An investigation is performed of the mechanism behind the peeling of an adsorbed flexible macromolecule from a surface under the action of a strong mean field formed by intermolecular interactions with other chains. The kinetic equation for the order parameter and its solution are obtained. The effect of a critical slowdown (in a sharp increase in periods of relaxation time at the critical point) is observed for finite chains.
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This work was supported by the Russian Foundation for Basic Research, project no. 19-42-350001-r_a.
The authors declare there were no conflicts of interest.
Translated by P. Vlasov
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Maximov, A.V., Maksimova, O.G. & Osipov, S.V. Kinetics of the Processes of Orientation and Adsorption in Polymer Adhesive Materials. Bull. Russ. Acad. Sci. Phys. 84, 1576–1578 (2020). https://doi.org/10.3103/S1062873820120254