Abstract
Sorption of rhenium(VII) and vanadium(V) from mineralized sulfate-chloride solutions by fibrous ionites of the FIBAN series is investigated. Equilibrium, kinetic, and dynamic characteristics of sorption of Re and V by the FIBAN ionite of the AK-22 brand, which contains functional groups =NH2, -NH2, -COOH, and ≡N, are found. It is established that the maximal capacity of this reagent in regards to vanadium(V) is observed at pH = 4. Sorption isotherms of Re and V are linear, being described by the Henry equation with constants K H = 1.36 ± 0.30 dm3/g (R 2 = 0.995) and 674 ± 21 cm3/g (R 2 = 0.999), respectively. Integral sorption kinetic curves are found under conditions of a limited solution volume, and effective diffusion coefficients of Re and V, which constituted 9.0 × 10−13 and 7.5 × 10−15 m2/s, respectively, are calculated allowing for the half-transformation time. The possibility of separating these metals in dynamic conditions is shown.
Similar content being viewed by others
References
Palant, A.A., Troshkina, I.D., and Chekmarev, A.M., Metallurgiya reniya (Metallurgy of Rhenium), Moscow: Nauka, 2007.
Laverov, N.P., Abdul’manov, I.G., Brovin, K.G., et al., Podzemnoe vyshchelachivanie polielementnykh rud (Underground Leaching of Complex Ores), Laverov, N.P., Ed., Moscow: Acad. Mining Sci. (AGN), 1998.
Mizin, V.G., Rabinovich, E.M., Sirina, T.P., et al., Kompleksnaya pererabotka vanadievogo syr’ya: Khimiya i tekhnologiya (Complex Processing of Vanadium Raw Materials), Yekaterinburg: Ural Branch Russ. Acad. Sci. (UrO RAN), 2005.
Sanitarno-epidemiologicheskie pravila i normativy SanPiN (Sanitary and Epidemiological Rules and Standards SanRiN), 2.1.4.2580-10.
Vanadii i ego soedineniya (67). Ser. Nauchnye obzory sovetskoi literatury po toksichnosti i opasnosti khimicheskikh veshchestv (Vanadium and Its Compounds (67). Ser. Science Reviews of Soviet Literature on Toxicology and Danger of Chemical Substances), Moscow: Center Int. Projects State Committee Sci. Tech. (GKNT), 1984.
Plevaka, A.V., Troshkina, I.D., Zemskova, L.A., and Voit, A.V., Russ. J. Inorg. Chem., 2009, vol. 54, no. 7, p. 1168.
Soldatov, V.S. and Sergeev, G.I., Zh. Vseros. Khim. Obshch-va, 1990, no. 1, p. 101.
Borisova, L.V. and Ermakov, A.N., Analiticheskaya khimiya reniya (Analytical Chemistry of Rhenium), Moscow: Khimiya, 1974.
Muzgin, V.N., Khamzina, L.B., Zolotavin, V.L., and Bezrukov, I.Ya., Analiticheskaya khimiya vanadiya (Analytical Chemistry of Vanadium), Moscow: Nauka, 1981.
Troshkina, I.D., Zemskova, L.A., Chekmarev, A.M., et al., 7th Int. Symp. on Technetium and Rhenium—Science and Utilization: Book of Proceedings, Moscow: Granitza, 2011.
Kokotov, Yu.A. and Pasechnik, V.A., Ravnovesie i kinetika ionnogo obmena (Equilibrium and Kinetics of Ion Exchange), Leningrad: Khimiya, 1979.
Frolov, Yu.G., Kurs kolloidnoi khimii (Course of Colloid Chemistry), Moscow: Khimiya, 1982.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Nway Shwan Oo, I.D. Troshkina, Aye Min, A.V. Shilyaev, 2014, published in Izvestiya VUZ. Tsvetnaya Metallurgiya, 2014, No. 2, pp. 42–47.
About this article
Cite this article
Oo, N.S., Troshkina, I.D., Min, A. et al. Sorption of rhenium and vanadium from mineralized solutions by fibrous ionites. Russ. J. Non-ferrous Metals 55, 242–246 (2014). https://doi.org/10.3103/S1067821214030134
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1067821214030134