Abstract
Low-temperature pyrolysis of slightly metamorphosed D, DG, and G coal in a Fisher retort produces semicoke, whose specific surface, total pore volume, micropore volume, and mesopore volume are determined. The porous structure of the semicoke is investigated at the 77 K isotherm corresponding to nitrogen sorption and desorption. The semicoke formed contains >50% micropores. The mesopores present are also relatively small (3–7 nm).
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References
Gryaznov, N.S., Osnovy teorii koksovaniya (Fundamental Theory of Coking), Moscow: Metallurgiya, 1976.
Makarov, G.N., Khimicheskaya tekhnologiya tverdykh goryuchikh iskopaemykh (Chemical Technology of Solid Fossil Fuels), Moscow: Khimiya, 1986.
Glushchenko, I.M., Prognoz kachestva koksa (Forecast of Coke Quality), Moscow: Metallurgiya, 1976.
Ivanov, V.P. and Bondarenko, I.S., Assessing coke structure, Coke Chem., 2013, vol. 56, no. 9, pp. 326–331.
Zvyagintseva, E.V. and Skripchenko, G.B., The reactivity of coke, Khim. Tverd. Topl. (Moscow), 2000, no. 6, pp. 61–72.
Bazegskii, A.E., Denisov, Yu.M., and Volynkina, E.P., The quality of bulky blast fuel, Koks Khim., 2000, nos. 11–12, pp. 15–17.
Miroshnichenko, D.V. and Ulanovskii, M.L., The reactivity of coke: measurement and influence factors, Koks Khim., 2004, no. 5, pp. 21–31.
Gyul’maliev, A.M., Sultanguzin, I.A., and Bologova, V.V., Simulation of the strength of metallurgical coke, Solid Fuel Chem., 2012, vol. 46, no. 2, pp. 90–92.
Guo, R., Sun, Z., Hu, W.-C., and Liang, Y.-H., Formation of pore structure during coking of bituminous coal: theory and application, Koks Khim., 2014, no. 11, pp. 11–14.
Cheng, H., Wang, Q., Zhang, S., and Han, X., The effects of different experimental conditions on the detected results of coal pore characteristics, Coke Chem., 2015, vol. 58, no. 9, pp. 329–341.
Fedorova, N.I., Manina, T.S., and Ismagilov, Z.R., Porous structure of high-temperature coke from black coal, Chem. Sustainable Dev., 2016, vol. 24, no. 3, pp. 385–391.
Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, New York: Academic, 1982, 2nd ed.
Lowell, S., et al., Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Dordrecht: Kluwer, 2010, vol. 5, pp. 11–12.
Fenelonov, V.B., Vvedenie v fizicheskuyu khimiyu formirovaniya supramolekulyarnoi struktury adsorbentov i katalizatorov (Introduction into Physical Chemistry of the Formation of Supramolecular Structure of Adsorbents and Catalysis), Novosibirsk: Sib. Otd., Ross. Akad. Nauk, 2002.
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Original Russian Text © N.I. Fedorova, Yu.N. Dudnikova, Z.R. Ismagilov, 2018, published in Koks i Khimiya, 2018, No. 4, pp. 29–33.
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Fedorova, N.I., Dudnikova, Y.N. & Ismagilov, Z.R. Porous Structure of Semicoke Based on Slightly Metamorphosed Coal. Coke Chem. 61, 131–135 (2018). https://doi.org/10.3103/S1068364X18040038
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DOI: https://doi.org/10.3103/S1068364X18040038