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Features of Cl K-edge XANES Spectra of Transition Metal Complexes {MCl6}n− (M = Rh, Pd, Re, Os, Ir, Pt)

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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {MCl6}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes.

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ACKNOWLEDGMENTS

This work was performed on equipment at the Siberian Center of Synchrotron and Terahertz Radiation based on the VEPP-4–VEPP-2000 Complex at the Budker Institute of Nuclear Physics. Our quantum chemical calculations were made using the resources of the Siberian Supercomputer Center at the Institute of Computational Mathematics and Mathematical Geophysics. The authors are grateful to the RF Ministry of Science and Higher Education.

Funding

This work was supported by the Russian Science Foundationas, project no. 22-22-00683.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. D. Fedorenko, I. P. Asanov, T. I. Asanova & D. B. Vasil’chenko

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. D. Nikolenko

  3. Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. D. Nikolenko, P. A. Piminov & K. Yu. Karyukina

  4. SKIF Synchrotron Radiation Facility, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630559, Koltsovo, Russia

    A. D. Nikolenko, P. A. Piminov & K. Yu. Karyukina

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  1. A. D. Fedorenko
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  2. I. P. Asanov
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Correspondence to A. D. Fedorenko.

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Translated by E. Boltukhina

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Fedorenko, A.D., Asanov, I.P., Asanova, T.I. et al. Features of Cl K-edge XANES Spectra of Transition Metal Complexes {MCl6}n− (M = Rh, Pd, Re, Os, Ir, Pt). Bull. Russ. Acad. Sci. Phys. 87, 654–661 (2023). https://doi.org/10.3103/S1062873822701805

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  • DOI: https://doi.org/10.3103/S1062873822701805

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