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Synthesis and properties of high-pressure phase [Er x Cu3](V4)O12

  • Proceedings of the International Symposium “Order, Disorder, and Properties of Oxides” (ODPO-11)
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

A new perovskite-like compound Er0.73Cu3V4O12 (space group Im \( \bar 3 \), Z = 2, a = 7.266 Å) has been synthesized barothermally (P = 8.0 GPa, t = 1000°C). Its electrical and magnetic properties have been studied. It is found that the temperature dependence of the electrical conductivity (in the range 78–300 K) has of semiconductor type. The behavior of the impedance and admittance has been analyzed at 290 K and frequencies of 200 Hz to 200 kHz under atmospheric pressure and at high (15–42 GPa) pressures.

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Correspondence to N. I. Kadyrova.

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Original Russian Text © N.I. Kadyrova, N.V. Melnikova, I.S. Ustinova, A.N. Babushkin, A.V. Korolev, Yu.G. Zaynulin, 2009, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2009, Vol. 73, No. 11, pp. 1639–1641.

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Kadyrova, N.I., Melnikova, N.V., Ustinova, I.S. et al. Synthesis and properties of high-pressure phase [Er x Cu3](V4)O12 . Bull. Russ. Acad. Sci. Phys. 73, 1539–1541 (2009). https://doi.org/10.3103/S1062873809110288

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  • DOI: https://doi.org/10.3103/S1062873809110288

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