Abstract
Presented are some examples of successful application of dc resistometry and impedance spectroscopy to characterization of micro and nano powders commonly used in SHS technology.
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Emel’yanov, A.N., Shkiro, V.M., Rogachev, A.S., and Rubtsov, V.I., Electric and thermal conductivity of Tibased powder mixtures for self-propagating high-temperature synthesis, Izv. Vyssh. Uchebn. Zaved, Tsvet. Metall., 2002, no. 2, pp. 67–70.
Bloshenko, V.N., Bokii, V.A., and Borovinskaya, I.P., Dissolution of metal oxide film during synthesis of titanium carbide, Fiz. Goreniya Vzryva, 1984, vol. 20, no. 6, pp. 87–90 [Combust. Explos. Shock Waves (Engl. Transl.), 1984, vol. 20, no. 6, pp. 673–676].
Mokrushin, V.V., General conduction theory and resistometric characterization metal powders, Proc. All-Russia Conf on Combustion and Explosion in Physical Chemistry and Process Engineering of Inorganic Materials, 2002, Chernogolovka (Moscow), pp. 268–274.
Mokrushin, V.V. and Tsarev, M.V., Resistivity Measurements for Characterization of SHS Powders, Int. J. Self-Prop. High-Temp. Synth., 2007, vol. 16, no. 2, pp. 96–104.
Tsarev, M.V., Mokrushin, V.V., Sten’gach, A.V., Tarasova, A.I., Berezhko, P.G., Kremzukov, I.K., and Zabavin, E.V., A study of the oxidation of titanium hydride powder by measurements of its electrical resistance, Zh. Fiz. Khim., 2010, vol. 84, no. 4, pp. 767–772 [Russ. J. Phys. Chem., Ser. A (Engl. Transl.), 2010, vol. 84, no. 4, pp. 679–683].
Bal’shin, M.Yu., Nauchnie osnovy poroshkovoi metallurgii i metallurgii volokna (Fundamentals of Powder and Fiber Metallurgy), Moscow: Metallurgiya, 1972.
Skorokhod, V.V., Theory of the physical properties of porous and composite materials and the principles for control of their microstructure in manufacturing processes, Porosk. Metall., 1995, vol. 34, nos. 1–2, pp. 53–71 [Powder Metall. Metal Ceram. (Engl. Transl.), 1995, vol. 34, nos. 1–2, pp. 48–63].
Mokrushin, V.V., Generalized conductivity of powders under load: Patterns of behavior, Dokl. Akad. Nauk, 1997, vol. 357, no. 3, pp. 332–334 [Dokl. Phys. (Engl. Transl.), 1997, vol. 42, no. 11, pp. 586–589].
Mokrushin, V.V. and Berezhko, P.G., Generalized conductivity of powders and percolation theory, Dokl. Akad. Nauk, 1999, vol. 368, no. 4, pp. 470–473 [Dokl. Phys. (Engl. Transl.), 1999, vol. 44, no. 10, pp. 656–660].
Kochetov, N.A., Rogachev, A.S., Emel’yanov, A.N., Illarionova, E.V., and Shkiro, V.M., Microstructure of heterogeneous mixtures for gasless combustion, Fiz. Goreniya Vzryva, 2004, vol. 40, no. 5, pp. 74–80 [Combust. Explos. Shock Waves (Engl. Transl.), 2004, vol. 40, no. 5, pp. 564–570].
Tsarev, M.V. and Mokrushin, V.V., Effect of granulometric properties of scandium powder on its conductivity, Zh. Tekh. Fiz., 2007, vol. 77, no. 3, pp. 80–86 [Tech. Phys. (Engl. Transl.), 2007, vol. 52, no. 3, pp. 369–375].
Tsarev, M.V., Mokrushin, V.V., and Zabavin, E.V., Electric conductivity of zirconium hydride powders with different particle size, Zh. Funkts. Mater., 2008, no. 5, pp. 192–197.
Gusev, A.I., Nanokrisyallicheskie materially: Metody polucheniya i svoistva (Nanoctystalline Materials: Preparation and Properties), Yekaterinburg: Izd. UrO RAN, 1998.
Tsarev, M.V., Loshkarev, V.N., Postnikov, A.Yu., and Mokrushin, V.V., Reactivity and conductivity of nano and micro-sized Ti and Al powders, Materialovedenie, 2008, no. 10, pp. 24–28.
Morokhov, I.D., Trusov, L.I., and Lapovok, V.N., Fizicheskie yavleniya v ultradispersnykh sredakh (Physical Phenomena in Finely Dispersed Media), Moscow: Energoatomizdat, 1984.
Vasil’ev, R.B., Dorofeev, S.G., Rumyantseva, M.N., Ryabova, L.I., and Gas’kov, A.M., Impedance spectroscopy of ultrafine-grained SnO2 ceramics with variable grain size, Fiz. Tekh. Poluprovod., 2006, vol. 40, no. 1, pp. 108–111 [Semiconductors (Engl. Transl.), vol. 40, no. 1, pp. 104–107].
Pavlov, S.S., Temperature dependence for specific conductivity of W and Ni nanopowders, in Sovremennaya nauka: Aktual’nye problemy teorii i praktiki, Ser. Estestvennye i tekhnicheskie nauki, 2012, no. 1, pp. 22–27.
Frolov, Yu.V. and Pivkina, A.N., Fractal structure and features of combustion in heterogeneous condensed systems, Fiz. Goreniya Vzryva, 1997, vol. 33, no. 5, pp. 3–19 [Combust. Explos. Shock Waves (Engl. Transl.), 1997, vol. 33, no. 5, pp. 513–527].
Gulyaev, P.Yu., Dolmatov, A.V., Milyukova, I.V., Trifonov, A.L., and Shiryaev, S.A, Numerical modeling of fractal packing structures in SHS powders, Polzunov. Al’manakh, 2007, no. 3, pp. 39–41.
Odelevskii, V.I., Calculation of generalized conductivity for heterogeneous systems, Zh. Tech. Fiz., 1951, vol. 21, no. 6, pp. 667–685.
Mokrushin, V.V., Berezhko, P.G., Yaroshenko, V.V., Golubev, V.A., and Balandin, V.A., A method for measuring the thickness of coatings on powder particles, USSR Inventor’s Certificate 1598600, 1990; Byull. Izobret., 1999, no. 23.
Obholtz, O.Ya., Berezko, V.V., Frolova, L.M., Dobrusin, S.Yu., and Shevlyakov, V.V., Estimates of oxygen amounts in oxide films of Ta powders, Tsvet. Met., 2004, no. 6, pp. 94–96.
Poristye pronitsaemye materially: Spravochnik (Porous Penetrable Materials: A Handbook), Belov, S.V., Ed., Moscow: Metallurgiya, 1987.
Impedance Spectroscopy: Theory, Experiment, and Applications, Barsoukov, E. and Ross, M.J., Eds., New York: Wiley, 2005.
Irvin, J.T.S., Sinclair, D.C., and West, A.R., Electroceramics: Characterization by impedance spectroscopy, Adv. Mater., 1990, vol. 2, no. 3, pp. 132–138.
Ivanov-Shits, A.K. and Murin, I.V., Ionika tverdogo tela (Solid-State Ionics), St. Petersburg: Izd. St.-Petersb. Gos. Univ., vol. 1, 2000.
Poklonskii, N.A. and Gorbachuk, N.I., Osnovy impedansnoi spektroskopii kompozitov:Kurs lektsii (Fundamentals of Impedance Spectroscopy of Composites: A Course of Lectures), Minsk: Izd. BGU, 2005.
Mokrushin, V.V., Golubev, V.A., Yaroshenko, V.V., and Balandin, V.A., A method for measuring electrophysical parameters of powders, USSR Inventor’s Certificate 1540482, 1989; Byull. Izobret., 1999, no. 23.
Ukshe, A.E. and Ukshe, E.A., Impedance of solid polycrystalline electrolyte, Elektrokhimiya, 1981, vol. 17, no. 5, pp. 776–780.
Sakharova, A.Ya., Sevast’yanov, A.E., Pleskov, Yu.V., Teplitskaya, G.L., Surikov, V.V., and Voloshin, A.A., Electrodes of synthetic semiconducting diamond: Electric conductivity as derived from impedance measurements, Elektrokhimiya, 1991, vol. 27, no. 2, pp. 263–268.
Poklonskii, N.A., Gorbachuk, N.I., Pototskii, I.V., and Trofimchuk, D.A, Electrical conductivity of composite materials based on fine-particle silicon near the metalinsulator transition, Neorg. Mater., 2004, vol. 40, no. 11, pp. 1293–1298 [Inorg. Mater. (Engl. Transl.), 2004, vol. 40, no. 11, pp. 1133–1137].
Poklonskii, N.A., Gorbachuk, N.I., and Aleinikova, D.A., Impedance of Si/SiO2 composites in the vicinity of the percolation threshold, Fiz. Tverd. Tela, 2011, vol. 53, no. 3, pp. 433–437 [Phys. Solid State [Phys. Solid State (Engl. Transl.), 2011, vol. 53, no. 3, pp. 458–461].
Kennedy, A.R. and Lopez, V.H., The decomposition behavior of as-received and oxidized TiH2 foamingagent powder, Mater. Sci. Eng., Ser. A, 2003, vol. 357, nos. 1–2, pp. 258–263.
Matijasevic-Lux, B., Banhart, J., Fiechter, S., Görke, O., and Wanderka, N., Modification of titanium hydride for improved aluminum foam manufacture, Acta Mater., 2006, vol. 54, no. 7, pp. 1887–1900.
Malov, Yu.I., Fokin, V.N., and Fokina, E.E., Compounds of titanium hydride and oxygen, Zh. Neorg. Khim., 1994, vol. 39, no. 1, pp. 15–17.
Tadokoro, S.K. and Muccillo, E.N.S., Influence of precursor purity and precipitating agent on impedance spectroscopy of CeO2:Y2O3 ceramics, J. Alloys Comp., 2004, vol. 374, nos. 1–2, pp. 190–193.
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Mokrushin, V.V., Tsarev, M.V., Korshunov, K.V. et al. Resistometry and impedance spectroscopy for characterization of powders used in SHS reactions. Int. J Self-Propag. High-Temp. Synth. 23, 26–35 (2014). https://doi.org/10.3103/S1061386214010099
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DOI: https://doi.org/10.3103/S1061386214010099