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A New Way of Preparing Nanosized Tysonite Phases

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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Nanopowders of tysonite solid solutions La1 − xBaxF3 − x (х = 0–0.07) are synthesized for the first time through the thermal decomposition of lanthanum and barium trifluoroacetates. Samples are characterized via electron microscopy, X-ray phase analysis, and impedance spectroscopy. Nanoparticles are found to be crystalline and have characteristic sizes of 20–75 nm. The ionic conductivity of solid solutions up to 300°C is determined by surface phenomena at the particle boundaries.

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ACKNOWLEDGMENTS

The work was performed using equipment of the shared resource centers of the Federal Research Center “Crystallography and Photonics” of the Russian Academy of Sciences and Russian Technological University MIREA.

Funding

This work was supported by the RF Ministry of Science and Higher Education as part of a State Task for the Federal Research Center “Crystallography and Photonics” of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia

    R. M. Zakalyukin, E. A. Levkevich, V. V. Grebenev & A. S. Kumskov

  2. Technological University MIREA, 119454, Moscow, Russia

    R. M. Zakalyukin & E. A. Levkevich

  3. Moscow State University, 119991, Moscow, Russia

    T. Yu. Glazunova & M. E. Buzoverov

Authors
  1. R. M. Zakalyukin
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  2. E. A. Levkevich
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  3. V. V. Grebenev
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  4. T. Yu. Glazunova
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  5. M. E. Buzoverov
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  6. A. S. Kumskov
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Corresponding author

Correspondence to R. M. Zakalyukin.

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The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Domoroshchina

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Zakalyukin, R.M., Levkevich, E.A., Grebenev, V.V. et al. A New Way of Preparing Nanosized Tysonite Phases. Bull. Russ. Acad. Sci. Phys. 87, 1417–1420 (2023). https://doi.org/10.3103/S1062873823703410

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  • DOI: https://doi.org/10.3103/S1062873823703410

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