Abstract
This paper presents results of the transmittance, photoacoustic and surface photovoltage experiments performed on the series of CdS1 – xTex thin films. These CdS1 – xTex (0 ≤ x ≤ 1) thin films were obtained on the glass substrate by the chemical molecular beam deposition (CMBD) method. From the experimental optical characteristics, the optical absorption coefficient spectra of the samples and values of the energy gaps vs. composition of the crystals were determined. The energy gaps of the layers changed from 2.44 to 1.34 eV. From the photo voltage characteristics, the diffusion lengths of the carriers were determined. They changed from 5 to 17 µm what can indicate a good quality of the layers.
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REFERENCES
Zhao, J., Chi, Z., Yang, Z., Chen, X., Arnold, M.S., Zhang, Y., Xu, J., Chi, Z., and Aldred, M.P., Recent developments of truly stretchable thin film electronic and optoelectronic devices, Nanoscale, 2018, vol. 10, pp. 5764–5792.
Moon, D., Lee, J., Roh, E., and Lee, N., Three-dimensional out-of-plane geometric engineering of thin films for stretchable electronics: a brief review, Thin Solid Films, 2019, vol. 688, id. 137435.
Ozgur, U., Hofstetter, D., and Morkoc, H., ZnO devices and applications: A review of current status and future prospects, in Proceedings of the IEEE 98, 2010, vol. 7, pp. 1255–1268.
Liu, F.J., Hu, Z.F., Sun, J., Li, Z.J., Huang, H.Q., Zhao, J.W., Zhang, X.Q., and Wang, Y.S., Ultraviolet photoresistors based on ZnO thin films grown by P-MBE, Solid-State Electron., 2012, vol. 68, pp. 90–92.
Liu, C., Tang, X., Guo, X., Liu, Q., Jiang, Y., Tang, Z., and Li, W., Photodiode characteristics of HfO2 thin films prepared by magnetron sputtering, Mater. Des., 2020, vol. 188, id. 108465.
Hwang, C., Park, S., Oh, H., Ryu, M., Cho, K., and Yoon, S., Vertical channel ZnO thin-film transistors using an atomic layer deposition method, IEEE Electron Device Lett., 2014, vol. 35, no. 3, pp. 360–362.
Mukhamedzyanov, H.N., Markov, V.F., and Maskaeva, L.N., Study of the characteristics of photoresistors based on hydrochemically deposited films of Pb0.902Sn0.098Se solid solution, Semiconductors, 2013, vol. 47, pp. 574–578.
Khan, M.N., Khan, M.S., Aziz, A., Rahman, S.A., and Khan, Z.R., Spectroscopic studies of sol-gel grown CdS nanocrystalline thin films for optoelectronic devices, Mater. Sci. Semicond. Process., 2013, vol. 16, pp. 1894–1898.
Li, J., Li, H., Ding, D., Li., Z., Chen, F., Wang, Y., Liu, S., Yao, H., Liu, L., and Shi, Y., High-performance photoresistors based on perovskite thin film with a high PbI2 doping level, Nanomaterials, 2019, vol. 9, id. 505.
McDonald, S.A., Konstantatos, G., Zhang, S., et al., Solution-processed PbS quantum dot infrared photodetectors and photovoltaics, Nat. Mater., 2005, vol. 4, pp. 138–142.
Lu, N., Jiang, W., Wu, Q., Geng, D., Li., L., and Liu, M., A review for compact model of thin-film transistors (TFTs), Micromachines, 2018, vol. 9, id. 599.
Razykov, T.M., A novel chemical molecular beam deposition method for fabrication of II–VI low dimensional structures, Microelectron. J., 2005, vol. 36, pp. 599–600.
Razykov, T.M., Structural and electrophysical properties of ZnTe and ZnxCd1 – xTe films obtained by chemical vapor-phase deposition, Appl. Sol. Energy, 1988, vol. 24, no. 4, pp. 1–5.
Razykov, T.M., Kuchkarov, K.M., Ferekides, C.S., Ergashev, B.A., Yuldoshov, R.T., Mamarasulov, N., and Zufarov, M.A., Characterization of CdTe thin films with different compositions obtained by CMBD for thin film solar cells, Sol. Energy, 2017, vol. 144, pp. 411–416.
Razykov, T.M., Boltaev, G.S., Bosio, A., Ergashev, B., Kouchkarov, K.M., Mamarasulov, N.K., Mavlonov, A.A., Romeo, A., Romeo, N., Tursunkulov, O.M., and Yuldoshov, R., Characterisation of SnSe thin films fabricated by chemical molecular beam deposition for use in thin film solar cells, Sol. Energy, 2018, vol. 159, pp. 834–840.
Razykov, T.M., Shukurov, A.X., Atabayev, O.K., Kuchkarov, K.M., Ergashev, B., and Mavlonov, A.A., Growth and characterization of Sb2Se3 thin films for solar cells, Sol. Energy, 2018, vol. 173, pp. 225–228.
Razykov, T.M., Bosio, A., Ergashev, B., Kouchkarov, K.M., Romeo, A., Romeo, N., Yuldoshov, R., Baiev, M., Makhmudov, M., Bekmirzoyev, J., Khurramov, R., and Fazylov, E., Growth and characterization of ZnxSn1 − xSe films for use in thin film solar cells, Sol. Energy, 2019, vol. 193, pp. 519–522.
Razykov, T.M., Chemical molecular beam deposition of II–VI binary and ternary compound films in gas flow, Appl. Surf. Sci., 1991, vol. 49, pp. 89–92.
Razykov, T.M., Bosio, A., Romeo, N., Ergashev, B.A., Mavlonov, A.A., Usmonov, A.Yu., and Esanov, Sh.A., Characterization of CdTe and CdS films for photoresistors, Appl. Sol. Energy, 2019, vol. 55, pp. 1–4.
Rasool, S., Saritha, K., Ramakrishna Reddy, K.T., Raveendranath Reddy, K., Bychto, L., Patryn, A., Maliński, M., Tivanov, M.S., and Gremenok, V.F., Optical properties of thermally evaporated In2S3 thin films measured using photoacoustic spectroscopy, Mater. Sci. Semicond. Process., 2017, vol. 72, pp. 4–8.
Rasool, S., Saritha, K., Ramakrishna Reddy, K.T., Bychto, L., Patryn, A., Maliński, M., Tivanov, M.S., and Gremenok, V.F., Optoelectronic properties of In2S3 thin films measured using surface photovoltage spectroscopy, Mater. Res. Express, 2019, vol. 6, no. 1, id. 076417.
Bychto, L. and Maliński, M., Photoacoustic spectroscopy analysis of thin semiconductor samples, Opto-Electron. Rev., 2018, vol. 26, pp. 217–222.
Bychto, L. and Maliński, M., Determination of the optical absorption coefficient spectra of thin semiconductor layers from their photoacoustic spectra, Int. J. Thermophys., 2018, vol. 39, id. 103.
Tauc, J., Grigorovici, R., and Vancu, A., Optical properties and electronic structure of amorphous germanium, Phys. Status Solidi, 1966, vol. 15, pp. 627–637.
Shroder, D.K., Surface voltage and surface photovoltage: history, theory and applications, Meas. Sci. Technol., 2001, vol. 12, no. 3, pp. R16–R31.
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This work was supported by the grants FA-F3-003 of the Basic Research Foundation and YoFA-Atech-2018-205 of the Uzbekistan Academy of Sciences.
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Razykov, T.M., Patryn, A., Maliński, M. et al. Optical Properties of CdS1 – xTex Thin Films Obtained by Chemical Molecular Beam Deposition Method. Appl. Sol. Energy 57, 181–187 (2021). https://doi.org/10.3103/S0003701X21030063
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DOI: https://doi.org/10.3103/S0003701X21030063