Abstract
The modification of carbon mass for self-igniting anodes is considered. The mass consists of a binder–filler system. The modifier employed is the phenolic fraction of coal tar. The filler is anthracite treated at 1800°C. The binder is moderate-temperature electrode pitch (grade B). Research shows that cocarbonization of the modifier in the binder–filler system on heating may consist of two processes: 1) before transition of the pitch to a viscofluid state, the additive facilitates mutual approach of its macromolecules and expands the temperature range of nucleation of graphite-like structures; 2) on account of adhesive forces, the phenolic fraction is attached to the filler (thermoanthracite) surface. That, in turn, should intensify the wetting, adsorption, adhesion, and sintering capacity of the electrode pitch (binder).
![](http://media.springernature.com/m312/springer-static/image/art%3A10.3103%2FS1068364X18100058/MediaObjects/11955_2019_10029_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.3103%2FS1068364X18100058/MediaObjects/11955_2019_10029_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.3103%2FS1068364X18100058/MediaObjects/11955_2019_10029_Fig3_HTML.gif)
Similar content being viewed by others
REFERENCES
Martin, S.W. and Nelson, H.W., Pitch binder coke yields, Ind. Eng. Chem., 1958, vol. 50, no. 1, pp. 33–40.
Wewerka, E.M., The determination of the molecular distributions of graphite binder materials by gel permeation chromatography, Carbon, 1968, vol. 6, no. 1, pp. 93–100.
Kremer, H.A., Recent developments electrode pitch and coal tar technology, Chem. Ind., 1982, vol. 18, pp. 702–713.
Pityulin, I.N., Surowcowa baza do produkcji koksu iglowego z zakladom Ukrainy, Karbo. Energochem. Ekol., 1997, vol. 42, no. 5, pp. 184–187.
Cheshko, F.F., Pityulin, I.N., Pyrin, A.I., and Shustikov, V.I., Alternative raw material for the production of pitch needle coke on coal base, Koks Khim., 1995, no. 3, pp. 25–27.
Tarakhno, E.V., Lutsenko, Yu.V., Cheshko, F.F., et al., Molecular distillation as method of evaluating the mesogeneity of components of coal-tar pitch, Koks Khim., 1998, no. 5, pp. 14–17.
Pinchuk, S.I., Organizatsiya eksperimentu pri modelyuvannii ta optimizatsii tikhnichnikh sistem: Navchal’nii posibnik (Experiment Planning in Modeling of Optimization of Technological Systems: Manual), Dnepropetrovsk: Dnipro-VAL, 2009.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by Bernard Gilbert
About this article
Cite this article
Malyi, E.I., Chemerinskii, M.S., Golub, I.V. et al. Tar-Based Modification of Carbon Mass for Self-Igniting Anodes. Coke Chem. 61, 392–395 (2018). https://doi.org/10.3103/S1068364X18100058
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068364X18100058