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Evaluation of Organochlorine Pesticides (OCPs) and Polychlorinated Biphenyls (PCBs) Concentrations in the River and Marine Sediments of Samsun Coastline

  • ANALYTICAL WATER CHEMISTRY
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Abstract

Today, the persistent organic pollutant loads which are formed as a result of modern agriculture and industrial production are becoming very dangerous for the environment and human health. Exposure of living things to these pollutants can occur by direct exposure to pollutants emission or by transport of pollutants as a result of food chain and meteorological events. For this reason, all environmental samples should be analyzed in this context and risk assessments should be made especially for regions where pollutant emissions may occur. In this study, bottom sediment sampling was made from a total of 16 stations including 8 freshwater and 8 seawater from the region located on the coastline of Yeşilırmak Basin. In sediment samples analysis were carried out for persistent organic pollutant (POP) groups (PCB, OCP) using standard methods. The toxic effects of the determined concentrations of the pollutants, which are situated in national and international legislations, primarily, were evaluated as a result of the related analysis. Gas chromatography mass spectrometry (GC-MSMS) systems were used for PCB and OCP analyses. As a result of the analyses, for 7 total PCB congeners with 23.73 μg kg–1 near the smelting and electrolysis plant at the Marine-5 coded marine station and for the OCP compounds, the highest concentrations were detected as agricultural activities at 8 freshwater sampling stations. PCB 138 compound with 4.99 PCB μg kg–1 for PCB and in the freshwater sampling stations 10.03 μg kg–1 for OCP with 4,4'-DDT have been observed. When the total results of POP analysis of sediment samples are evaluated, it has been observed that there are unintentionally occurring compounds, but their effect levels are low in terms of aquatic life.

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REFERENCES

  1. Kılavuz, S.A., Determination of PCDD/F levels of consumed food and risk assessment in Kocaeli, PhD Thesis, Izmit: Kocaeli Univ., 2010.

  2. Güngörmüş, E., Ambient air persistent organic pollutant monitoring, backtrajectory modeling, and health risk assessment, MSc Thesis, Izmir: Izmir Inst. Technol., 2015.

  3. Mitra, S., Corsolini, S., Pozo, K., Audy, O., Sarkar, S.K., and Biswas, J.K., Characterization, source identification and risk associated with polyaromatic and chlorinated organic contaminants (PAHs, PCBs, PCBzs and OCPs) in the surface sediments of Hooghly estuary, India, Chemosphere, 2019, vol. 221, pp. 154–165.

    Article  CAS  Google Scholar 

  4. dos Santos, I.F., Ferreira, L.C., Domínguez, S., and Bayona, C., Analytical strategies for determining the sources and ecotoxicological risk of PAHs in river sediment, Microchem. J., 2018, vol. 137, pp. 90–97.

    Article  CAS  Google Scholar 

  5. Mrema, E.J., Rubino, F.M., Brambilla, G., Moretto, A., Tsatsakis, A.M., and Colosio, C., Persistent organochlorinated pesticides and mechanisms of their toxicity, Toxicology, 2013, vol. 307, pp. 74–88.

    Article  CAS  Google Scholar 

  6. Porpora, M.G., Resta, S., and Fuggetta, E., Organochlorine pesticides exposure & preterm birth Indian, J. Med. Res., 2016, vol. 143, no. 6, pp. 685–687.

    CAS  Google Scholar 

  7. Zhao, Z., Jiang, Y., Li, Q., Cai, Y., Yin, H., Zhang, L., and Zhang, J., Spatial correlation analysis of polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) in sediments between Taihu Lake and its tributary rivers, Ecotoxicol. Environ. Saf., 2017, vol. 142, pp. 117–128.

    Article  CAS  Google Scholar 

  8. Shen, L. and Wania, F., Compilation, evaluation, and selection of physical-chemical property data for organochlorine pesticides, J. Chem. Eng. Data, 2005, vol. 50, pp. 742–768.

    Article  CAS  Google Scholar 

  9. Rose, M.D., Environmental contaminants: Dioxins, furans, and dioxin-like polychlorinated biphenyls, in Encyclopedia of Food Safety, vol. 2: Hazards and Diseases, Amsterdam: Elsevier, 2013, pp. 315–322.

  10. Mochida, Y., Fukata, H., Matsuno, Y., and Mori, C., Reduction of dioxins and polychlorinated biphenyls (PCBs) in human body, Fukuoka Igaku Zasshi, 2007, vol. 98, no. 4, pp. 106–115.

    CAS  Google Scholar 

  11. Wan, W., Bai, J., Zhang, G., Jia, J., Wang, X., Liu, X., and Cui, B., Occurrence, sources and ecotoxicological risks of polychlorinated biphenyls (PCBs) in sediment cores from urban, rural and reclamation-affected rivers of the Pearl River delta, China, Chemosphere, 2019, vol. 218, pp. 359–367.

    Article  Google Scholar 

  12. IPCS, Polychlorinated Biphenyls: Concise International Chemical Assessment Document 55, Geneva: World Health Org., 2003.

    Google Scholar 

  13. Learn about Polychlorinated Biphenyls (PCBs), Washington, DC: US Environ. Prot. Agency, 2003.

    Google Scholar 

  14. Erickson, M.D., PCB Properties, Uses, Occurrence, and Regulatory History, New York: Environ. Meas. Lab., US Dep. Energy, 2001.

  15. Basin Protection Action Plans, Yeşilırmak Basin, Gebze: TÜBİTAK Marmara Res. Center, 2010.

  16. Goerlitz, D. and Law, L., Note on removal of sulfur interferences from sediment extracts for pesticide analysis, Bull. Environ. Contam. Toxicol., 1971, vol. 6, no. 1, pp. 9–10.

    Article  CAS  Google Scholar 

  17. Burton, G.A., Sediment quality criteria in use around the world, Limnology, 2002, vol. 3, pp. 65–75.

    Article  CAS  Google Scholar 

  18. Goncharuk, V.V., Kovalenko, V.F., and Zlatskii, I.F., Comparative analysis of drinking water quality of different origin based on the results of integrated bioassay, J. Water Chem. Technol., 2012, vol. 34, no. 1, pp. 61–64.

    Article  Google Scholar 

  19. Goncharuk, V.V. and Kovalenko, V.F., Theoretical aspects of natural and drinking water biotesting, J. Water Chem. Technol., 2012, vol. 34, no. 2, pp. 103–106.

    Article  Google Scholar 

  20. Milyukin, M.V. and Goncharuk, V.V., Chemical monitoring of organic ecotoxicants in aqueous systems, J. Water Chem. Technol., 2019, vol. 41, no. 5, pp. 307–312.

    Article  Google Scholar 

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ACKNOWLEDGMENTS

This research Yeşilırmak Basin Pollution Point and Distributed Resource Management Project (project no. 115Y013 and Sub-Project no. 115Y025) under the Scientific and Technological Research Council of Turkey (TUBITAK) underfinanced and the master writer includes a part of his thesis at Environmental Engineering Department of Sakarya University. The authors would like to thank TUBITAK for supporting the project and the TUBITAK Marmara Research Center, Environmental and Cleaner Production Institute for providing the necessary laboratory support for the analysis.

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Correspondence to Burak Dinç.

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Burak Dinç, Avaz, G., Canlı, O. et al. Evaluation of Organochlorine Pesticides (OCPs) and Polychlorinated Biphenyls (PCBs) Concentrations in the River and Marine Sediments of Samsun Coastline. J. Water Chem. Technol. 43, 131–138 (2021). https://doi.org/10.3103/S1063455X21020041

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  • DOI: https://doi.org/10.3103/S1063455X21020041

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