Abstract
Heterogeneous equilibria in the Gd-Mn-O system at low oxygen pressures are studied by the static method in combination with X-ray diffraction analysis of quenched solid phases. The sequence of phase equilibria upon the dissociation of GdMn2O5 and GdMnO3 is determined. A fragment of an isothermal section of the phase equilibrium diagram of Gd-Mn-O in composition-oxygen pressure coordinates at 1173 K is constructed.
Similar content being viewed by others
References
Yankin, A.M., Balakirev, V.F., Vedmid’, L.B., and Fedorova, O.M., Zh. Fiz. Khim., 2003, vol. 77, no. 11, p. 2108.
Portnoi, K.I. and Timofeeva, N.I., Kislorodnye soedineniya redkozemel’nykh elementov (Oxygen Compounds of Rare-Earth Materials), Moscow: Metallurgiya, 1986.
Tret’yakov, Yu.D., Khimiya nestekhiometricheskikh okislov (Chemistry of Nonstoichiometric Oxides), Moscow: MGU, 1974.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.B. Vedmid’, A.M. Yankin, O.M. Fedorova, S.Kh. Estemirova, V.F. Balakirev, 2012, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2012, Vol. 76, No. 7, pp. 840–842.
About this article
Cite this article
Vedmid’, L.B., Yankin, A.M., Fedorova, O.M. et al. Sequence of phase transformations in the Gd-Mn-O system. Bull. Russ. Acad. Sci. Phys. 76, 751–753 (2012). https://doi.org/10.3103/S1062873812070386
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1062873812070386