Abstract
Optimal conditions for the microextraction concentration and spectrophotometric determination of iodine (I, V, VII) forms as ionic associates of triiodide anions with the cation of astrazone brilliant red 4G dye have been found. A new procedure for the spectrophotometric determination of the total iodine content in drinking and mineral waters with the detection limit of 8.9 μg/dm3 was developed and tested. This procedure is combined with microextraction concentration and meets the requirements of “green” chemistry.
Similar content being viewed by others
References
Kubasova, E.D. and Kubasov, R.V., Uspekhi Sovrem. Biologii, 2009, vol. 129, no. 2, pp. 181–190.
Lyakhnovich, N.A. and Gutikova, L.V., Mediko–Biol. Probl. Zhiznedeyatel’nosti, 2013, no. 2(10), pp. 13–23.
Abusuev, S.A., Yakhiyaev, M.A., Salikhov, Sh,K., and Kazanbieva, P.D., Probl. Zhen. Zdorov’ya, 2016 vol. 11, no. 1, pp. 26–31.
Babkina, O.A., Vest. VGU, Ser. Geologiya, 2010, no. 1, pp. 252–255.
Edmonds, J.S. and Morita, M., Pure Appl. Chem., 1998, vol. 70, no. 8, pp. 1567–1584.
Ananeva, V., Trokhymenko, O., Khvorov, M., and Golub, O., Visn. Kyiv. nats. un–tu im. Tarasa Shevchenka, Khimiya, 2007, issue 45, pp. 10–12.
Noskova, G.N., Tolmacheva, T.P., and Ivanova, E.E., Zavod. lab. “Diagnostika materialov”, 2004, vol. 70, no. 11, pp. 9–13.
Trokhymenko, A.Yu. and Zaporozhets, O.A., Dop. NANU, 2013, no. 2, pp. 125–132.
Trokhymenko, A. and Zaporozhets, O., Visn. Lviv. un–tu, Ser. khim., 2012, issue 53, pp. 185–191.
Zaruba, S., Bozoova, V., Vishnikin, A.B., et al., Microchem. J., 2017, vol. 132, pp. 59–68.
Sergeev, G.M., Shlyapunova, E.V., and Makeeva, I.V., Analitika i Kontrol’, 2006, vol. 10, no. 1, pp. 49–54.
Zui, O.V. and Goncharuk, V.V., Geterogenno–khemilyuminestsentnyi analiz v opredelenii nanogrammovykh kolichestv anionov (Heterogeneous Chemiluminescence Analysis in Determining the Nanogram Amounts of Anions), Kiev: Nauk. dumka, 2013.
Nayanova, E.V., Sergeev, G.M., and Elipasheva, E.V., Zhurn. Analit. Khimii, 2016, vol. 71, no. 3, pp. 261–265.
Nayanova, E.V., Elipasheva, E.V., and Sergeev, G.M., Ibid., 2015, vol. 70, no. 5, pp. 497–501.
El–Shahawi, M.S. and Al–Hashemi, F.A., Talanta, 1996, vol. 43, no. 12, pp. 2037–2043.
Drozd, A.V. and Tishakova, T.S., Visn. Kharkiv. nats. un–tu im. V.N. Karazina, 2010, issue 18(41), pp. 101–106.
Pogrebnyak, O.S., Visn. Cherkas. un–tu, Ser. “Khim. nauki”, 2014, no. 14(307), pp. 3–8.
Benvidi, A., Heidari, F., Tabaraki, R., and Mazloum–Ardakani, M., Zhurn. Analit. Khimii, 2012, vol. 67, no. 7, pp. 727–734.
Ni, Y. and Wang, Y., Microchem. J., 2007, vol. 86, no. 2, pp. 216–226.
Afkhami, A. and Zarei, A.R., Talanta, 2001, vol. 53, no. 4, pp. 815–821.
Ghasemi, J., Saaidpour, S., and Ensafi, A.A., Anal. Chim. Acta, 2004, vol. 508, no. 1, pp. 119–126.
Kormosh, Zh., Savchuk, T., Korolchuk, S., and Bazel, Ya., Electroanalysis, 2011, vol. 23, no. 9, pp. 2144–2147.
Li, T.–J., Lin, C.–Y., Balamurugan, A., et al., Anal. Chim. Acta, 2012, vol. 737, pp. 55–63.
Othman, A.M., Zhurn. Analit. Khimii, 2010, vol. 65, no. 11, pp. 1217–1223.
Ciftci, H. and Tamer, U., Anal. Chim. Acta, 2011, vol. 687, no. 2, pp. 137–140.
Salimi, A., Hallaj, R., Kavosi, B., and Hagighi, B., ibid., 2010, vol. 661, no. 1, pp. 28–34.
Drozd, A.V. and Tishakova, T.S., Visn. Kharkiv. nats. un–tu im. V.N. Karazina, 2008, issue 16(39), pp. 98–102.
Rodriguez, E.S., Setiawan, A.N., Pope, S., et al., Anal. Methods, 2016, no. 8, pp. 5587–5595.
Kolotilina, N.K. and Dolgonosov, A.M., Sorbts. i Khromatograf. Protsessy, 2009, vol. 9, no. 5, pp. 610–615.
Gupta, M., Jain, A., and Verma, K.K., Talanta, 2007, vol. 71, no. 3, pp. 1039–1046.
Bichsel, Y. and Von Gunten, U., Anal. Chem., 1999, vol. 71, no. 1, pp. 34–38.
DSTU ISO 10304–3:2003. Yakist vody. Vyznachennia rozchynenykh anioniv metodom ridynnogo ionnogo khromatografuvannia. Ch. 3. Vyznachannia khromatu, iodydu, sulfitu, tiotsianatu i tiosulfatu (Standard of Ukraine ISO 10304–3:2003. Quality of Water. Determination of Dissolved Anions by the Liquid Ion Chromatography Method. Part 3. Determination of Chromate, Iodide, Sulfite, Thiocyanide, and Thiosulfate), Kiev: Derzhspozhyvstandart Ukrainy, 2005.
DSTU ISO 4816:2007. Produkty kharchovi. Metody vyznachennia vmistu zagalnogo iodu (Food Products. Methods for Determination of the Total Iodine Content), Kiev: Derzhspozhyvstandart Ukrainy, 2009.
GOST 23268.16–78. Vody mineral’nye pit’evye lechebnye, lechebno–stolovye i prirodnye stolovye. Metody opredeleniya iodid–ionov (Mineral Waters: Drinking Medicinal, Medicinal–Table and Natural Table. Methods for Determination of Iodide Ions), Moscow: Gosstandart SSSR, 1978.
Doerffel, K., Statistik in der analytischen chemie, Leipzig: Wiley–VCH, 1990.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.S. Ryabukhina, Ya.R. Bazel, 2018, published in Khimiya i Tekhnologiya Vody, 2018, Vol. 40, No. 4, pp. 430–441.
About this article
Cite this article
Ryabukhina, T.S., Bazel, Y.R. Spectrophotometric Determination of the Total Iodine Content in Drinking and Mineral Waters Using the Microextraction Preconcentration. J. Water Chem. Technol. 40, 228–233 (2018). https://doi.org/10.3103/S1063455X18040082
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1063455X18040082