Abstract
Broadband spectra of ordinary water, heavy water, and ice are analyzed in terms of the dynamic conductivity. It is shown that the spectrum below 1015 Hz satisfies the sum rule for the oscillator strength and is related to the dynamics of the proton/deuteron subsystem in the quasilattice of low-mobility oxygen atoms. Debye relaxation andOHband are represented as a result of the same mechanism, i.e., the proton motion in the harmonic potential averaged over different observation periods.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. von Hippel, Trans. Electr. Insul. 23, 801 (1988).
J. D. Jackson, Classical Electrodynamics, 2nd ed. (Wiley, New York, 1975).
W. J. Ellison, J. Phys. Chem. Ref. Data 36, 1 (2007).
J.-B. Brubach, A. Mermet, A. Filabozzi, et al., J. Chem. Phys. 122, 184509 (2005).
S. Gopalakrishnan, D. Liu, H.C. Allen, et al., Chem. Rev. 106, 1155 (2006).
J. Schiffer and D. F. Hornig, J. Chem. Phys. 49, 4150 (1968).
J. Martí, J. A. Padro, and E. Guàrdia, J. Chem. Phys. 105, 639 (1996).
S. Imoto, S. S. Xantheas, and S. Saito, J. Chem. Phys. 138, 054506 (2013).
D. Kennedy and C. Norman, Science 309, 75 (2005).
A. A. Volkov, V. G. Artemov, and A. V. Pronin, Eur. Phys. Lett. 106, 46004 (2014).
G. P. Johari, A. Hallbrucker, and E. Mayer, J. Chem. Phys. 94, 1212 (1990).
J. K. Vij, D. R. J. Simpson, and O. E. Panarina, J. Mol. Liq. 112, 125 (2004).
H. Yada, M. Nagain, and K. Tanaka, Chem. Phys. Lett. 464, 166 (2008).
M. R. Querry, D. M. Wieliczka, and D. J. Segelstein, “Refractive Index of Water (H2O),” in Handbook of Optical Constants of Solids, Ed. by E.D. Palik (Academic, New York, 1991).
S. G. Warren, Appl. Opt. 23, 1026 (1984).
S. G. Warren and R. E. Brandt, J. Geophys. Res. 113, D14220 (2008).
U. Møller, D. G. Cooke, K. Tanaka, and P. U. Jepsen, J. Opt. Soc. Am. B 26(9), A113 (2009).
D. J. Segelstein, “The Complex Refractive Index of Water,” PhD Thesis (Univ. Missouri-Kansas City, 1981).
V. G. Artemov and A. A. Volkov, Ferroelectrics 466, 158 (2014).
L. D. Landau and E. M. Lifshitz, Statistical Physics, Part 1, 5th ed. (Fizmatlit, Moscow, 2002; Oxford Univ., Oxford, 1998).
S. H. Lee and J. C. Rasaiah, J. Chem. Phys. 139, 124507 (2013).
P. Bruesch, S. Strassler, and H. R. Zeller, Phys. Stat. Sol. (a) 31, 217 (1976).
R. Kubo, M. Toda, and N. Hashitsume, Statistical Physics II. Nonequilibrium Statistical Mechanics (Springer, Heidelberg, 1985).
Y. Marechal, J. Chem. Phys. 95, 5565 (1991).
Y. Marechal, J. Mol. Struct. 1004, 146 (2011).
J.-J. Max and C. Chapados, J. Chem. Phys. 131, 184505 (2009).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.A. Govras, V.Yu. Bychenkov, 2015, published in Kratkie Soobshcheniya po Fizike, 2015, Vol. 42, No. 6, pp. 31–36.
About this article
Cite this article
Artemov, V.G. Dielectric spectrum of water as a proton dynamics response. Bull. Lebedev Phys. Inst. 42, 187–191 (2015). https://doi.org/10.3103/S1068335615060068
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068335615060068