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Relation of X-ray photoelectron spectra with the magnetic properties of high-spin pivalic MnII and FeII

  • Proceedings of the International Symposium “Low-Dimensional Systems and Surfaces” (LDS-2008), Proceedings of the International Symposium “Orderings in Minerals and Alloys” (OMA-11) and Proceedings of the International Symposium “Order, Disorder,
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Trimethylacetate complexes of manganese and iron of identical structure have been studied by X-ray photoelectron spectroscopy. The increase in both spin-orbit splitting and difference in the binding energy of satellite and M 2p 3/2 line with an increase in magnetic moment is observed for the manganese complexes with oxygen and partially nitrogen environment of metal atoms. A reverse dependence is found for iron complexes. It is suggested that binuclear and hexanuclear manganese complexes show antiferromagnetic interactions, while similar iron complexes exhibit ferromagnetic interactions.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    T. M. Ivanova, A. A. Sidorov, M. A. Kiskin, V. M. Novotortsev & I. L. Eremenko

  2. Chemistry Department, St. Petersburg State University, St. Petersburg, 198904, Russia

    A. V. Shchukarev

Authors
  1. T. M. Ivanova
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  2. A. V. Shchukarev
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  3. A. A. Sidorov
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  4. M. A. Kiskin
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  5. V. M. Novotortsev
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  6. I. L. Eremenko
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Corresponding author

Correspondence to T. M. Ivanova.

Additional information

Original Russian Text © T.M. Ivanova, A.V. Shchukarev, A.A. Sidorov, M.A. Kiskin, V.M. Novotortsev, I.L. Eremenko, 2009, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2009, Vol. 73, No. 7, pp. 987–989.

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Ivanova, T.M., Shchukarev, A.V., Sidorov, A.A. et al. Relation of X-ray photoelectron spectra with the magnetic properties of high-spin pivalic MnII and FeII . Bull. Russ. Acad. Sci. Phys. 73, 932–934 (2009). https://doi.org/10.3103/S1062873809070223

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  • DOI: https://doi.org/10.3103/S1062873809070223

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