Advertisement

Physics of Wave Phenomena

, Volume 16, Issue 4, pp 292–299 | Cite as

Nature of long-lived nonequilibrium states of water and glycyltryptophan aqueous solutions

  • L. V. Belovolova
  • M. V. Glushkov
  • G. I. Vinogradova
  • E. A. Vinogradov
Ultraviolet Spectroscopy

Abstract

It was shown that long-term quasi-periodic and transient processes of variations in fluorescence parameters of water and diluted aqueous solutions can be explained by reversible chain reactions of peroxidation of organic impurities localized on the vapor-gas bubble surface. These processes are initiated by reactive oxygen species and are accompanied by changes in gas contents, conductivity, and pH of an aqueous medium. By the example of Tween-85 additives to diluted solutions of glycyltryptophan, it was shown that the effect of organic impurities is most pronounced at their low concentrations.

PACS numbers

33.50.Dq 78.60.Mq 78.60.Ps 82.60.Lf 82.70.Uv 87.15.mq 87.15.np 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    V. I. Bruskov, Zh. K. Masalimov, and A. V. Chernikov, “Heat-Induced Generation of Reactive Oxygen Species in Water,” Dokl. Biochem. Biophys. 384, 181 (2002).CrossRefGoogle Scholar
  2. 2.
    V. I. Bruskov, Zh. K. Masalimov, and A. V. Chernikov, “Heat-Induced Generation of Reactive Oxygen Species During Reduction of Dissolved Air Oxygen,” Dokl. Biol. Sci. 381, 586 (2001).CrossRefGoogle Scholar
  3. 3.
    G. A. Domrachev, I. N. Didenkulov, Yu. L. Rodygin, D. A. Selivanovskii, and P.A. Stunzhas, “Water Dissociation in Flows near a Hard Wall,” Khim. Fiz. 20(4), 82 (2001).Google Scholar
  4. 4.
    I. I. Stepuro, R. I. Adamchuk, T. P. Piletskaya, V. I. Stepuro, and S.A. Maskevich, “Ultrasound-Induced Formation of S-Nitrosoglutathione and S-Nitrosocysteine in Aerobic Aqueous Solutions of Glutathione and Cysteine,” Biochem. (Moscow). 65(12), 1385 (2000).CrossRefGoogle Scholar
  5. 5.
    M. M. Potselueva, A.V. Pustovidko, Yu. V. Evtodienko, R.N. Khramov, and L. M. Chailakhyan, “Formation of Reactive Oxygen Species in Aqueous Solutions after Exposure to Extremely-High Frequency Electromagnetic Fields,” Dokl. Ross. Akad. Nauk. 359(3), 415 (1998).Google Scholar
  6. 6.
    V. N. Kazachenko, E. E. Fesenko, K. V. Kochetkov, and N.K. Chemeris, “Millimeter-Wave Irradiation of Water and Aqueous Solutions Changes the Content of Free Oxygen Therein,” Biophysics. 43(6), 931 (1998).Google Scholar
  7. 7.
    V. I. Lobyshev, B. D. Ryzhikov, and Z. E. Shikhlinskaya, “Spontaneous and External Electromagnetic Field-Induced Long-Term Transition Processes in Dilute Aqueous Solutions of Glycyltryptophan and in Water,” Biophysics. 43(4), 673 (1998).Google Scholar
  8. 8.
    V. I. Lobyshev, R. E. Shikhlinskaya, and B.D. Ryzhikov, “Experimental Evidence for Intrinsic Luminescence of Water,” J.Mol. Liquids. 82(1–2), 73 (1999).CrossRefGoogle Scholar
  9. 9.
    V. I. Lobyshev, M. S. Tomkevich, and I. Yu. Petrushanko, “Experimental Study of Potentiated Aqueous Solutions,” Biophysics. 50(3), 416 (2005).Google Scholar
  10. 10.
    L. V. Belovolova and M.V. Glushkov, http://zhurnal.ape.relarn.ru/articles/2006/215.pdf
  11. 11.
    L. V. Belovolova, M.V. Glushkov, and G. I. Vinogradova, http://zhurnal.ape.relarn.ru/articles/2006/268.pdf
  12. 12.
    J. G. Calvert and J. N. Pitts, Photochemistry (Wiley, N.Y., 1966).Google Scholar
  13. 13.
    R. M. Pashley, M. Rzechowicz, L.R. Pashley, and M. J. Francis, “De-Gassed Water Is a Better Cleaning Agent,” J. Phys. Chem. B. 109(3), 1231 (2005).CrossRefGoogle Scholar
  14. 14.
    M. A. Margulis, Acoustochemical Reactions and. Sonoluminescence (Khimiya, Moscow, 1986), p. 99 [in Russian].Google Scholar
  15. 15.
    L. V. Belovolova, Candidate’s Dissertation in Mathematics and Physics (Chem. Phys. Inst. AN USSR, Moscow, 1987) [in Russian].Google Scholar
  16. 16.
    N. F. Bunkin, N.V. Suyazov, and D. Yu. Tsipenyuk, “Small-Angle Scattering of Laser Radiation by Stable Micron Particles in Twice-Distilled Water,” Quantum Electron. 35(2), 180 (2005).CrossRefGoogle Scholar
  17. 17.
    B. G. Emets, “Determination of Average Sizes and Concentration of Air Bubbles in Water by Nuclear Magnetic Resonance,” Pisma Zh. Eksp. Teor. Fiz. 23(13), 43 (1997) [JETP Lett.].Google Scholar
  18. 18.
    P. Vallée, J. Lafait, L. Legrand, P. Mentré, M.-O. Monod, and Y. Thomas, “Effects of Pulsed Low-Frequency Electromagnetic Fields on Water Characterized by Light Scattering Techniques: Role of Bubbles,” Langmuir. 21(6), 2293 (2005).CrossRefGoogle Scholar
  19. 19.
    I. P. Pozdnyakov, Yu. A. Sosedova, V. F. Plyusnin, V. P. Grivin, and N. M. Bazhin, “Photochemistry of Salicylate Anion in Aqueous Solution,” Russ. Chem. Bull. 56(7), 1318 (2007).CrossRefGoogle Scholar
  20. 20.
    I. V. Perminova, Khimiya i Zhizn. No. 1, 50 (2008) [Chemistry and Life].Google Scholar
  21. 21.
    I. L. Lavrik, Khimiya i Zhizn. No. 4, 42 (2001) [Chemistry and Life].Google Scholar
  22. 22.
    S. V. Patsaeva, V. V. Fadeev, E. M. Filippova, V. V. Chubarov, and V. I. Yuzhakov, “Diagnostics of Organic Admixtures in Acids by the Laser Fluorimetry Method,” BRAS Phys. 56(12), 1959 (1992).Google Scholar
  23. 23.
    V. L. Voeikov, V. V. Koldunov, and D. S. Kononov, “Sustained Oscillations of Chemiluminescence in Course of Amino-Carbonyl Reaction in Aqueous Solutions,” Russ. J. Phys. Chem. 75, 1579 (2001).Google Scholar
  24. 24.
    Yu. A. Vladimirov, Soros. Obraz. Zh. 7(2), 20 (2001).Google Scholar
  25. 25.
    R. V. Bensasson, E. J. Land, and T. G. Truscott, Flash Photolysis and Pulse Radiolysis (Pergamon Press, Oxford, 1983), p. 165.Google Scholar
  26. 26.
    Yu. A. Vladimirov, “Free Radical Oxidation of Lipids and Physical Properties of the Lipid Layer of Biological Membranes,” Biofizika. 32(5), 830 (1987) [Biophysics].Google Scholar
  27. 27.
    R. F. Vasil’ev, “Chemiluminescence in Solutions,” Sov. Phys.-Usp. 9(4), 504 (1967).CrossRefADSGoogle Scholar
  28. 28.
    M. F. Timochko and Ya. I. Alekseevich, Khimiya i Zhizn. No. 1, 45 (1991) [Chemistry and Life].Google Scholar
  29. 29.
    N. V. Shinkarenko and V. B. Aleskovskii, “Singlet Oxygen: Methods of Preparation and Detection,” Russ. Chem. Rev. 50(3), 220 (1981).CrossRefGoogle Scholar
  30. 30.
    Yu. V. Gurikov and N. F. Bondarenko, “Natural Water as an Oxidizing System,” Russ. J. Phys. Chem. A. 75(7), 1103 (2001).Google Scholar
  31. 31.
    A. M. Kuzin, “Electromagnetic Information in the Phenomenon of Life,” Biophysics. 45(1), 134 (2000).Google Scholar

Copyright information

© Allerton Press, Inc. 2008

Authors and Affiliations

  • L. V. Belovolova
    • 1
  • M. V. Glushkov
    • 1
  • G. I. Vinogradova
    • 1
  • E. A. Vinogradov
    • 1
  1. 1.Prokhorov General Physics InstituteRussian Academy of SciencesMoscowRussia

Personalised recommendations