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Features of structure and properties of Na n C60 (n = 2, 3) fullerides synthesized in toluene

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Abstract

The structure and electron properties of Na n C60 (n = 2, 3) sodium fullerides synthesized from simple compounds in toluene were studied. It was shown that Na2C60 fulleride forms a face-centered cubic lattice at temperatures above 300 K. As the temperature is lowered, the phase transition to a structure with a simple cubic lattice takes place. The temperature dependences of the properties of Na3C60 with a more complex structure exhibit features that are presumably due to sodium atom redistribution in the Na3C60 fulleride lattice and the formation of sodium ion clusters.

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Authors and Affiliations

  1. Department of Low-Temperature Physics and Superconductivity, Faculty of Physics, Moscow State University, Moscow, 119991, Russia

    N. B. Brandt, A. V. Zoteev, E. A. Konstantinova, A. V. Krechetov, V. A. Kul’bachinskii & V. G. Kytin

  2. Faculty of Chemistry, Moscow State University, Moscow, 119998, Russia

    B. M. Bulychev & Yu. A. Velikodnyi

  3. Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. P. Tarasov

Authors
  1. N. B. Brandt
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  2. B. M. Bulychev
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  3. Yu. A. Velikodnyi
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  4. A. V. Zoteev
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  5. E. A. Konstantinova
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  6. A. V. Krechetov
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  7. V. A. Kul’bachinskii
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  8. V. G. Kytin
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  9. V. P. Tarasov
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Corresponding author

Correspondence to V. G. Kytin.

Additional information

Original Russian Text © N.B. Brandt, B.M. Bulychev, Yu.A. Velikodnyi, A.V. Zoteev, E.A. Konstantinova, A.V. Krechetov, V.A. Kul’bachinskii, V.G. Kytin, V.P. Tarasov, 2009, published in Vestnik Moskovskogo Universiteta. Fizika, 2009, No. 2, pp. 65–69.

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Brandt, N.B., Bulychev, B.M., Velikodnyi, Y.A. et al. Features of structure and properties of Na n C60 (n = 2, 3) fullerides synthesized in toluene. Moscow Univ. Phys. 64, 172–176 (2009). https://doi.org/10.3103/S0027134909020155

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  • DOI: https://doi.org/10.3103/S0027134909020155

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