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Phase Transformations in C60 Fullerene with Iron and Aluminum at High Pressures and Temperatures

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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

A neutron diffraction study of the effect metal additives have on phase transformations at high temperatures and pressures in C60 fullerene in the amorphous state and in the form of a face-centered cubic structure. It is found that introducing metals into crystalline C60 fullerene considerably raises the temperature of its transformation into disoriented graphite. No such effect is observed in amorphous fullerene, since that of metal additives is compensated for by a reduction in the stability of fullerene due to amorphization produced by preliminary mechanical activation.

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Funding

This work was supported by the Russian Foundation for Basic Research, project no. 18-32-00262-mol_а (“Preparing a Metal–Carbon Mixture for Neutron Diffraction Studies”). P. A. Borisova and M. S. Blanter thank the Russian Foundation for Basic Research, project no. 19-02-00162-а (“Diffraction Studies”). V. V. Brazhkin acknowledges the support of the Russian Science Foundation, project no. 19-12-00111 (“Experiments at High Pressures”).

Author information

Authors and Affiliations

  1. National Research Center “Kurchatov Institute, 123182, Moscow, Russia

    P. A. Borisova

  2. Russian Technological University (MIREA), 119454, Moscow, Russia

    M. S. Blanter

  3. Institute for High Pressure Physics, Russian Academy of Sciences, 142190, Troitsk, Moscow oblast, Russia

    V. V. Brazhkin & V. P. Filonenko

Authors
  1. P. A. Borisova
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  2. M. S. Blanter
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  3. V. V. Brazhkin
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  4. V. P. Filonenko
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Corresponding author

Correspondence to M. S. Blanter.

Additional information

Translated by I. Obrezanova

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Borisova, P.A., Blanter, M.S., Brazhkin, V.V. et al. Phase Transformations in C60 Fullerene with Iron and Aluminum at High Pressures and Temperatures. Bull. Russ. Acad. Sci. Phys. 84, 851–856 (2020). https://doi.org/10.3103/S1062873820070072

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  • DOI: https://doi.org/10.3103/S1062873820070072

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