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SHS of Y2Ti2O7-based mineral-like ceramics: Influence of green density

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Abstract

Explored was the influence of compacting pressure (P) and green density (ρ) on the properties of Zr-doped mineral-like pyrochlore ceramics Y2(Ti1 – x Zr x )2O7 (x ≤ 0.3) prepared by SHS method. The optimal ρ values that provide minimal porosity and maximal mechanical strength of synthesized ceramics were found. An increase in ρ was found to decrease combustion temperature and increase pyrochlore lattice parameter a. Green density was also found to affect phase composition of the SHS-produced ceramics under study.

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References

  1. Barinova, T.V., Podbolotov, K.B., Borovinskaya, I.P., and Shchukin, A.S., Self-propagating high-temperature synthesis of ceramic matrices for immobilization of actinide-containing wastes, Radiochemistry, 2014, vol. 56, no. 5, pp. 554–559. doi 10.1134/ S106636221405017

    Article  Google Scholar 

  2. Barinova, T.V., Borovinskaya, I.P., Barinov, V.Yu., Kovalev, I.D., and Shchukin, A.S., SHS of pyrochloretype ceramic matrices for immobilization of actinidecontaining nuclear wastes, Int. J. Self-Propag. High-Temp. Synth., 2017, vol. 26, no. 1, pp. xx–yy.

    Article  Google Scholar 

  3. Glagovskii, E.M., Kuprin, A.V., Pelevin, L.P., Konovalov, E.E., Velichkin, V.L., and Myasoedov, B.F., Crystalline host phases for actinides obtained by selfpropagating high-temperature synthesis, Radiochemistry, 2001, vol. 43, no. 6, pp. 632–638.

    Article  Google Scholar 

  4. Vinokurov, S.E., Kulyako, Yu.M., Perevalov, S.A., and Myasoedov, B.E., Immobilization of actinides in pyrochlore-type matrices produced by self-propagating high-temperature synthesis, C. R. Acad. Sci., Ser. Chim., 2007, no. 10, pp. 1128–1130. doi 10.1016/ j.crci.2007.04.011

    Google Scholar 

  5. Laverov, N.P., Yudintsev, S.V., Konovalov, E.E., Nikolskii, M.S., Mishevets, T.O., Nikonov, B.S., and Omel’yanenko, B.I., Self-propagating high-temperature synthesis and characteristics of cermet matrices for isolation of wastes with long-lived radionuclides, Radiochemistry, 2012, vol. 54, no. 4, pp. 511–516.

    Article  Google Scholar 

  6. Varma, A. and Lebrat, J.-P., Combustion synthesis of advanced materials, Chem. Eng. Sci., 1992, vol. 47, nos. 9–11, pp. 2179–2194.

    Article  Google Scholar 

  7. Yudintsev, S.V., Stefanovskii, S.V., and Chou, S., Phase formation in Ca–Ce–Ti–Zr–(Hf)–O systems and optimization of synthesis conditions for pyrochlorebased actinide matrices, Fiz. Khim. Obrab. Mater., 2008, no. 3, pp. 70–80.

    Google Scholar 

  8. Baluev, A.V., Galkin, B.Ya., Mityakhina, V.S., and Isupov, V.K., Radioactive waste and matrices for its immobilization: A Review, Radiochemistry, 2000, vol. 42, no. 4, pp. 322–336.

    Google Scholar 

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Correspondence to T. V. Barinova.

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Barinova, T.V., Borovinskaya, I.P., Barinov, V.Y. et al. SHS of Y2Ti2O7-based mineral-like ceramics: Influence of green density. Int. J Self-Propag. High-Temp. Synth. 26, 119–123 (2017). https://doi.org/10.3103/S1061386217020030

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  • DOI: https://doi.org/10.3103/S1061386217020030

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