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Catalytic Pd–Ag nanoparticles immobilized on fiber glass by surface self-propagating thermal synthesis

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Abstract

Pd–Ag nanoparticles with different Pd/Ag ratio were deposited onto fiber glass by using the technique of surface self-propagating thermal synthesis (SSTS) and characterized by X-ray photoelectron spectroscopy (XPS), atomic absorption spectroscopy (ААS), and EXAFS spectroscopy. The samples reduced in hydrogen exhibited the formation of Pd–Ag alloy whose tentative structure and composition were suggested. Thermally scheduled reduction of Pd–Ag catalysts in hydrogen made the Ag atoms partially oxidized. Reported are the catalytic properties of synthesized Pd–Ag samples in selective hydrogenation of acetylene.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    Y. S. Kotolevich, N. S. Smirnova, P. G. Tsyryul’nikov & M. V. Trenikhin

  2. National Research State University, Tomsk, 634050, Russia

    G. V. Mamontov & O. V. Vodyankina

  3. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    N. I. Petrova

  4. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. I. Nizovskii, A. V. Kalinkin, M. Y. Smirnov & V. B. Goncharov

  5. Omsk State Technical University, Omsk, 644050, Russia

    A. I. Nizovskii

Authors
  1. Y. S. Kotolevich
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  2. G. V. Mamontov
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  3. O. V. Vodyankina
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  4. N. I. Petrova
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  5. N. S. Smirnova
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  6. P. G. Tsyryul’nikov
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  7. M. V. Trenikhin
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  8. A. I. Nizovskii
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  9. A. V. Kalinkin
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  10. M. Y. Smirnov
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  11. V. B. Goncharov
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Corresponding author

Correspondence to V. B. Goncharov.

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Kotolevich, Y.S., Mamontov, G.V., Vodyankina, O.V. et al. Catalytic Pd–Ag nanoparticles immobilized on fiber glass by surface self-propagating thermal synthesis. Int. J Self-Propag. High-Temp. Synth. 26, 234–239 (2017). https://doi.org/10.3103/S1061386217040045

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  • DOI: https://doi.org/10.3103/S1061386217040045

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