Skip to main content
Log in

Quality and Utility of Shubarkol Shale from Kazakhstan

  • COAL
  • Published:
Coke and Chemistry Aims and scope Submit manuscript

Abstract

The quality of Shubarkol carbonaceous shale from Kazakhstan is studied by state-of-the-art methods, with particular attention to its composition, its mineral composition, and its chemical, petrographic, physicochemical, and thermomechanical properties. According to one industrial classification, the shale is of humic–sapropelic type in genetic terms; it consists primarily of sorbomixtinite. The product yield in semicoking (550°C) and coking (900°C) is studied, with detailed analysis of the solid particles, tar, and gas. Industrial uses are recommended both for the initial shale and for the semicoking products.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Brendow, K., Global oil shale issues and perspectives, Oil Shale, 2003, vol. 20, no. 1, pp. 81–92.

    Google Scholar 

  2. Kuznetsov, Goryuchie slantsy mira (Oil Shale of the World), Moscow: Nedra, 1975.

  3. Bitumens, Asphalts, and Tar Sands, Chilingarian, G.V. and Yen, T.F., Eds., Amsterdam: Elsevier, 1978.

    Google Scholar 

  4. Zelenin, N.I. and Ozerov, I.M., Spravochnik po goryuchim slantsam (Oil Shale Handbook), Leningrad: Nedra, 1983.

  5. Glezin, I.L., Efimov, V.M., Petukhov, E.F., et al., Spravochnik slantsepererabotchika (Handbook of Oil Shale Worker), Rudin, M.G. and Serebryannikov, N.D., Eds., Leningrad: Khimiya, 1988.

    Google Scholar 

  6. Fraiman, G.B., Shale industry: processes and development trends, Ugol’, 1999, no. 8, pp. 39–41.

  7. Fraiman, G.B., Myakov, S.B., and Salikhov, R.M., The status and prospective development of shale industry, Ugol’, 2003, no. 8, pp. 52–55.

  8. Efimov, V.M., Ioonas, R.E., Doilov, S.K., and Aranovich, Yu.V., Slantsepererabatyvayushchaya promyshlennost’ SSSR i puti ee razvitiya (Shale Processing Industry in USSR and Its Development), Moscow: TsNIITEneftekhim, 1982.

  9. Petrov, A.M., Borodulin, V.A., and Grigor’eva, A.V., Wasteless industry in shale mining, Ugol’, 1988, no. 10, pp. 9–12.

  10. Sheindlin, A.E., Oil shale as a prospective raw material for national economy, Goryuchie Slantsy, 1984, no. 1, pp. 2–5.

  11. Problems of semicoking of bulk oil shale, Tr. Nauchno-Issled. Inst. Slantsev, 1978, no. 22.

  12. Problemy sozdaniya moshchnykh generatorov dlya polukoksovaniya goryuchikh slantsev (Creation of Powerful Generators for Semicoking of Oil Shale), Moscow: TsNIITEneftekhim, 1991, no. 25.

  13. Pokonova, Yu.V. and Fainberg, V.S., Shale chemistry, Itogi Nauki Tekh., Ser.:Tekhnol. Org. Veshchestv, 1985, vol. 10.

    Google Scholar 

  14. Efimov, V.M., Purre, N.A., and Rappu, L.I., Characteristic of shale as technological raw material, Tr. Nauchno-Issled. Inst. Slantsev, 1973, no. 19, pp. 7–15.

  15. Petrovich, N.I., Ostroukhov, N.N., Vasilyev, V.V., Salamatova, E.V., and Strakhov, V.M., Comparison of the composition of gasoline fractions obtained by semicoking of kukersite oil shale in Kiviter and Petroter systems, Coke Chem., 2018, vol. 61, no. 10, pp. 401–407.

    Article  Google Scholar 

  16. Petrovich, N.I., Ostroukhov, N.N., Vasilyev, V.V., Salamatova, E.V., and Strakhov, V.M., Comparison of diesel fractions produced by semicoking of kukersite shale in different equipment, Coke Chem., 2019, vol. 62, no. 1, pp. 23–28.

    Article  Google Scholar 

  17. Petrovich, N.I., Ostroukhov, N.N., Vasilyev, V.V., Salamatova, E.V., and Strakhov, V.M., Comparison of light fuel-oil fractions produced by semicoking of kukersite shale in a gas generator and in a solid-fuel system, Coke Chem., 2019, vol. 62, no. 6, pp. 249–257.

    Article  Google Scholar 

  18. Zelenin, N.I., Fainberg, V.S., and Chernysheva, K.B., Khimiya i tekhnologiya slantsevoi smoly (Chemistry and Technology of Shale Resin), Moscow: Khimiya, 1968.

  19. Polozov, V.F. and Ozerov, I.M., Industrial classification of oil shale, Khim. Tverd. Topl. (Moscow), 1974, no. 1, pp. 81–85.

  20. Syroezhko, A.M., Foughalia, H., Slavoshevskaya, N.V., and Strakhov, V.M., Thermal and thermochemical processing of regular and enriched shale of different genetic types in mixtures with petroleum residues, Coke Chem., 2011, vol. 54, no. 5, pp. 169–175.

    Article  Google Scholar 

  21. Gerasimov, A.M., Syroezhko, A.M., Dronov, S.V., and Strakhov, V.M., Processing of carbon-bearing materials mixed with fuel shales, Coke Chem., 2012, vol. 55, no. 5, pp. 184–187.

    Article  Google Scholar 

  22. Vasil’ev, V.V., Antikorrozionnye i gidroizolyatsionnye materially na osnove netraditsionnogo syr’ya-slantsevykh smol i okislennykh neftyanykh bitumov (Anticorrosion and Waterproof Materials Based on Unconventional Raw Materials—Shale Resins and Oxidized Petroleum Bitumen), St. Petersburg: S.-Peterb. Gos. Inzh.-Ekon. Univ., 2007.

  23. Kolomiets, V.A., Kurakov, Yu.I., and Samofalov, V.S., Use of oil shale in production of graphitized products, Materialy XII Vserossiiskogo ugol’nogo soveshchaniya “Innovatsionnye napravleniya izucheniya, otsenki i effektivnosti ispol’zovaniya mineral’no-syr’evoi bazy tverdykh goryuchikh iskopaemykh,” Tezisy dokladov (Proc. XII All-Russ. Coal Conf. “Innovative Trends in Study, Evaluation, and Effective Use of Mineral Resources of Solid Fossil Fuels,” Abstracts of Papers), Rostov-on-Don, 2010, pp. 121–125.

  24. Oyunbold, D., Syroezhko, A.M., Slavoshevskaya, N.V., and Strakhov, V.M., Influence of coal, shale, and petrochemical binders and fillers on the properties of cold-rammed hearth mass, Coke Chem., 2010, vol. 53, no. 6, pp. 222–227.

    Article  Google Scholar 

  25. Fedorov, V.A., Signalov, I.N., Dushina, A.P., and Aleskovskii, V.B., The use of cyclone ash of pulverized oil shale for wastewater treatment, Tsvetn. Met., 1978, no. 4, pp. 33–34.

  26. Pokonova, Yu.V. and Grabovskii, A.I., Sorption of nnoble metals by sorbents from oil shale products, Tsvetn. Met., 1989, no. 1, pp. 121–122.

  27. Kurunov, I.F., Yarikov, I.S., Lyapin, S.S., and Emel’yanov, V.L., The industrial use of shungite in the smelting of cast iron, Stal’, 2003, no. 7, pp. 9–13.

  28. Nikitin, L.D., Portnov, L.V., Bugaev, S.F., and Dolinskii, V.A., Using shungite in blast-furnace smelting, Steel Transl., 2007, vol. 37, no. 10, pp. 858–860.

    Article  Google Scholar 

  29. Dolinskii, V.A., Nikitin, L.D., Portnov, L.V., et al., Possible use of shungite in blast furnaces at the West Siberian Metallurgical Plant, Izv. Vyssh. Uchebn. Zaved., Chern. Metall., 2007, no. 12, pp. 16–19.

  30. Bliznyukov, A.S., Use of shungite minerals in blast furnace smelting, Chern. Metall., Byull. Nauchno-Tekh. Ekon. Inf., 2008, no. 5, pp. 5–14.

  31. Mizin, V.G. and Strakhov, V.M., Undustrial use of shungite minerals in production of ferroalloys, Chern. Metall., Byull. Nauchno-Tekh. Ekon. Inf., 2009, no. 10, pp. 78–83.

  32. Nechipurenko, S.V., Tasibekov, Kh.S., Toknaev, R.R., et al., Shungity Kazakhstana: svoistva i puti prakticheskogo ispol’zovaniya (Shungites of Kazakhstan: Properties and Practical Use), Almaty: Kazakh. Univ., 2018.

  33. Novikova, N.V., Sin’kova, L.A., and Semenov, L.V., The use of carbonaceous minerals in blast furnace industry, Ugol’, 1988, no. 9, pp. 20–21.

  34. Strakhov, V.M., Coke-industry waste from SS coal as a blast-furnace raw material, Coke Chem., 2007, vol. 50, no. 4, pp. 92–93.

    Article  Google Scholar 

  35. Baisanov, S.O., Tolymbekov, M.Zh., Zharmenov, A.A., et al., Using clay rock in smelting ferrosilicoaluminum, Coke Chem., 2008, vol. 38, no. 8, pp. 668–670.

    Google Scholar 

  36. Mizin, V.G., Serov, G.V., Sablin, N.I., et al., Smelting of 45% ferrosilicon on high-ash Angarsk semicoke, Stal’, 1974, no. 10, pp. 909, 910.

  37. Strakhov, V.M., Valov, N.I., Mizin, V.G., et al., Use of Angarsk semicoke in production of casted iron, Koks Khim., 1975, no. 6, pp. 25–28.

Download references

ACKNOWLEDGMENTS

The author thanks the following for assistance in this research: V.M. Men’shenin (ENRC), S.P. Kim (OAO Shubarkol Komir), I.L. Glezin (OAO VNIINeftekhim), and A.M. Syroezhko (St. Petersburg Technological University).

I.V. Surovtseva, N.V. Osipova, L.A. Nadtoka, and T.D. Nedesheva participated in the analyses and tests.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. M. Strakhov.

Additional information

Translated by B. Gilbert

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Strakhov, V.M. Quality and Utility of Shubarkol Shale from Kazakhstan. Coke Chem. 63, 5–20 (2020). https://doi.org/10.3103/S1068364X20010081

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068364X20010081

Keywords:

Navigation