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Ionic polymerization in an electric field and consequences of the spatial redistribution of growing macroions and counterions

  • Proceedings of the 23rd International Scientific Conference “Relaxation Phenomena in Solids,” Dedicated to the Centenary of the Birth of V.S. Postnikov
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Reaction mixtures in which polymerization processes proceed are investigated both in an electric field and under classical conditions. The observed kinetic effects are explained using a model concept of the primary contribution to the revealed field effects from the dissociation of ion pairs due to the spatial redistribution of ions. This model may be applied to both cationic and anionic polymerization processes.

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Author information

Authors and Affiliations

  1. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, 117393, Russia

    A. T. Ponomarenko & V. G. Shevchenko

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. R. Tameev

Authors
  1. A. T. Ponomarenko
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  2. A. R. Tameev
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  3. V. G. Shevchenko
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Corresponding author

Correspondence to A. T. Ponomarenko.

Additional information

Original Russian Text © A.T. Ponomarenko, A.R. Tameev, V.G. Shevchenko, 2016, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2016, Vol. 80, No. 9, pp. 1238–1240.

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Ponomarenko, A.T., Tameev, A.R. & Shevchenko, V.G. Ionic polymerization in an electric field and consequences of the spatial redistribution of growing macroions and counterions. Bull. Russ. Acad. Sci. Phys. 80, 1131–1133 (2016). https://doi.org/10.3103/S1062873816090380

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  • DOI: https://doi.org/10.3103/S1062873816090380

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