Abstract
Experimental data on the study of nitriding the powdered NiTi intermetallic compound formed in the course of reduction of calcium hydride are given. A theoretical analysis showed that this process occurs in the external mode with the decomposition of titanium nickelide NiTi through a Ni3 Ti intermediate phase into titanium nickelide and a Ni(Ti) solid solution of titanium in nickel. It was found that, at t = 1000–1200°C, nitridation should be terminated by the formation of the following equilibrium phase: TiN1.0 titanium nitride of stoichiometric composition and nickel containing practically no titanium. A model of the nitridation process is proposed which provides the qualitative description of the growth of forming TiN and Ni phases and evaluation of the time of total disappearance of titanium nickelide for NiTi powder particles of a specific size.
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References
Kislyi, P.S., Bodnaruk, N.I., and Borovikova, M.S., Kermety (Cermets), Kiev: Naukova Dumka, 1985.
Kaidash, O.N., Marinich, M.A., Kuzenkova, M.A., and Manzheleev, I.V., Poroshk. Metall., 1991, no. 1, p. 77.
Kulik, A.Ya., Borisov, Yu.S., Mnukhin, A.S., and Nikitin, M.D., Gazotermicheskoe napylenie kompositsionnykh poroshkov (Gas-Thermal Deposition of Composite Powders), Leningrad: Mashinostroenie, 1985.
Kotenev, V.I. and Kasimtsev, A.V., USSR Inventor’s Certificate, 1991.
Kasimtsev, A.V., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 2002, no. 6, p. 51.
Kiparisov, S.S. and Levinskii, Yu.V., Vnutrennee okislenie i azotirovanie metallov (Internal Oxidation and Nitridation of Metals), Moscow: Metallurgiya, 1979.
Levinskii, Yu.V., Vnutrenne okislennye i vnutrenne azotirovannye nanomaterialy (Internally Oxidized and Internally Nitrided Nanomaterials), Moscow: Ecomet, 2007.
Savva, S.S., Weatherly, G.C., and Kirkaldy, J.S., Metall. Mater. Trans. A, 1996, vol. 27A, p. 1611.
Fizicheskie velichiny: Spravochnik (Physical Quantities: Handbook), Grigor’ev, I.S. and Meilikhova, E.Z., Eds., Moscow: Energoatomizdat, 1991.
Lakhtin, Yu.M., Kogan, Ya.D., Shashkov, D.V., et al., Metally, 1989, no. 3, p. 91.
Diagrammy sostoyaniya dvoinykh metallicheskikh sistem: Spravochnik (Phase Diagrams of Binary Metal Systems: Handbook), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 2001.
Wriedt, H.A., Bull. Alloy Phase Diagrams, 1985, vol. 6, p. 558.
Kiparisov, S.S. and Levinskii, Yu.V., Azotirovanie tugoplavkikh metallov (Nitridation of Refractory Metals), Moscow: Metallurgiya, 1972.
Krupp, U. and Christ. H.-J., Oxid. Met., 1999, vol. 52, nos. 3–4, p. 299.
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Original Russian Text © A.V. Kasimtsev, Yu.V. Levinskii, V.V. Zhigunov, 2008, published in Izvestiya VUZ. Poroshkovaya Metallurgiya i Funktsional’nye Pokrytiya, 2008, No. 2, pp. 3–8.
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Kasimtsev, A.V., Levinskii, Y.V. & Zhigunov, V.V. Production of a Ni-TiN composite powder by nitridation of titanium nickelide. Russ. J. Non-ferrous Metals 49, 383–388 (2008). https://doi.org/10.3103/S1067821208050131
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DOI: https://doi.org/10.3103/S1067821208050131