Skip to main content
Log in

Redox Reactions in Natural and Waste Water Treatment Processes

  • WATER TREATMENT AND DEMINERALIZATION TECHNOLOGY
  • Published:
Journal of Water Chemistry and Technology Aims and scope Submit manuscript

Abstract

The reasonability of using the redox potential to characterize the state of a certain water system was substantiated. Peat fulvic acids characteristic for the natural water of the Dnipro River were selected as a target compound for study before and after the adsorption processes. Fruitstone-derived activated carbon (FDAC), FDAC oxidized by hydrogen peroxide (FADC-O), and FDAC modified with iron oxides (FDAC-Fe) were used as adsorbents. All the systems with both distilled and tap water were shown to have an oxidative character for the period of study, especially after sodium azide and hydrogen peroxide were added. The introduction of fulvic acids into the system neutralized this effect due to their interaction. The redox potential was proposed to use for simplified measurement as an indicator of pollution in water of different types.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

REFERENCES

  1. James, C.N., Copeland, R., and Lytle, D.A., Relationships between oxidation-reduction potential, oxidant, and pH in drinking water, Proc. AWWA Water Quality Technology Conference, San Antonio, TX, November, 2004, pp. 14–18.

  2. Yu, R.-F., Chen, H.-W., Cheng, W.-P., and Shen, Y.-C., Dynamic control of disinfection for wastewater reuse applying ORP/pH monitoring and artificial neural networks, Resour., Conserv. Recycl., 2008, vol. 52, nos. 8–9, pp. 1015–1021. https://doi.org/10.1016/j.resconrec.2008.03.007

    Article  Google Scholar 

  3. Sigg, L., Redox potential measurements in natural waters significance, concepts and problems, in Redox Fundamentals, Processes and Applications, Berlin: Springer, 2000, pp. 1–12. https://doi.org/10.1007/978-3-662-04080-5_1

  4. McMahon, P.B. and Chapelle, F.H., Redox processes and water quality of selected principal aquifer systems, Ground Water, 2008, vol. 46, no. 2, pp. 259–271. https://doi.org/10.1111/j.1745-6584.2007.00385.x

    Article  CAS  PubMed  Google Scholar 

  5. Reduction–Oxidation (Redox) Control in Ohio’s Ground Water Quality, Technical Series on Ground Water Quality, Division of Drinking and Ground Waters, 2014.

  6. Kim, H., Kwon, S., Han, S., Yu, M., Kim, J., Gong, S., and Colosimo, M.F., New ORP/pH based control strategy for chlorination and dechlorination of wastewater: Pilot scale application, Water Sci. Technol., 2006, vol. 53, no. 6, pp. 145–151. https://doi.org/10.2166/wst.2006.188.11

    Article  CAS  PubMed  Google Scholar 

  7. Melnik, L.A., Vakulenko, V.F., Saprykina, M.N., and Sova, A.N., Change of the oxidation reduction potential of model and natural waters during their disinfection by ozone, J. Water Chem. Technol., 2021, vol. 43, no. 1, pp. 85–91. https://doi.org/10.3103/S1063455X21010094

    Article  Google Scholar 

  8. Ukrainets, A.I., Bolshak, Y.V., Marinin, A.I., and Svyatnenko, R.S., Redox balance of drinking water—An indicator of its quality and physiological adequacy, Pishch. Prom-st, 2018, no. 24, pp. 6–14. https://doi.org/10.24263/2225-2916-2018-24-3

  9. Račys, V., Kliučininkas, L., Jankūnaitė, D., and Albrektienė, R., Application of ORP for the evaluation of water contamination, Proc. Linnaeus ECO-TECH 10, Kalmar, 2010.

  10. Bol’shak, Y.V., Kalenyk, O.S., Marynin, A.I., and Svyatnenko, R.S., Study of the regularities of the formation of healthy antioxidant electron-donating properties of functional drinking water modified with ascorbic and citric acid, Nauchn. Vestn. Lviv. Nats. Univ. Vet. Med. Biotekhnol, Ser.: Pishch. Tekhnol., 2020, vol. 22, no. 94, pp. 3–7. https://doi.org/10.32718/nvlvet-f9401

    Article  Google Scholar 

  11. Methods in Microbiology, Norris, J.R. and Ribbons, D.W., Eds., London: Academic, 1970, vol. 2.

  12. von Rohr, M.R., Hering, J.G., Kohler, H.-P.E., and von Gunten, U., Column studies to assess the effects of climate variables on redox processes during riverbank filtration, Water Res., 2014, vol. 61, pp. 263–275. https://doi.org/10.1016/j.watres.2014.05.018

    Article  CAS  Google Scholar 

  13. Khasanov, A.T., What kind of water preserves health? Nov. Tekhnol., Nauchn. Vestn. Kremechug. Univ. Ekon., Inf, Tekhnol. Upr., 2013, no. 3–4, pp. 135–138. http://nbuv.gov.ua/UJRN/NewTech_2013_3-4_26.

  14. Klymenko, N.A., Savchina, L.A., Sidorenko, Yu.V., and Vrubel, T.L., Specificity of the combined bioregeneration of activated carbons under dynamic conditions, J. Water Chem. Technol., 2005, vol. 27, no. 5, pp. 44–53.

    Google Scholar 

  15. Oliveira, C.A., Silva, C.N., Yoshida, M.I., and Lago, R.M., The effect of H2 treatment on activated carbon for the oxidation of organic contaminants in water and H2O2 decomposition, Carbon, 2004, vol. 42, no. 11, pp. 2279–2284. https://doi.org/10.1016/j.carbon.2004.05.003

    Article  CAS  Google Scholar 

  16. Sadhasivam, S., Savitha, S., Swaminathan, K., and Lin, F.-H., Production, purification and characterization of mid-redox potential laccase from a newly isolated Trichoderma harzianum WL1, Process Biochem., 2008, vol. 43, no. 7, pp. 736–742. https://doi.org/10.1016/j.procbio.2008.02.017

    Article  CAS  Google Scholar 

  17. Klimenko, N.A., Savchina, L.A., Kozyatnik, I.P., Malysheva, M.L., and Polyakova, T.V., The impact of various oxidation modes on the variation of structural characteristics of activated carbon, J. Water Chem. Technol., 2008, vol. 30, no. 5, pp. 269–275. https://doi.org/10.3103/S1063455X08050020

    Article  Google Scholar 

  18. Zabneva, O.V., Smolin, S.K., Klimenko, N.A., Shvidenko, O.G., Grechanik, S.V., and Sinel’nikova, A.V., Structural and sorption properties of activated carbon modified with iron oxides, J. Water Chem. Technol., 2012, vol. 34, no. 6, pp. 264–270. https://doi.org/10.3103/S1063455X12060033

    Article  Google Scholar 

  19. Osadcha, N.M., Balance of flow of humic substances in the cascade of Dnipro reservoirs, Nauchn. Tr. Ukr. Nauchno-Issled. Gidrometeorol. Inst., 2012, vol. 263, pp. 81–99. http://nbuv.gov.ua/UJRN/Npundgi_2012_263_8.

    Google Scholar 

  20. Marczenko, Z., Kolorymetryczne Oznaczanie Pierwiastkow, Warszawa: Wysdawnictwa Naukowo-Techniczne, 1968.

    Google Scholar 

Download references

Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. A. Savchyna.

Ethics declarations

The authors of this work declare that they have no conflicts of interest.

Additional information

Publisher’s Note.

Allerton Press remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Savchyna, L.A., Klymenko, N.A. & Samsoni-Todorova, O.O. Redox Reactions in Natural and Waste Water Treatment Processes. J. Water Chem. Technol. 46, 64–73 (2024). https://doi.org/10.3103/S1063455X24010077

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1063455X24010077

Key words:

Navigation