Abstract
The main production methods of WC powders, notably, rapid carbothermic reduction (RCR), “calcination–reduction–carburization” (CRC), reduction of tungsten oxide with carbon in rotating furnaces, spray conversion process (SCP), high-energy milling, etc., are considered. The influence of growth inhibitors of the carbide grain on the structure of hard alloys is analyzed. According to the data of some authors, the optimal inhibitor content is 0.5–1.5 wt %, and the alloy embrittles at its higher content due to the formation of complex carbide phases. It is shown that nanosized hard alloys (d WC < 100 nm) cannot be prepared by the traditional liquid-phase sintering the mixtures, and the application of alternative solid-phase consolidation methods is necessary. The structure, properties, and application regions of submicron and nanosized hard alloys fabricated by hot pressing, high-frequency induction pressing, electric discharge sintering under the plasma pressure consolidation (PPC), spark plasma sintering (SPS), etc., are considered.
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References
Fal’kovskii, V.A. and Klyachko, L.I., Tverdye splavy (Hard Alloys), Moscow: Ruda i Metally, 2005.
Andrievskii, R.A. and Ragulya, A.V., Nanostrukturnye materialy (Nanostructured Materials), Moscow: Akadema, 2005.
Johnston, G.P., Muenchausen, R., Smith, D.M., et al., Am. Ceram. Soc. Bull., 1992, vol. 75, no. 12, p. 3293.
Starck, H.C., FRG Patent 19 852 459, 2000.
McCandlish, L.E., Kear, B.H., and Bhatia, USPatent 5352269, 1994.
Kudrya, N.A., Fal’kovskii, V.A., and Chistyakova, V.A., Vyyasnenie vozmozhnosti primeneniya plazmennogo poroshka vol’frama: Otchet 1 19-8211-38 (Revelation of the Possibility of Applying Plasma Tungsten Powder, Report no. 8211-38), Moscow: Vsesoyuzn. Nauch.Issled. Inst. Tverd. Splavov, 1983.
Conner, C.L., in Proc. 14th Int. Plansee Seminar, Austria: RWF Werbegesellschaft, 1977, p. 171.
McCandlish, L.E. and Seegopaul, P., in Proc. Eur. Conf. Advances in Hard Materials Production, Stockholm, 1996, p. 93.
Seegopaul, P. and Gao, L., US Patent 6?524?366, 2003.
Borovinskaya, I.P., Ignat’eva, T.I., Vershinnikov, V.I., and Sachkova, N.V., Inorg. Mater., 2004, vol. 40, no. 10, p. 1043.
Yao, L. and Kear, B.H., US Patent 5?919?428, 1999.
Hojo, J., Oku, T., and Kato, A., J. Less-Common Met., 1978, vol. 59, no. 1, p. 85.
Wan, C.-W., Chen, B.-S., and Sohn, H.Y., J. Mater. Res., 1993, vol. 8, no. 10, p. 2702.
Tang, X., Haubner, R., Lux, B., and Kieffer, B., J. Phys. IV, 1995, vol. 5, p. 1013.
Kim, J.C. and Kim, B.K., Scr. Mater., 2004, vol. 50, no. 7, pp. 969–972.
Sohn, H.Y., Ryu, T., Hwang, K.S., and Fang, Z.Z., Proc. NTCA, 2004, vol. 34, no. 2, pp. 533–537.
Sohn, H.Y., Ryu, T., Choi, J.W., et al., Jom-Us., 2007, vol. 59, no. 12, p. 44.
Lin Sha, Lin Yang, Vang Ynibin, et al., Chin. Raze. Earth. Soc., 2003, vol. 21, no. 6, p. 677.
Kim, B.K., Ha, G.G., and Woo, Y., US Patent 6511551, 2003.
El-Eskandarany, M.S., Mahday, A.A., Ahmed, H., et al., J. Alloy Compd., 2000, vol. 312, nos. 1–2, p. 315.
Butler, B.G., Lu, J., Fang, Z.G.Z., et al., Int. J. Powder Metal., 2007, vol. 43, no. 1, p. 35.
Lee, G., Ha, G.H., and Kim, B.K., J. Korean Inst. Metal Mater., 1999, vol. 37, no. 10, p. 1233.
Panov, V.S., Chuvilin, A.M., and Fal’kovskii, V.A., Tekhnologiya i svoistva spechennykh tverdykh splavov (Technology and Properties of Sintered Hard Alloys), Moscow: MISiS, 2004.
Liu, S., et al., in Proc. 16th Plansee Seminar, vol. 2, p. 353, Austria, 2005.
Fal’kovskii, V.S., Innovatsii v tekhnologii tverdykh splavov: Nano-i ul’tradispersnye struktury (Innovations in Technology of Hard Alloys: Nanodispersed and Ultradispersed Structures), Moscow: Mosk. Inst. Tonk. Khim. Tekhnol., 2008.
Borovsky, G.V., Annunciation, J.V., Abramov, A.V., et al., in Proc. 16th Plansee Seminar, vol. 2, p. 224–229, Austria, 2005.
Fang, Z., Wang, X., and Ryu, T., Int. J. Refract. Metal. Hard Mater., 2009, vol. 27, no. 2, p. 288.
Schubert, W.D., in Proc. Int. Conf. Tungsten Hard Metals and Refractory Alloys, Annapolis, USA: MD, 2000, p. 13.
Maheshwari, P., Fang, Z.G.Z., and Sohn, H.Y., Int. J. Powder Metal., 2007, vol. 43, no. 2, p. 41.
Fang, Z.Z. and Eason, J.W., Int. J. Refract. Metal. Hard Mater., 1995, vol. 13, no. 5, p. 297.
McCandlish, L.E., Kear, B.H., and Kim, B.K., Nanostruct. Mater., 1992, vol. 1, no. 2, p. 119.
Wang, X., Fang, Z.Z., and Sohn, H.Y., Int. J. Refract. Metal. Hard Mater., 2008, vol. 26, no. 3, p. 232.
Konyashin, I., Ries, B., Lachmann, F., et al., Int. J. Refract. Metal. Hard Mater., 2008, vol. 26, no. 3, p. 583.
Klyachko, L.I., in Proc. 15th Plansee Seminar, Austria, 2001, pp. 203–207.
Panov, V.S., Teoreticheskie osnovy prochnosti spechennykh tverdykh splavov (Theoretical Foundations of the Strength of Sintered Hard Alloys), Moscow: MISiS, 2011.
Zaitsev, A.A., Vershinnikov, V.I., Panov, V.S., et al., Izv. Vyssh. Uchebn. Zaved., Poroshk. Metal. Funkts. Pokryt., 2013, no. 3, p. 21.
Gille, G., Szesny, B., Dreyer, K., et al., Int. J. Refract. Metal. Hard Mater., 2002, vol. 20, no. 1, p. 3.
Jia, K., Fischer, T.E., and Gallois, B., Nanostruct. Mater., 1998, vol. 10, no. 5, p. 875.
Bartha, L., Atato, P., Toth, A.L., et al., J. Adv. Mater., 2000, vol. 32, no. 3, p. 23.
Konner, C.L., J. Adv. Mater., 2004, p. 171.
Lisovskii, A.F., Sverkhtverd. Mater., 2011, no. 4, p. 9.
Zamulaeva, E.I., Development of Nanostructured Coatings Based on WC–Co, Extended Abstract of Cand. Sci. (Eng.) Dissertation, Moscow: MISiS, 2009.
Alymov, M.I., Ross. Khim. Zh., 2009, vol. 53, no. 2, p. 111.
Tsvetkov, Yu.V., Blagoveshchenskii, Yu.V., Klyachko, L.I., et al., in Sbornik trudov 3-i Vserossiiskoi konferentsii po nanomaterialam NANO-2009 (Collected Works of 3rd All-Russian Conf. on Nanomaterials), Yekaterinburg, 2009, pp. 726–728.
Dubensky, E.M. and Nilsson, R.T., US Patent 5773735, 1996.
Wang, X., Fang, Z., and Sohn, H.Y., in Proc. Int. Conf. Powder Metallurgy & Particulate Materials., Engquist, J., Ed., Denver, US, 2007, pp. 8–10.
Michalski, A. and Siemiaszko, D., Int. J. Refract. Metal. Hard Mater., 2007, vol. 25, no. 2, p. 153.
Chuvildev, V.N., Moskvicheva, A.V., Blagoveshenskiy, Y.V., et al., in Proc. 17th Plansee Seminar, Austria, 2009, vol. 2, p. 240.
Azcona, I., Ordonez, A., Sanchez, J.M., and Castro, F., J. Mater. Sci., 2002, vol. 37, no. 19, p. 4189.
Panov, V.S. and Shumenko, V.N., Tekhnologiya i svoistva spechennykh tverdykh splavov: Kurs lektsii (Technology and Properties of Sintered Hard Alloys: Course of Lectures), Moscow: MISiS, 2013.
Froschauer, L. and Fulrath, R.M., Direct observation of liquid-phase sintering in the system tungsten carbidecobalt: Rep. no. LBL-3189, Berkeley, CA: Lawrence Berkeley Laboratory, University of California, Oct. 1974.
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Original Russian Text © V.S. Panov, A.A. Zaitsev, 2014, published in Izvestiya VUZ. Poroshkovaya Metallurgiya, 2014, No. 3, pp. 38–48.
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Panov, V.S., Zaitsev, A.A. Developmental tendencies of technology of ultradispersed and nanosized WC–Co hard alloys alloyed with tantalum carbide: Review. Russ. J. Non-ferrous Metals 56, 477–485 (2015). https://doi.org/10.3103/S106782121504015X
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DOI: https://doi.org/10.3103/S106782121504015X