol. 66, no. 6. https://doi.org/10.3103/S1068364X23700874
Suleimenov, S.T., Fiziko-khimicheskie protsessy strukturoobrazovaniya v stroitel’nykh materialakh i mineral’nykh otkhodakh promyshlennosti (Physicochemical Structure Formation Processes in Structural Materials and Mineral Industrial Waste), Moscow: Monuskrip, 1996.
Kolpakov, A.V., Denisov, D.Yu., and Abdrakhimov, V.Z., Combusion processes at firing of porous fillers based on waste of fule shales and oil slime separation products, Aktual’nye voprosy tekhnicheskikh nauk: Mater. II Mezhdunar. nauch. konf, Perm: Merkurii, 2013, pp. 70–74. https://moluch.ru/conf/tech/archive/73/3424/.
Abdrakhimov, V.Z. and Abdrakhimova, E.S., Oxidation processes in the firing of porous filler based on oil production wastes and intershale clay, Theor. Found. Chem. Eng., 2020, vol. 54, no. 4, pp. 750–755. https://doi.org/10.1134/s0040579519050026
Anpilov, S.M. and Abdrakhimov, V.Z., Use of light fraction ash and inter-shale clay in the production of earthquake-resistant bricks, Ugol’, 2021, no. 4, pp. 57–62. https://doi.org/10.18796/0041-5790-2021-4-57-62
Safronov, E.G., Abdrakhimov, V.Z., Naryzhnaya, N.Yu., and Silinskaya, S.M., Promising Recycling of Aspiration Dust and Interstitial Clay in the Production of Earthquake-Resistant Bricks, Ekol. Prom-st. Ross., 2023, vol. 27, no. 4, pp. 40–43. https://doi.org/10.18412/1816-0395-2023-4-40-43
Saibulatov, S.Zh., Suleimenov, S.T., and Ralko, A.V., Zolokeramicheskie stenovye materialy (Ash-Ceramic Wall Materials), Alma-Ata: Nauka, 1982.
Smailova, B.O., Idrisov, D.A., Saibulatov, S.Zh., Kuliba-ev, A.A., Lyan, A.N., Shevando, V.V., and Kalieva, Zh.E., Physicochemical processes at firing of ash-slag-ceramic materials, Stroitel’nye Mater., 2003, no. 2, pp. 54–56.
Kol’tsova, T.N., Compositions of gismondine, cymrite, anorthite, and celsian solid solutions, Inorg. Mater., 2017, vol. 53, no. 7, pp. 741–751. https://doi.org/10.1134/S0020168517070123
Sergievich, O.A., Alekseenko, I.A., and Artem’ev, E.A., Ceramic materials with increased wear-resistance for machine-buildingand light industry, Tr. Kol’skogo Nauchn. Tsentra Ross. Akad. Nauk, 2017, vol. 8, no. 5–1, pp. 167–172.
Kukhtin, B.A., Golovin, E.P., Fedorov, N.V., et al., Glass formation in anorthite ceramics, Khim. Khim. Tekhnol., 2007, vol. 50, no. 5, pp. 79–82.
Vereshchagin, V.I., Buruchenko, A.E., and Men’shikova, V.K., Nonshrinkable facing ceramic material based on diopside raw material, Sovrem. Probl. Nauki Obraz., 2015, no. 1, pp. 18–25.
Safronova, T.V. and Zykova, Yu.A., Physicochemical processes of interaction between diopside and polymineral low-plastic initial products, Vestn. Irkutsk. Gos. Tekh. Univ., 2012, no. 10, pp. 188–194.
Funding
This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
The authors of this work declare that they have no conflicts of interest.
Additional information
Translated by B. Gilbert
About this article
Cite this article
Abdrakhimov, V.Z., Nikitina, N.V. Phase Composition of Interstitial Clay and Gas Emissions on Heat Treatment. Coke Chem. 66, 431–437 (2023). https://doi.org/10.3103/S1068364X23701028
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068364X23701028