Skip to main content
  • Proceedings of the XVII Russian Symposium on Scanning Electron Microscopy and Analytical Methods of Investigation Applied for Solid States Physics
  • Published:

Studying the structure of nanocomposites obtained via the chemical decomposition of metal siloxanes in polymer matrices

Bulletin of the Russian Academy of Sciences: Physics volume 76, pages 1005–1008 (2012)Cite this article

Abstract

The structure of polymer nanocomposites containing CuS clusters is studied by atom force (AFM), scanning (SEM), and transmission (TEM) electron microscopy, and by narrow-angle X-ray scattering (SAXS). The results point to the existence of spherical nanoparticles of 3–50 nm in diameter and larger agglomerates of sizes 1–5 μm in the studied nanocomposites (NCs). The morphology of NCs depends on the conditions of synthesis.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. Handbook on Nanostructured Materials and Nanotechnology, Nalwa, M.S.N.Y., Ed., Acad. Press, 1994, vols. 1–5.

  2. Sapurina, I.Yu. and Stejskal, J., Usp. Khim., 2010, vol. 79, no. 12, p. 1218.

    Google Scholar 

  3. Sun, T. and Gare, S., Adv. Mater., 2002, vol. 14, p. 128.

    Article  Google Scholar 

  4. Xu, Q., Leng, J., Lu, G., et al., React. Funct. Polym., 2010, vol. 70, no. 9, p. 663.

    Article  Google Scholar 

  5. Bober, P., Steiscal, J., Tarchova, M., et al., React. Funct. Polym., 2010, vol. 70, no. 9, p. 656.

    Article  Google Scholar 

  6. Volkova, T.V., Pashkova, O.H., Filatova, A.G., Zubavichus, Ya.V., Gumargalieva, K.Z., and Vygodskii, Ya.S., Bull. Russ. Acad. Sci. Phys., 2007, vol. 71, no. 10, p. 1477.

    Article  Google Scholar 

  7. Wan, W.-M. and Pan, C.Y., Macromolec., 2007, vol. 40, p. 8899.

    ADS  Google Scholar 

  8. Tran, B., Li, D., and Kaner, R., Adv. Mater., 2009, vol. 21, nos. 14–15, p. 1487.

    Article  Google Scholar 

  9. Chen, Ch.-L. and Rosi, N.L., Angew. Chem., 2010, vol. 49, no. 11, p. 1924.

    Article  Google Scholar 

  10. Burda, C., Chem, X.B., Narayanan, R., and Saged, El., Angew. Chem. Rev., 2005, vol. 105, p. 1025.

    Google Scholar 

  11. Daniel, M.C. and Astric, D., Angew. Chem. Rev., 2004, vol. 104, p. 293.

    Google Scholar 

  12. Subhramannia, M. and Pillai, V.K., J. Mater. Chem., 2008, vol. 18, p. 5857.

    Article  Google Scholar 

  13. Liu, A., Xie, T., and Yong, G., Macromol. Chem. Phys., 2006, vol. 206, p. 2180.

    Article  Google Scholar 

  14. Makarova, L.I., Filimonova, L.V., Dubrovina, L.V., et al., Vysokomol. Soedin., Ser. B, 2010, vol. 52, no. 6, p. 1050.

    Google Scholar 

  15. Chernyshov, A.A., Veligzhanin, A.A., and Zubavichus, Y.V., Nucl. Instrum. Methods. Phys. Res. A, 2009, vol. 603, p. 95.

    Article  ADS  Google Scholar 

  16. Konarev, P.V., Volkov, V.V., and Sokolova, A.V., J. Appl. Crystallogr., 2003, vol. 36, p. 1277.

    Article  Google Scholar 

  17. Beaucage, G., J. Appl. Crystallogr., 1996, vol. 29, p. 134.

    Article  Google Scholar 

  18. Berkov, A., Vremya Novatsii, 2006, issue 3, nos. 5–6, p. 28.

Download references

Author information

Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    B. G. Zavin, N. V. Cherkun, N. V. Sergienko, A. A. Anisimov, L. V. Filimonova, O. V. Sinitsyna, I. V. Yaminskii, O. A. Belyakova, Ya. V. Zubavichus, I. O. Volkov & E. M. Belavtseva

  2. Institute of Nuclear Fusion, Kurchatov Institute Russian Research Center, Moscow, 123182, Russia

    O. A. Belyakova & Ya. V. Zubavichus

  3. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    A. G. Filatova

Authors
  1. B. G. Zavin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Cherkun
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Sergienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Anisimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. V. Filimonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. O. V. Sinitsyna
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. I. V. Yaminskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. G. Filatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. O. A. Belyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. Ya. V. Zubavichus
    View author publications

    You can also search for this author in PubMed Google Scholar

  11. I. O. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  12. E. M. Belavtseva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. G. Zavin.

Additional information

Original Russian Text © B.G. Zavin, N.V. Cherkun, N.V. Sergienko, A.A. Anisimov, L.V. Filimonova, O.V. Sinitsyna, I.V. Yaminskii, A.G. Filatova, O.A. Belyakova, Ya.V. Zubavichus, I.O. Volkov, E.M. Belavtseva, 2012, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2012, Vol. 76, No. 9, pp. 1118–1121.

About this article

Cite this article

Zavin, B.G., Cherkun, N.V., Sergienko, N.V. et al. Studying the structure of nanocomposites obtained via the chemical decomposition of metal siloxanes in polymer matrices. Bull. Russ. Acad. Sci. Phys. 76, 1005–1008 (2012). https://doi.org/10.3103/S1062873812090250

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1062873812090250

Keywords

  • Atom Force Microscopy
  • Polymer Nanocomposites
  • Dimethyl Siloxane
  • Copper Sulfide
  • Large Agglomerate