Abstract
A way of estimating the average number of molecules in the nuclei of a condensing liquid phase is proposed. The procedure is based on statistical calculations of fluctuations in the density of molecules in a medium. The average number of molecules in the nuclei of water droplets of critical size is calculated in the temperature range of 273 to 373 K using data from molecular dynamics modeling.
Similar content being viewed by others
REFERENCES
Gibbs, J.W., The Scientific Papers, vol. 1: Thermodynamics, New York: Longmans, 1906.
Volmer, M., Kinetik der Phasenbildung (Kinetics of Phase Formation), Dresden: Steinkopff, 1939.
Pavlov, S.V., Bull. Russ. Acad. Sci.: Phys., 2019, vol. 83, no. 9, p. 1051.
Aleshin, A.N., Bull. Russ. Acad. Sci.: Phys., 2019, vol. 83, no. 10, p. 1195.
Physical Metallurgy, Cahn, R.W. and Haasen, P., Eds., Amsterdam: North-Holland, 1983, 3rd ed.
Murashkevich, A.N. and Zharskii, I.M., Teoriya i metody vyrashchivaniya monokristallov (Theory and Methods of Growing Single Crystals), Minsk: Beloruss. Gos. Tekh. Univ., 2010.
Shevkunov, S.V., High Temp., 2012, vol. 50, no. 2, p. 255.
Shebzukhova, M.A., Shebzukhov, A.A., Bzhikhatlov, K.C., and Lyuyev, V.K., Bull. Russ. Acad. Sci.: Phys., 2019, vol. 83, no. 6, p. 749.
Akhmatov, Z.A., Khokonov, A.Kh., and Khoko-nov, M.Kh., Bull. Russ. Acad. Sci.: Phys., 2016, vol. 80, no. 11, p. 1358.
Malenkov, G.G., J. Phys.: Condens. Matter, 2009, vol. 21, 283101.
Shevkunov, S.V., J. Exp. Theor. Phys., 2009, vol. 108, p. 447.
Shevkunov, S.V., High Temp., 2013, vol. 51, no. 1, p. 79.
Galimzyanov, B.N. and Mokshin, A.V., Colloid J., 2017, vol. 79, no. 1, p. 26.
Mokshin, A.V. and Galimzyanov, B.N., Russ. J. Phys. Chem. B, 2017, vol. 11, no. 3, p. 473.
Mokshin, A.V. and Galimzyanov, B.N., J. Chem. Phys., 2014, vol. 140, 024104.
Mokshin, A.V., Galimzyanov, B.N., and Barrat, J.L., Phys. Rev. E, 2013, vol. 87, 062307.
Landau, L.D. and Lifshits, E.M., Statisticheskaya fizika (Statistical Physics), Moscow: Nauka, 1976.
Mokshin, A.V. and Galimzyanov, B.N., J. Phys. Chem. B, 2012, vol. 116, no. 39, 11959.
Moore, E.B. and Molinero, V., Nature, 2011, vol. 479, p. 506.
Molinero, V. and Moore, E.B., J. Phys. Chem. B, 2009, vol. 113, p. 4008.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The author declares that he has no conflicts of interest.
Additional information
Translated by T. Sokolova
About this article
Cite this article
Syrovatko, Y.V. Statistical Way of Calculating the Average Number of Molecules of Critical Nuclei in Homogeneous Nucleation. Bull. Russ. Acad. Sci. Phys. 86, 150–153 (2022). https://doi.org/10.3103/S1062873822020290
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1062873822020290