Abstract
The combustion patterns of powder mixtures (100 – X)(Ti + C) + XNiCr, X = 0–20%, and phase composition of synthesis products were studied. The different nature of the dependence of the burning velocity on the nichrome content for blends containing titanium powders with particles of characteristic sizes of 60 and 120 μm was explained within the framework of the convective–conductive model by the retarding influence of impurity gases released ahead of the combustion front. The conditions for warming up Ti particles before the front were not met for mixtures of fine and coarse titanium powders. XRD spectra of combustion products showed the necessity of using fine titanium powder to obtain cermets without side phases of intermetallic compounds.
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REFERENCES
Liu, Y., Yu, B.H., Guan, D.H., Wang, Z.-B., and Bi, J., Microstructure and properties of TiC/NiCr cermets produced by partial liquid-phase sintering, J. Mater. Sci. Lett., 2001, vol. 20, pp. 619–620. https://doi.org/10.1023/A:1010965216385
Chesnokov, A.E. and Filippov, A.A. Study of physical properties of Ti–C–NiCr cermet compacts obtained by hot pressing, J. Appl. Mech. Tech. Phys., 2022, vol. 63, pp. 329–334. https://doi.org/10.1134/S002189442202016
Bolelli, G., Colella, A., Lusvarghi, L., Morelli, S., Puddu, P., Righetti, E., Sassatelli, P., and Testa, V., TiC–NiCr thermal spray coatins as an alternative to WC–CoCr and Cr3C2–NiCr, Wear, 2020, vols. 450–451, p. 203273. https://doi.org/10.1016/j.wear.2020.203273
Kiryukhantsev–Korneev, P.V., Sytchenko, A.D., and Levashov, E.A., Comparative study of coatings formed by electrospark alloying using TiC–NiCr and Ti–C–NiCr–Eu2O3 electrodes, Russ. J. Non-ferrous Metal, 2019, vol. 60, pp. 662–672. https://doi.org/10.3103/S1067821219060099
Zhang, W., Sui, M.L., Zhou, Y.Z., Guo, J.D., He, G.H., and Li, D.X., Evolution of microstructure in TiC/NiCr cermet induced by electropusing, J. Mater. Res., 2003, vol. 18, pp. 1543–1550. https://doi.org/10.1557/JMR.2003.0213
Seplyarsky, B.S., Kochetkov, R.A., Lisina, T.G., Abzalov, N.I., and Alymov, M.I., Phase composition and structure of titanium carbide/nickel binder synthesis products, Inorg. Mater., 2019, vol. 55, no 11, pp. 1104–1110. https://doi.org/10.1134/S0020168519110116
Seplyarskii, B.S., Kochetkov, R.A., Lisina, T.G., Rubtsov, N.M., and Abzalov, N.I., Explanation of increase in combustion velocity of Ti + C powder mixture upon dilution with nickel using convective–conductive combustion model, Int. J. Self-Propag. High-Temp. Synth. 2022, vol. 31. no. 4, pp. 195–206. https://doi.org/10.3103/S1061386222040100
Seplyarskii, B.S. The nature of the anomalous dependence of the velocity of combustion of “gasless” systems on the sample diameter, Dokl. Phys. Chem., 2004, vol. 396, nos. 4–6, pp. 130–133. https://doi.org/10.1023/B:DOPC.0000033505.34075.0a
Azatyan, T.S., Mal’tsev, V.M., Merzhanov, A.G., and Seleznev, V.A., Spectral-optical investigation of the mechanism of the combustion of mixtures of titanium and carbon, Combust. Explos. Shock Waves, 1977, vol. 13, no. 2, pp. 156–158. https://doi.org/10.1007/BF00754993
Zenin, A.A., Merzhanov, A.G., and Nersisyan, G.A., Thermal wave structure in SHS processes, Combust. Explos. Shock Waves, 1981, vol. 17, no. 1, pp. 63–71. https://doi.org/10.1007/BF00772787
Korol’chenko, I.A., Kazakov, A.V., Kukhtin, A.S., and Krylov, V.L., Experimental’noe opredelenie temperaturoprovodnosti materialov (Experimental determination of thermal conductivity of materials), Пожаровзрывоопасность веществ и материалов, 2004, vol. 13, no. 4, pp. 36–38.
Seplyarskii, B.S. and Kochetkov, R.A. Granulation as a tool for stabilization of SHS reactions, Int. J. Self-Propag. High-Temp. Synth., 2017, vol. 26, no. 2, pp. 134–136. https://doi.org/10.3103/S106138621702011X
Slezak, T., Zmywaczyk, J., and Koniorczyk, P. Thermal diffusivity investigations of the titanium grade 1 in wide temperature range, 21AIP Conf. Proc., 2019, vol. 2170, no. 1, p. 020019. https://doi.org/10.1063/1.5132738
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Seplyarskii, B.S., Kochetkov, R.A., Lisina, T.G. et al. Patterns of Synthesis of TiC–NiCr Cermets from Powder Mixtures: Influence of Nichrome Content and Titanium Particles Size. Int. J Self-Propag. High-Temp. Synth. 33, 75–79 (2024). https://doi.org/10.3103/S1061386224010060
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DOI: https://doi.org/10.3103/S1061386224010060