Abstract
The processes of low-frequency and infra-low-frequency polarization in solid solutions (1 ‒ х) Ba0.95Pb0.05TiO3 + хСо2О3 (x = 0; 0.1; 0.3; 0.5; 1; 2 wt %) prepared using conventional ceramic technology are studied at a wide range of temperatures. It is shown that adding cobalt (Co) substantially alters the thermal anomalies of the dielectric properties of samples and shifts the temperature of the ferroelectric phase transition. Data on the dielectric response in the samples are compared to the behavior of the elastic properties of ceramics at different contents of impurities. It is established that the disordering of the ceramic structure increases as Co is added. The domain component, which determines the main contribution from low-frequency polarization, is greatly reduced, and the nature of the dielectric non-linearity of the material is determined by inducing a macroscopic polar state from the microscopic state (the accumulation of polar nanodomains and phase boundaries).
Similar content being viewed by others
REFERENCES
Briančin, J. and Medvecký, L’, J. Mater. Sci. Lett., 2002, vol. 21, p. 55.
Lebedev, A.I., Sluchinskaya, I.A., Erko, A., Veligzhanin, A.A., and Chernyshov, A.A., Phys. Solid State, 2009, vol. 51, no. 5, p. 991.
Li, W., Qi, J., Wang, Y., et al., Mater. Lett., 2002, vol. 57, p. 1.
Li, Q., Qi, J., Wang, Y., et al., J. Eur. Ceram. Soc., 2001, vol. 21, p. 2217.
Markiewicz, E., Bujakiewicz-Koronska, R., Majda, D., et al., J. Electroceram., 2014, vol. 32, p. 92.
Cheng, B.L., Gabbay, M., Duffy, W., Jr., et al., J. Mater. Sci., 1996, vol. 31, p. 4951.
Bujakiewicz-Koronska, R., Markiewicz, E., Nalecz, D.M., et al., J. Ceram. Int., 2014, vol. 41, p. 3983.
Nozdrev, V.F. and Fedorishchenko, N.V., Molekulyarnaya akustika (Molecular Acoustics), Moscow: Vysshaya Shkola, 1974.
Colla, E.V., Furman, E.L., Gupta, S.M., et al., J. Appl. Phys., 1999, vol. 85, no. 3, p. 1693.
Bormanis, K., Burkhanov, A.I., Tumanov, I.E., et al., Ferroelectrics, 2013, vol. 442, p. 137.
Poplavko, Yu.M., Pereverzeva, L.P., and Raevskii, I.P., Fizika aktivnykh dielektrikov: uchebnoe posobie (The Physics of Active Dielectrics: Study Guide), Rostov-on-Don: Yuzhn. Fed. Univ., 2009.
Viehland, D., Kim, M.Y., Xu, Z., and Li, J.-F., Proc. Int. Conf. “Electroceramics V,” Aveiro, 1996, vol. 1, p. 97.
Burkhanov, A.I., Shilnikov, A.V., and Sternberg, A., Ferroelectrics, 1989, vol. 90, p. 39.
Burkhanov, A.I., Shilnikov, A.V., and Dimza, V., Ferroelectrics, 1992, vol. 131, p. 267.
Ke, S.M., Huang, H.T., Fan, H.Q., et al., Appl. Phys. Lett., 2012, vol. 101, p. 082901.
Burkhanov, A.I. and Shil’nikov, A.V., Ferroelectrics, 2004, vol. 299, p. 153.
Colla, E.V., Sullivan, K., and Weissman, M.B., J. Appl. Phys., 2016, vol. 119, no. 1, p. 014109.
Smirnova, E., Sotnikov, A., Zaitseva, N., et al., Phys. Lett. A, 2010, vol. 374, p. 4256.
Balashova, E.V., Lemanov, V.V., Albers, J., and Klöpperpieper, A., Phys. Solid State, 1998, vol. 40, no. 6, p. 995.
Bokov, A. and Ye, Z.-G., J. Adv. Dielectr., 2012, vol. 2, no. 2, p. 1241010.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Translated by I. Obrezanova
About this article
Cite this article
Burkhanov, A.I., Dikov, R.V., Bormanis, K. et al. Processes of Low-Frequency and Infra-Low-Frequency Polarization in Ferroelectric Ceramics (1 – x)Ba0.95Pb0.05TiO3 + xCo2O3. Bull. Russ. Acad. Sci. Phys. 83, 1094–1099 (2019). https://doi.org/10.3103/S106287381909003X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S106287381909003X