Skip to main content
Log in

Investigation of a Novel CoCrCuNiTi High Entropy Alloy on Microstructure and Mechanical Properties

  • PHYSICAL METALLURGY AND HEAT TREATMENT
  • Published:
Russian Journal of Non-Ferrous Metals Aims and scope Submit manuscript

Abstract

A novel 3d transition metal high entropy alloy (3d TM HEA), CoCrCuNiTi, was exploited by Ti addition into a common 4-elemental group of CoCrCuNi. Its phase constitution, microstructure, and compressive properties in as-cast and annealed conditions were investigated. The studied alloys in both states were composed of a complex multiphase structure, including two BCC phases, one FCC phase, one cubic laves phase, and one HCP Ni3Ti phase. The two BCC phases took up around 50 vol % in total, and the other three phases occurred within the remaining regions. The majority of the BCC phases were attributed to the promising ultimate compressive strength of the studied alloys in both conditions (as-cast: 2.53 GPa, annealed: 2.22 GPa). Furthermore, an outstanding hardness of 694 HV was obtained in the as-cast alloy, implying that no strong relationship was exhibited among the hardness, phase constituent, or valence electron concentration (VEC) in the CoCrCuNi-base HEAs system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Yeh, J.W., Chen, S.K., and Lin, S.J., et al., Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes, Adv. Eng. Mater., 2004, vol. 6, pp. 299–303.

    Google Scholar 

  2. Cantor, B., Chang, I.T.H., Knight, P., et al., Microstructural development in equiatomic multicomponent alloys, Mater. Sci. Eng., A, 2004, vols. 375–377, pp. 213–218.

    Google Scholar 

  3. Miracle, D.B. and Senkov, O.N., A critical review of high entropy alloys and related concepts, Acta Mater., 2017, vol. 122, pp. 448–511.

    Google Scholar 

  4. Tsai, M.H. and Yeh, J.W., High-entropy alloys: a critical review, Mater. Res. Lett., 2014, vol. 2, no. 3, pp. 107–123.

    Google Scholar 

  5. Zhang, Y., Zuo, T.T., Tang, Z., et al., Microstructures and properties of high-entropy alloys, Prog. Mater. Sci., 2014, vol. 61, pp. 1–93.

    Google Scholar 

  6. Yeh, J.W., Chen, S.K., Gan, J.Y., et al., Formation of simple crystal structures in Cu–CoNi–Cr–Al–Fe–Ti–V alloys with multiprincipal metallic elements, Metall. Mater. Trans. A, 2004, vol. 35, pp. 2533–2536.

    Google Scholar 

  7. Tong, C.J., Chen, M.R., Chen, S.K., et al., Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements, Metall. Mater. Trans. A, 2004, vol. 36, pp. 1263–1271.

    Google Scholar 

  8. Eleti, R.R., Bhattacharjee, T., Shibata, A., et al., Unique deformation behavior and microstructure evolution in high temperature processing of HfNbTaTiZr refractory high entropy alloy, Acta Mater., 2019, vol. 171, pp. 132–145.

    Google Scholar 

  9. Li, J., Fang, Q., Liu, B., et al., Transformation induced softening and plasticity in high entropy alloys, Acta Mater., 2018, vol. 147, pp. 35–41.

    Google Scholar 

  10. Basu, I., Ocelik, V., and De Hosson, J.T.M., Size dependent plasticity and damage response in multiphase body centered cubic high entropy alloys, Acta Mater., 2018, vol. 150, pp. 104–116.

    Google Scholar 

  11. Quiambao, K.F., McDonnell, S.J., Schreiber, D.K., et al., Passivation of a corrosion resistant high entropy alloy in non-oxidizing sulfate solutions, Acta Mater., 2019, vol. 164, pp. 362–376.

    Google Scholar 

  12. Hsu, Y.J., Chiang, W.C., and Wu, J.K., Corrosion behavior of FeCoNiCrCux high-entropy alloys in 3.5% sodium chloride solution, Mater. Chem. Phys., 2005, vol. 92, no. 1, pp. 112–117.

    Google Scholar 

  13. Zhou, Y.J., Zhang, Y., Wang, Y.L., et al., Microstructure and compressive properties of multicomponent Alx(TiVCrMnFeCoNiCu)100−x high-entropy alloys, Mater. Sci. Eng., A, 2007, vols. 454–455, pp. 260–265.

    Google Scholar 

  14. Derimow, N., Clark, T., Roach, C., et al., Processing pathway effects in CoCrCuNi + X (Fe, Mn) high-entropy alloys, Philos. Mag., 2019, vol. 99, no. 15, pp. 1899–1913.

    Google Scholar 

  15. Hsu, U.S., Hung, U.D., Yeh, J.W., et al., Alloying behavior of iron, gold and silver in AlCoCrCuNi-based equimolar high-entropy alloys, Mater. Sci. Eng., A, 2007, vols. 460–461, pp. 403–408.

    Google Scholar 

  16. Tsai, M.H., Yuan, H., Cheng, G., et al., Morphology, structure and composition of precipitates in Al0.3CoCrCu0.5FeNi high-entropy alloy, Intermetallics, 2013, vol. 32, pp. 329–336.

    Google Scholar 

  17. Jung, J., Lee, S.J., Kim, S., et al., Effect of Ti additions on micro-alloyed Nb TRIP steel, Steel Res. Int., 2011, vol. 82, no. 7, pp. 857–865.

    Google Scholar 

  18. He, T.T., Wang, W., Chen, D.M., et al., Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy, Int. J. Hydrogen Energy, 2014, vol. 39, no. 2, pp. 684–691.

    Google Scholar 

  19. Zhou, Y.J., Zhang, Y., Wang, Y.L., et al., Solid solution alloys of AlCoCrFeNiTix with excellent room-temperature mechanical properties, Appl. Phys. Lett., 2007, vol. 90, no. 18, p. 181904.

    Google Scholar 

  20. Chen, M.R., Lin, S.J., Yeh, J.W., et al., Microstructure and properties of Al0.5CoCrCuFeNiTix (x = 0–2.0) high-entropy alloys, Mater. Trans., 2006, vol. 47, no. 5, pp. 1395–1401.

    Google Scholar 

  21. Hu, Z., Zhan, Y., Zhang, G., et al., Effect of rare earth Y addition on the microstructure and mechanical properties of high entropy AlCoCrCuNiTi alloys, Mater. Des., 2010, vol. 31, no. 3, pp. 1599–1602.

    Google Scholar 

  22. Varalakshmi, S., Kamaraj, M., and Murty, B.S., Processing and properties of nanocrystalline CuNiCoZnAlTi high entropy alloys by mechanical alloying, Mater. Sci. Eng., A, 2010, vol. 527, nos. 4–5, pp. 1027–1030.

    Google Scholar 

  23. Wang, X.F., Zhang, Y., Qiao, Y., et al., Novel microstructure and properties of multicomponent CoCrCuFeNiTix alloys, Intermetallics, 2007, vol. 15, no. 3, pp. 357–362.

    Google Scholar 

  24. Cai, Z., Jin, G., Cui, X., et al., Experimental and simulated data about microstructure and phase composition of a NiCrCoTiV high-entropy alloy prepared by vacuum hot-pressing sintering, Vacuum, 2016, vol. 124, pp. 5–10.

    Google Scholar 

  25. Couzinié, J.P., Lilensten, L., Champion, Y., et al., On the room temperature deformation mechanisms of a TiZrHfNbTa refractory high-entropy alloy, Mater. Sci. Eng., A, 2015, vol. 645, pp. 255–263.

    Google Scholar 

  26. Senkov, O.N., Scott, J.M., Senkova, S.V., et al., Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy, J. Alloys Compd., 2011, vol. 509, no. 20, pp. 6043–6048.

    Google Scholar 

  27. Wang, W.R., Wang, W.L., Wang, S.C., et al., Effects of Al addition on the microstructure and mechanical property of AlxCoCrFeNi high-entropy alloys, Intermetallics, 2012, vol. 26, pp. 44–51.

    Google Scholar 

  28. Kao, Y.F., Chen, T.J., Chen, S.K., et al., Microstructure and mechanical property of as-cast, -homogenized, and -deformed AlxCoCrFeNi (0 ≤ x ≤ 2) high-entropy alloys, J. Alloys Compd., 2009, vol. 488, no. 1, pp. 57–64.

    Google Scholar 

  29. Tsai, M.H., Tsai, K.Y., Tsai, C.W., et al., Criterion for sigma phase formation in Cr- and V-containing high-entropy alloys, Mater. Res. Lett., 2013, vol. 1, no. 4, pp. 207–212.

    Google Scholar 

  30. Tung, C.C., Yeh, J.W., Shun, T., et al., On the elemental effect of AlCoCrCuFeNi high-entropy alloy system, Mater. Lett., 2007, vol. 61, no. 1, pp. 1–5.

    Google Scholar 

  31. Li, A., Ma, D., and Zheng, Q., Effect of Cr on microstructure and properties of a series of AlTiCrxFeCoNiCu high-entropy alloys, J. Mater. Eng. Perform., 2014, vol. 23, no. 4, pp. 1197–1203.

    Google Scholar 

Download references

ACKNOWLEDGMENTS

Financial supports from the Natural Science Foundation of China (Grants no. 51801124) and Natural Science Research of Jiangsu Higher Education Institutions of China (Grants no. 18KJB430012) are gratefully acknowledge.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lu Wang.

Ethics declarations

We declared that the present work has no conflicts with other researchers or organizations.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yi, J., Yang, L., Xu, M. et al. Investigation of a Novel CoCrCuNiTi High Entropy Alloy on Microstructure and Mechanical Properties. Russ. J. Non-ferrous Metals 62, 197–205 (2021). https://doi.org/10.3103/S1067821221020073

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1067821221020073

Keywords:

Navigation