Abstract
The possibility of using the PSTC-3F synthetic organosilicone sorbent for the adsorption removal of mercury from an aqueous solution has been studied. The dependence of mercury adsorption on the pH of the solution, the amount of the adsorbent and the duration of the contact of the solution with the adsorbent is examined. It is shown that the higher the solution acidity is, the higher the adsorption value is. It has been established that the mercury adsorption process on the PSTC-3F sorbent is described by the Freundlich equation.
Similar content being viewed by others
REFERENCES
Anbia, M. and Amirmahmoodi, S. Removal of Hg (II) and Mn (II) from aqueous solution using nanoporous carbon impregnated with surfactants, Arab. J. Chem., 2016, vol. 9, pp. 319–325.
Fiaizullina, R.V., Makarova, M.A., and Abrosimova, N.A., The possibility of wastewater treatment of heavy metals by natural sorbents, in Proc. 17 Int. Multidisciplinary Sci. Geoconf. SGEM 2017. Ser. Soils, Forest Ecosyst. Vol. 52. Varna, Bulgaria, Sofia, 2017, pp. 1027–1034.
Fiaizullina, R.V., Kuznetsov, E.V., and Salavatova, D.S., Adsorption equilibrium in the “Mercury (II)–silicone sorbent” system, in Tr. XXII Mezhd. nauch. simp. imeni akademika M.A. Usova “Problemy geologii i osvoeniya nedr”. T. 1. Sekt. 9 (Proc. XXII Int. Sci. Symp. Named in Honor of M.A. Usov “Problems of Geology and the Development of Mineral Resources. Vol. 1. Pt. 9), Tomsk: Tomsk. Politekhn. Univ., 2018, pp. 865–866.
Foo, K.Y. and Hameed, B.H., Insights into the modeling of adsorption isotherm systems, Chem. Eng. J., 2010, no. 156, pp. 2–10.
Freundlich, H.M.F., Over the adsorption in solution, J. Phys. Chem., 1906, vol. 57A, pp. 385–470.
Konya, J. and Nagy, N.M., Sorption of dissolved mercury (II) species on calcium-montmorillonite: an unusual pH dependence of sorption process, J. Radioanal. Nucl. Chem., 2011, vol. 288, pp. 447–454.
Langmuir, I., The constitution and fundamental properties of solids and liquids, J. Am. Chem. Soc., 1916, vol. 38, no. 11, pp. 2221–2295.
Laperdina, T.G., Opredelenie rtuti v prirodnykh vodakh (Mercury Determination in Natural Waters), Novosibirsk: Nauka, 2000.
Mukhamadiyarova, R.V. and Smirnova, A.S., Study of the mercury content in solid natural samples, Moscow Univ. Geol. Bull., 2014, vol. 69, no. 1, pp. 36–40.
Nazarenko, V.A., Antonovich, V.P., and Nevskaya, E.M., Gidroliz ionov metallov v razbavlennykh rastvorakh (Hydrolysis of Metal Ions in Dilute Solutions), Moscow: Atomizdat, 1979.
Voronkov, M.G., Vlasova, N.N., Pozhidaev, Yu.N., et al., Highly complex and ampholyte—poly[N,N'-bis(3-silseskioksanilpropil)thiourea)], Dokl. Ross. Akad. Nauk, 1991, vol. 320, no. 3, pp. 658–662.
Vasil’eva, I.E., Pozhidaev, Yu.N., Vlasova, N.N., et al., Sorption-atomic-emission determination of gold, platinum and palladium in rocks and ores using PSTC-3F sorbent, Analitika Kontrol, 2010, vol. 14, no. 1, pp. 16–24.
ACKNOWLEDGMENTS
We are grateful to A.Yu. Bychkov, Yu.V. Alekhin and D.A. Bychkov, the staff in the Chair of Geochemistry , for kind attention to our work and the valuable comments.
Funding
The experimental work was supported by the Russian Foundation for Basic Research (project no. 17-05-01055), data processing was supported by the Russian Science Foundation (project no. 19-17-00200).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Translated by L. Mukhortova
About this article
Cite this article
Fiaizullina, R.V., Kuznetsov, E.V. & Salavatova, D.S. Mercury Adsorption from Aqueous Solution Using a Synthetic Organosilicon Sorbent. Moscow Univ. Geol. Bull. 75, 381–386 (2020). https://doi.org/10.3103/S0145875220040067
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S0145875220040067