Abstract
The magnetic susceptibility of Sr2MnSbO6 solid solutions in a Sr2AlSbO6 diamagnetic diluent is investigated. Variation in the magnetic characteristics with temperature and the solution concentration indicates the coexistence of two spin states of manganese atoms: low-spin and high-spin. The possibility of spin transitions is due to temperature-dependent local distortions in the crystal structure of the solutions.
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Brach, B.Ya., Bobrysheva, N.P., Rakitin, Yu.V., and Ryabkov, Yu.I., Vestn. Leningr. Univ., 1982, no. 16, p. 99.
Faik, A., Gateschki, M., Igartua, J.M., et al., J. Solid State Chem., 2008, vol. 181, p. 1759.
Lufaso, M., Woodward, P.M., and Goldberger, J., J. Solid State Chem., 2004, vol. 177, p. 1651.
Retuerto, M., Alonso, J.A., Garcia-Hernandez, M., and Martinez-Lope, M.J., Solid State Commun., 2006, vol. 139, p. 19.
Bobrysheva, N.P., Kozin, A.O., and Panichev, N.A., in Sbornik. Khimiya tverdogo tela (Collection of Works. Chemistry of Solids), Available from: Cherkassy: ONIITEKhIM, no. 870 XII D-80, p. 152.
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Original Russian Text © N.P. Bobrysheva, A.O. Kozin, A.A. Selyutin, 2012, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2012, Vol. 76, No. 3, pp. 408–410.
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Bobrysheva, N.P., Kozin, A.O. & Selyutin, A.A. The spin state of manganese atoms in Sr2MnSbO6 complex oxides. Bull. Russ. Acad. Sci. Phys. 76, 359–361 (2012). https://doi.org/10.3103/S1062873812030069
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DOI: https://doi.org/10.3103/S1062873812030069