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Character of ordering of nickel atoms in LiMO2

  • Proceedings of the International Symposium “Orderings in Minerals and Alloys” (OMA-11)
  • Published:
Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

The state of nickel atoms in the solid solutions based on LiScO2 and LiGaO2 has been investigated. It is established that the anomalies of magnetic characteristics can be explained by only the presence of stable clusters, containing Ni(III) atoms in two (high and low) spin states. The cluster stability is independent of the crystallographic environment of the nickel atoms replacing the scandium and gallium ones.

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References

  1. Selyutin, A.A., Bobrysheva, N.P., Chezhina, N., et al., Zh. Obshch. Khim., 2007, vol. 77, no. 10, p. 1608.

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  2. Rakitin, Yu.V. and Kalinnikov, V.T., Sovremennaya magnetokhimiya (Modern Magnetochemistry), St. Petersburg: Nauka, 1992.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, 199034, Russia

    A. A. Selyutin & N. P. Bobrysheva

Authors
  1. A. A. Selyutin
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  2. N. P. Bobrysheva
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Correspondence to A. A. Selyutin.

Additional information

Original Russian Text © A.A. Selyutin, N.P. Bobrysheva, 2009, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2009, Vol. 73, No. 8, pp. 1132–1134.

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Selyutin, A.A., Bobrysheva, N.P. Character of ordering of nickel atoms in LiMO2 . Bull. Russ. Acad. Sci. Phys. 73, 1071–1072 (2009). https://doi.org/10.3103/S1062873809080164

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  • DOI: https://doi.org/10.3103/S1062873809080164

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