Skip to main content
SpringerLink
Log in

Studying the local structural features of Zn2 − 2x Cd2x V2O7 by NMR and IR spectroscopy

  • Proceedings of the International Symposium “Ordering in Minerals and Alloys” (OMA-14)
  • Published:
Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

The local structure of pyroanion groups in the incommensurate phase X-Zn2 − 2x Cd2x V2O7 (0.11 ≤ x ≤ 0.48) with a zero volumetric expansion coefficient is studied. Comparative analysis of IR and NMR spectra of samples in the X-phase and of ZnCdV2O7 revealed that vanadium atoms have a similar structural and an identical charge environment. Additional bands in the IR spectra of the X-phase in the range of end vibrations are due to the influence of the cation sublattice.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Krasnenko, T.I., Zolotukhina, L.V., and Andrianova, L.V., Russ. J. Inorg. Chem., 2000, vol. 45, no. 3, p. 323.

    Google Scholar 

  2. Krasnenko, T.I., Zolotukhina, L.V., and Andrianova, L.V., Neorgan. Mater., 2000, vol. 35, no. 10, p. 1226.

    Google Scholar 

  3. Calvo, C., Canad. J. Chem., 1973, no. 51, p. 1004.

  4. Krasnenko, T.I., Zubkov, V.G., Tyutyunnik, A.P., et al., Kristallografiya, 2002, vol. 48, no. 1, p. 35.

    ADS  Google Scholar 

  5. Drown, I.I. and Hummel, F.A., Trans. Brit. Ceram. Soc., 1961, vol. 64, no. 8, p. 387.

    Google Scholar 

  6. Rotermel’, M.V., Krasnenko, T.I., Zakharov, R.G., et al., Russ. J. Inorg. Chem., 2004, vol. 49, no. 11, p. 1753.

    Google Scholar 

  7. Krasnenko, T.I. and Rotermel’, M.V., Russ. J. Inorg. Chem., 2010, vol. 54, no. 3, p. 430.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620219, Russia

    T. I. Krasnenko, N. A. Zhuravlev & L. A. Perelyaeva

Authors
  1. T. I. Krasnenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Zhuravlev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. A. Perelyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. I. Krasnenko.

Additional information

Original Russian Text © T.I. Krasnenko, N.A. Zhuravlev, L.A. Perelyaeva, 2012, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2012, Vol. 76, No. 3, pp. 421–424.

About this article

Cite this article

Krasnenko, T.I., Zhuravlev, N.A. & Perelyaeva, L.A. Studying the local structural features of Zn2 − 2x Cd2x V2O7 by NMR and IR spectroscopy. Bull. Russ. Acad. Sci. Phys. 76, 371–373 (2012). https://doi.org/10.3103/S1062873812030173

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1062873812030173

Keywords

Search

Navigation