Skip to main content
Log in

Synthesis and Nonlinear Electro-Optical Properties of Zn4B6O13

  • Published:
Journal of Contemporary Physics (Armenian Academy of Sciences) Aims and scope

Abstract

This paper reports the results of the investigation of second order optical nonlinearity, as well as the polarization nonlinear behavior of Zn4B6O13. For experiments samples were prepared by thermal treatment of glass tapes and solid state synthesis. The tapes were obtained by a rapid melt quenching technique. The thermal processes in the glass tapes were investigated by differential thermal analysis. The synthesized materials were studied by X-ray diffraction. For the sample thermally treated at 710°C for 18 h, the remnant polarization up to 0.04 μC/cm2 was measured under an electric field of 49 kV/cm. It was shown that the second harmonic generation intensity of Zn4B6O13 is 1.9 times higher than that of the well-known optical material KH2PO4.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Chen, Ch., Wu, Y., Jiang, A., Wu, B., You, G., Li, R., and Lin, Sh., J. Opt. Soc. Am. B, 1989, vol. 6, p. 616.

    Article  ADS  Google Scholar 

  2. Wu, Y., Sasaki, T., Nakai, S., Yokotani, A., Tang, H., and Chen, Ch., Appl. Phys. Lett., 1993, vol. 62, p. 2614.

    Article  ADS  Google Scholar 

  3. Mori, Y., Kuroda, I., Nakajima, S., Sasaki, T., and Nakai, S., Appl. Phys. Lett., 1995, vol. 67, p. 1818.

    Article  ADS  Google Scholar 

  4. Studebaker, D.B., Stauf, G.T., Marks, T.J., Zhou, H., and Wong, G.K., Appl. Phys. Lett., 1997, vol. 70, p. 565.

    Article  ADS  Google Scholar 

  5. Xia, M., Jiang, X., Lin, Zh., and Li, R., J. Am. Chem. Soc., 2016, vol. 138, p. 14190.

    Article  Google Scholar 

  6. Becker, P., Adv. Mater., 1998, vol. 10, p. 979.

    Article  Google Scholar 

  7. Martinez-Ripoll, M., Martínez-Carrera, S., and García-Blanco, S., Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 1971, vol. 27, p. 672.

    Article  Google Scholar 

  8. Garcia-Blanco, S. and Fayos, J., Z. Kristallogr., 1968, vol. 127, p. 145.

    Article  Google Scholar 

  9. Smith, P., Garcia-Blanco, S., and Rivoir, L., Z. Kristallogr., 1961, vol. 115, p. 460.

    Article  Google Scholar 

  10. Terol, S. and Oterio, M.J., Z. Naturforschg A, 1961, vol. 16, p. 920.

    Article  ADS  Google Scholar 

  11. Smith, P., Garcia-Blanco, S., and Rivoir, L., Z. Kristallogr., 1964, vol. 119, p. 375.

    Article  Google Scholar 

  12. Smith-Verdier, P. and Garcia-Blanco, S., Z. Kristallogr., 1980, vol. 151, p. 175.

    Google Scholar 

  13. Bohaty, L., Haussuhl, S., Liebertz, J., and Stahr, S., Z. Kristallogr., 1982, vol. 161, p. 157.

    Article  Google Scholar 

  14. Meijerink, A., Blasse, G., and Glasbeek, M., J. Phys.: Condens. Matter, 1990, vol. 2, p. 6303.

    ADS  Google Scholar 

  15. Alemi, A., Mohseni, N., Dolatyari, M., and Bakhtiari, A., Int. J. Bio-Inorg. Hybd. Nanomat., 2012, vol. 1, p. 79.

    Google Scholar 

  16. Hovhannisyan, R., Alexanyan, H., Hovhannisyan, M., Petrosyan, B., and Harutyunyan, V., Chapter 3, Ferroelectrics – Physical Effects, InTech, 2011, pp. 49–76.

    Google Scholar 

  17. International Center for Diffraction Data [ICDD] (2008). Powder Diffraction Fails, PDF-2 release database, Pennsylvania, USA, ISSN 1084-3116.

  18. Sawyer, C.B. and Tower, C.H., Phys. Rev., 1930, vol. 35, p. 269.

    Article  ADS  Google Scholar 

  19. Kurtz, S.K. and Perry, T.T., J. Appl. Phys., 1968, vol. 39, p. 3798.

    Article  ADS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The author is grateful to Mr. O. Alexanyan from OMEGA Ltd. and Dr. I. Harutyunyan from the Department of Optics, Yerevan State University for fruitful discussions.

Funding

This work was supported by OMEGA Ltd. and the University of Electronic Science and Technology of China.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. G. Harutyunyan.

Additional information

Translated by V.G. Harutyunyan

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Harutyunyan, V.G. Synthesis and Nonlinear Electro-Optical Properties of Zn4B6O13 . J. Contemp. Phys. 56, 25–29 (2021). https://doi.org/10.3103/S1068337221010084

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068337221010084

Keywords:

Navigation