Abstract
The results of experimental investigations into the possibility of formation of consolidated power hard alloys by the explosive compacting method without subsequent sintering are presented. Carbides of tungsten (WC), chromium (Cr3C2), and silicon (SiC) are used as main carbide components, and titanium, nickel, and copper serve as a metallic binder. The compression pressure of the powder mixture in shockwaves during the explosive compacting is varied in a range from 5 to 16 GPa, and the heating temperature is varied from 250 to 950°C. The structure, chemical composition, and phase composition are investigated using optical (Axiovert 40MAT, Carl Zeiss), scanning electron (FEI Versa 3D), and transmission electron (FEI Titan 80-300, Tecnai G2 20F) microscopes. It is shown that powder compositions with the titanium binder are densified substantially better than mixtures with copper or nickel. The hardness of materials after the explosive compacting reaches 1200 HV. The range of temperatures corresponding to (0.35–0.4)tm (where tm is the absolute melting point of the main alloy carbide), the cleavage character of the samples changes from intercrystallite to transcrystallite when passing through it. It is revealed that this is associated with the formation of strong boundaries between carbide particles and metallic matrix, which represent interlayers with a thickness of the order of 80–100 nm with its proper crystalline structure differing from the structure of main alloy components.
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REFERENCES
Schwarzkopf, P. and Kieffer, R., Cemented Carbides, Macmillan, 1960.
Groover, M.P., Fundamentals of Modern Manufacturing: Materials, Processes and Systems, Wiley, 2010, 4th ed.
Gourdin, W.H., Dynamic consolidation of metal powders, Progr. Mater. Sci., 1986, vol. 30, pp. 39–80.
Prummer, R.A., Explosive compaction of powders, principle and prospects, Materialwissenschaft und Werkstofftechnik, 1989, vol. 20, pp. 410–415.
Murr, L.E., Staudhammer, K.P., and Meyers, M.A., Metallurgical Applications of Shock-Wave and High-Strain-Rate Phenomena, New York: Dekker 1986.
Prummer, R.A., Balakrishna Bhat, T., Siva Kumar, K., and Hokamoto, K., Explosive Compaction of Powders and Composites, Enfield, 2006.
Krokhalev, A.V., Kharlamov, V.O., Kuz’min, S.V., and Lysak, V.I., Regularities of formation of hard alloys made of mixtures of chromium carbide powders with titanium using the explosion energy, Izv. Vyssh. Uchebn. Zaved, pporoshk. Metall. Funkts. Pokryt., 2012, no. 1, pp. 32–37.
Kayuk, V.G., Masljuk, V.A., and Kostenko, A.D., Tribological properties of hard alloys based on chromium carbide, Powder Metall. Met. Ceram., 2003, vol. 42, pp. 257–261.
Hussainova, I., Jasiuk, I., Sardela, M., and Antonov, M., Micromechanical properties and erosive wear performance of chromium carbide based cermets, Wear, 2009, vol. 267, pp. 152–159.
Da-Yung Wang, Ko-Wei Weng, Chi-Lung Chang, and Wei-Yu Ho, Synthesis of Cr3C2 coatings for tribological applications, Surf. Coat. Technol., 1999, vol. 120, pp. 622–628.
Petrova, A.M. and Shtern, M.B., The influence of nanostructural oxide films on wear-resistance of titanium materials, in: Carbon Nanomaterials in Clean Energy Hydrogen Systems, Netherlands: Springer, 2008, pp. 851–856.
Krokhalev, A.V., Kharlamov, V.O., Kuz’min, S.V., and Lysak, V.I., Computer calculation of compression parameters during the explosion deposition of powder coatings, Izv. VolgGTU, ser. Svarka Vsryv. Sv-va Svarn. Soed., 2010, no. 5, pp. 110–116.
Krasulin, Yu.L. and Nazarov, G.Z., Mikrosvarka davleniem (Pressure Microwelding), Moscow: Metallurgiya, 1976.
Krasulin, Yu.L., Dislocations as active centers in topochemical reactions, Theor. Exper. Chem., 1969, vol. 3, no. 1, pp. 31–35.
Krasulin, Yu.L. and Shorshorov, M.Kh., Revisiting the mechanism of formation of the connection of dissimilar material in the solid state, Fiz. Khim. Obrab. Mater., 1967, no. 1, pp. 89–97.
Ushanova, E.A., Nesterova, E.V., Petrov, S.N., Rybin, V.V., Kuz’min, S.V., and Greenberg, V.A., Development of the preparation technology of the samples for electron microscopy investigations of nanocrystalline adhesion zones in dissimilar compounds based on ion polishing methods, Vopr. Materialoved., 2011, no. 1, pp. 110–117.
Focused Ion Beam Systems: Basics and Applications, Nan Yao, Ed., Cambridge: Cambridge Univ., 2007.
Shabashov, V.A., Filippova, N.P., Ovchinnikov, V.V., Mulyukov, R.R., and Valiev, R.Z., Determination of the “grain-boundary phase” in submicrocrystalline iron by the Mössbauer spectroscopy, Phys. Met. Metallogr., 1998, vol. 85, no. 3, pp. 318–326.
Shevchenko, V.Ya., Khasanov, O.L., Yur’ev, G.S., and Pokholkov, Yu.P., Observation of structural features of the ultradispersed state of zirconium dioxide by the synchrotron radiation diffraction, Dokl. Akad. Nauk, 2001, vol. 377, no. 6, pp. 797–799.
Lysak, V.I., Kuz’min, S.V., Krokhalev, A.V., and Grinberg, B. A., Structure of boundaries in composite materials obtained using explosive loading, Phys. Met. Metallogr., 2013, no. 11, pp. 947–952.
Haubold, T., Birringer, R., Lengeler, B., and Gleiter, H., EXAFS studies of nanocrystalline materials exhibiting a new solid state structure with randomly arranged atoms, Phys. Lett. A, 1989, vol. 135, pp. 461–466.
Song, J., Kostka, A., Veehmayer, M., and Raabe, D., Hierarchical microstructure of explosive joints: Example of titanium to steel cladding, Mater. Sci. Eng. A, 2011, vol. 528, pp. 2641–2647.
ACKNOWLEDGMENTS
This study was supported by the Russian Scientific Foundation, project no. 14-29-00158.
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Translated by N. Korovin
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Krokhalev, A.V., Kharlamov, V.O., Tupitsin, M.A. et al. Revisiting the Possibility of Formation of Hard Alloys from Powder Mixtures of Carbides with Metals by Explosive Compacting without Sintering. Russ. J. Non-ferrous Metals 59, 550–556 (2018). https://doi.org/10.3103/S1067821218050073
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DOI: https://doi.org/10.3103/S1067821218050073