Solid Fuel Chemistry

, Volume 52, Issue 2, pp 116–120 | Cite as

Characterization of the Organic Matter of Humic Acids by Pyrolytic Gas Chromatography–Mass Spectrometry

  • N. V. Yudina
  • A. V. Savel’eva
  • V. N. Melenevskii
Article

Abstract

The results of the pyrolytic analysis of products of the organic matter of Sphagnum fuscum, fuscum peat, and humic acids separated from peat with the use of pyrolysis–chromatography–mass spectrometry in the Rock-Eval version are presented. It was shown that Sphagnum fuscum and peat differed only slightly in the degrees of chemical transformation. Benzene, phenol, and their alkyl-substituted homologues predominated in the thermal desorption products of humic acids upon pyrolysis to 400°C. Acetic acid, monohydric phenols, syringol, and guaiacol, which are the basic compounds in the high-temperature fraction, were formed on the pyrolysis humic acids to 700°C from the carbohydrate, phenylpropionic, and guaiacylpropane structural fragments.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Perminova, Extended Abstract of Doctoral (Chem.) Dissertation, Moscow: Moscow State Univ., 2000, p. 44.Google Scholar
  2. 2.
    Ivanov, A.A., Yudina, N.V., and Savel’eva, A.V., Khim. Rastit. Syr’ya, 2014, no. 1, p. 263.Google Scholar
  3. 3.
    Parfenova, L.N., Mal’tseva, E.V., and Bogolitsyn, K.G., Fund. Issled. Khim. Nauki, 2014, no. 5, p. 44.Google Scholar
  4. 4.
    Kalabin, G.A., Kanitskaya, L.V., and Kushnarev, D.F., Kolichestvennaya spektroskopiya YaMR prirodnogo organicheskogo syr’ya i produktov ego pererabotki (Quantitative NMR Spectroscopy of Natural Organic Raw Materials and Their Conversion Products), Moscow: Khimiya, 2000.Google Scholar
  5. 5.
    Byambagar, B., Kushnarev, D.F., Fedorova, T.E., Novikova, L.N., Yakovleva, Yu.N., Ostrovskaya, R.M., Proidakov, A.G., and Kalabin, G.A., Khim. Tverd. Topl. (Moscow), 2003, no. 1, p. 83.Google Scholar
  6. 6.
    Tomson, A.E. and Naumova, G.V., Torf i produkty ego pererabotki (Peat and Its Processing Products), Minsk: Belaruskaya Navuka, 2009.Google Scholar
  7. 7.
    Lishtvan, I.I., Kaputskii, F.N., Yanuta, Yu.G., Abramets, A.M., Monich, G.S., Strigutskii, V.P., Glukhova, N.S., and Aleinikova, V.N., Vestn. Bel. Gos. Univ., Ser. 2, 2012, no. 2, p. 12.Google Scholar
  8. 8.
    Poirier, N., Derenne, S., Balesdent, J., Mariotti, A., Massiot, D., and Largeau, C., Eur. J. Soil Sci., 2003, vol. 54, p. 243.CrossRefGoogle Scholar
  9. 9.
    Sebag, D., Disnar, J.R., Guillet, B.Di., Giovanni, C., Verrecchia, E.P., and Durand, A., Eur. J. Soil Sci., 2006, vol. 57, p. 344.CrossRefGoogle Scholar
  10. 10.
    Li, L., Jia, W., Sheng, G., Fu, J., and Huang, W., Appl. Geochem., 2006, p. 1455.Google Scholar
  11. 11.
    Olivella, M.A., Rio del, J.C., Palacios, J., Vairavamurthy, M.A., and Heras, F.-X.C., J. Anal. Appl. Pyrolysis, 2002, vol. 63, p. 59.CrossRefGoogle Scholar
  12. 12.
    Ikeya, K., Ishida, Y., Ohtani, H., et al., J. Anal. Appl. Pyrolysis, 2006, vol. 75, p. 174.CrossRefGoogle Scholar
  13. 13.
    Disnar, J.R., Guillet, B., Keravis, D.Di., Giovanni, C., and Sebag, D., Org. Geochem., 2003, vol. 34, p. 327.CrossRefGoogle Scholar
  14. 14.
    Jocteur-Montrozier, L. and Robin, A.M., Rev. Ecol. Biol. Sol., 1988, vol. 24, p. 203.Google Scholar
  15. 15.
    Lishtvan, I.I, Osnovnye svoistva torfa i metody ikh opredeleniya (Main Properties of Peat and Methods for Their Determination), Minsk: Nauka i Tekhnika, 1975.Google Scholar
  16. 16.
    Melenevskii, V.N., Kontorovich, A.E., Kashirtsev, V.A., and Kim, N.S., Neftekhimiya, 2009, no. 4, p. 1.Google Scholar
  17. 17.
    Stankiewicz, B.A., Briggs, D.E.G., and Evershed, R.P., Energy Fuels, 1997. vol. 11, p. P. 515.CrossRefGoogle Scholar
  18. 18.
    Melenevskii, V.N., Leonova, G.A., and Konyshev, A.S., Geol. Geofiz., 2011, vol. 52, no. 6, p. 751.Google Scholar
  19. 19.
    Deniau, I., Derenne, S., Beaucaire, C., Pitsch, H., and Largeau, C., Org. Geochem., 2004. vol. 35, p. P. 387.CrossRefGoogle Scholar

Copyright information

© Allerton Press, Inc. 2018

Authors and Affiliations

  • N. V. Yudina
    • 1
  • A. V. Savel’eva
    • 1
  • V. N. Melenevskii
    • 2
  1. 1.Institute of Petroleum Chemistry, Siberian BranchRussian Academy of SciencesTomskRussia
  2. 2.Trofimuk Institute of Petroleum Geology and Geophysics, Siberian BranchRussian Academy of SciencesNovosibirskRussia

Personalised recommendations