Skip to main content
Log in

Diamondlike nanocomposite a-C:H:Cr Coatings: Structure, mechanical, and tribological properties

  • Proceedings of the International Symposium “Physics of Crystals 2013”
  • Published:
Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

The results from a comprehensive investigation of the structure, phase and chemical composition, microhardness, and nanomechanical and tribological properties of chromium-doped coatings of hydrogenised amorphous carbon a-C:H:Cr are presented. The coatings are deposited via reactive magnetron sputtering in an Ar + C2H2 + N2 gas mixture at various volume concentrations of nitrogen and acetylene. It is found that the carbon in the coatings is formed as disordered mixtures of domains with tetrahedral (sp 3) and hexagonal (sp 2) carbon coordinations. In addition, the doping metal in the coating consists of nanosized inclusions of metallic chromium and its carbide and nitride phases. Additional nitrogen doping resulting in the formation of chromium nitride is shown to improve the micromechanical and tribological properties of the obtained coatings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Nevolin, V.N., Fominski, V.Yu., Gnedovets, A.G., and Romanov, R.I., Tech. Phys., 2009, vol. 54, no. 1, p. 117.

    Article  Google Scholar 

  2. Shtansky, D.V., Sheveiko, A.N., Petrzhik, M.I., et al., Surf. Coat. Technol., 2005, vol. 200, nos. 1–4, special issue, p. 208.

    Article  Google Scholar 

  3. Semenov, A.P., J. Frict. Wear, 2009, vol. 30, no. 1, p. 62.

    Article  Google Scholar 

  4. Semenov, A.P. and Khrushchov, M.M., J. Frict. Wear, 2010, vol. 31, no. 2, p. 142.

    Article  Google Scholar 

  5. Minazawa, H., Sakai, U., Kashiwakura, Y., and Ueno, M., Proc. Int. Tribology Congress, Yokohama: Jpn. Soc. Tribol., 1995, p. 120.

    Google Scholar 

  6. Miyake, S. and Kaneko, R., Proc. 1st Int. Conf. Applications of Diamond Films and Related Materials, Tzeng, Y., et al., Eds., New York: Elsevier, 1991, p. 691.

  7. Miyake, S., Proc. Int. Tribology Congress, Yokohama: Jpn. Soc. Tribol., 1995, p. 86.

    Google Scholar 

  8. Miyake, S., Kaneko, R., Kikuya, Y., and Sugimoto, I., J. Tribol., 1991, vol. 113, no. 2, p. 384.

    Article  Google Scholar 

  9. Klaffke, D. and Scopp, A., Surf. Coat. Technol., 1998, vol. 98, nos. 1–3, p. 953.

    Article  Google Scholar 

  10. Wahl, K.J., Dunn, D.N., and Singer, I.L., Wear, 2000, vol. 237, p. 1.

    Article  Google Scholar 

  11. Wei, R., Wilbur, P.J., and Kustas, F.M., J. Tribol., 1992, vol. 114, no. 2, p. 298.

    Article  Google Scholar 

  12. Corbella, C., Vives, M., Pinyol, A., et al., Surf. Coat. Technol., 2004, vols. 177–178, p. 409.

    Article  Google Scholar 

  13. Ouyang, J.-H., Sasaki, S., Murakami, T., et al., Wear, 2009, vol. 266, p. 96.

    Article  Google Scholar 

  14. Meng, W.J. and Gillispie, B.A., J. Appl. Phys., 1998, vol. 84, no. 8, p. 4314.

    Article  ADS  Google Scholar 

  15. Meng, W.J., Tittsworth, R.C., Jiang, J.C., et al., J. Appl. Phys., 2000, vol. 88, no. 5, p. 2415.

    Article  ADS  Google Scholar 

  16. Gassner, G., Patscheider, J., Mayrhofer, P.H., et al., J. Vac. Sci. Technol. B, 2006, vol. 24, no. 4, p. 1837.

    Article  Google Scholar 

  17. Gassner, G., Mayrhofer, P.H., Mitterer, C., and Kiefer, J., Surf. Coat. Technol., 2005, vol. 200, p. 1147.

    Article  Google Scholar 

  18. Hovsepian, P.E., Kok, Y.N., Ehiasarian, A.P., et al., Surf. Coat. Technol., 2005, vol. 200, p. 1572.

    Article  Google Scholar 

  19. Zhou, Z., Ross, I.M., and Ma, L., et àl., Wear, 2011, vol. 271, p. 2150.

    Article  Google Scholar 

  20. Paul, A., Lim, J., Choi, K., and Lee, C., Mat. Sci. Eng. A, 2002, vol. 332, p. 123.

    Article  Google Scholar 

  21. Atamanov, M.V., Dubravina, A.A., Levin, I.S., et al., Probl. Mashinostr. Avtomatiz., 2013, no. 3, p. 102.

    Google Scholar 

  22. Khrushchov, M.M. and Sveshnikov, S.V., Nanoinzheneriya, 2012, no. 8, p. 37.

    Google Scholar 

  23. Khrushchov, M.M., Levin, I.S., and Dubravina, A.A., Trudy 11-i Mezhd. konf. “Plenki i pokrytiya-2013” (Proc. 11th Int. Conf. “Films and Coatings-2013”), St. Petersburg: St. Petersburg State Polytechnical Univ., 2013, p. 290.

    Google Scholar 

  24. Guinier, A., Theorie et technique de la radiocrystallographie, Paris: Dunod, 1956.

    Google Scholar 

  25. Petrzhik, M.I. and Levashov, E.A., Crystallogr. Rep., 2007, vol. 52, no. 6, p. 966.

    Article  ADS  Google Scholar 

  26. Kombalov, V.S., Metody i sredstva ispytanii na trenie i iznos konstruktsionnykh i smazochnykh materialov: Spravochnik (Methods and Means for Friction and Wear Tests for Structural and Lubricative Materials. Handbook), Frolov, K.V. and Marchenko, E.A., Eds., Moscow: Mashinostroenie, 2008.

  27. Metodika raschetnoi otsenki iznosostoikosti poverkhnostei treniya detalei mashin (The Method to Estimate Wear Resistance of Friction Surfaces of Machines Elements), Moscow: Izd. Standartov, 1979.

  28. Robertson, J., Mat. Sci. Eng. R: Rep., 2002, vol. 37, p. 129.

    Article  Google Scholar 

  29. Khrushchov, M.M., Marchenko, E.A., and Semenov, A.P., Izv. Samarsk. Nauch. Tsentra Ross. Akad. Nauk, 2011, vol. 13, no. 4(3), p. 1248.

    Google Scholar 

  30. Khrushchov, M.M. and Semenov, A.P., J. Frict. Wear, 2013, vol. 34, no. 1, p. 57.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. M. Khrushchov.

Additional information

Original Russian Text © M.M. Khrushchov, M.V. Atamanov, E.A. Marchenko, M.I. Petrzhik, I.S. Levin, 2014, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2014, Vol. 78, No. 10, pp. 1257–1265.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khrushchov, M.M., Atamanov, M.V., Marchenko, E.A. et al. Diamondlike nanocomposite a-C:H:Cr Coatings: Structure, mechanical, and tribological properties. Bull. Russ. Acad. Sci. Phys. 78, 1007–1014 (2014). https://doi.org/10.3103/S1062873814100104

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1062873814100104

Keywords

Navigation