Skip to main content
Log in

Unusual Nano-Microcrystals of Natural Diamond

  • Production, Structure, Properties
  • Published:
Journal of Superhard Materials Aims and scope Submit manuscript

Abstract

Described are unusual nano-microcrystals of natural diamond found in a meteorite crater of Ukraine and advised about the earlier unknown mechanism of diamond polyhedra growth—the formation by globules. It was revealed that diamond nano-microcrystals in a meteorite crater are very similar to globular crystals, and at the same time have octahedral faceting. The morphology and composition of diamond nano-microcrystals are studied by scanning electron microscopy and with an energy dispersive X-ray analyser. These tiny crystals are grown on the grains of impact apographitic diamond from the Bilylivka meteorite crater (Zapadnaya impact crater) on the Ukrainian Shield. Their surface morphology indicates that the nano-microdiamonds are grown, most probably, by a vapor deposition process immediately after the formation of the impact diamond–transformation of the graphite into diamond and lonsdaleite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gurov, E.P., Gurova, E.P., and Rakitskaya, R.B., Impact diamonds in the craters of the Ukrainian Shield, Meteoritics, 1995, vol. 30, pp. 515–516.

    Google Scholar 

  2. Gurov, E.P., Gurova, E.P., and Rakitskaya, R.B., Impact diamonds of the Zapadnaya crater: Phase Composition and some properties, Meteor. Planet. Sci., 1996, vol. 31, A56.

    Google Scholar 

  3. Val’ter, A.A., Gursky, D.S., and Erjomenko, G.K., Diamondiferous of the astroblemes of Ukraine and the nature of high concentrations of impact diamond, Mineral. J. (Ukraine), 1998, vol. 20, no. 6., pp. 48–63.

    Google Scholar 

  4. Gurov, E. P., Gurova, E.P., and Socur, T.M., Geology and petrography of the Zapadnaya crater in the Ukraine Shield, Impacts in Precambrian Shields, Plado, J., Pesonen, L.J., Eds., Heidelberg: Springer–Verlag, Berlin, 2002, pp. 173–188.

    Chapter  Google Scholar 

  5. Tsymbal, S.N., Kvasnitsa, V.N., Tsymbal, Yu. S., and Mel’nichuk, E.B., Diamond from impactites of Belilovka(Zapadnaya) astrobleme (the Ukrainian Shield), Mineral J. (Ukraine), 1999, vol. 21, pp. 45–52.

    CAS  Google Scholar 

  6. Oleinik, G.S., Valter, A.A., and Erjomenko, G.K., The structure of high lonsdaleite diamond grains from the impactites of the Belilovka (Zapadnaya) astrobleme (Ukraine), 34th Lunar and Planetary Science Conf. (LPSC), League City, Texas, US, March, 17–21, 2003, no. 1561.

  7. Kvasnytsya, V.M., Wirth, R., and Tsymbal, S.M., Nano-micromorphology and anatomy impact apographitic diamonds from Bilylivka (Zapadnaya) astrobleme (the Ukrainian Shield), Mineral J. (Ukraine), 2015, vol. 37, no. 4, pp. 36–45.

    Article  Google Scholar 

  8. Kvasnytsya, V. and Wirth, R., Micromorphology and internal structure of apographitic impact diamonds: SEM and TEM study, Diam. Relat. Mater., 2013, vol. 32, pp. 7–16.

    Article  CAS  Google Scholar 

  9. Mel’nikova, V.A., Kolesnichenko, G.A., and Naidich, Yu.V., Spherulitic character of crystallization of diamond films deposited from the vapor phase, Dop. NAS of Ukraine, 1996, vol. 9, pp. 99–104.

    Google Scholar 

  10. Wells, A.F., Crystal habit and internal structure, Phylsoph. Magazine, 1946, vol. 37, no. 266, pp. 184–199.

    CAS  Google Scholar 

  11. Wolff, G.A., Faces and habits of diamond type crystals, Am. Mineral, 1956, vol. 41 (60), pp. 60–66.

    CAS  Google Scholar 

  12. Hartman, P., The non-uniform distribution of faces in a zone, Zeit. Kristalographie, 1965, vol. 121, pp. 78–80.

    Article  CAS  Google Scholar 

  13. Sunagawa, I., Morphology of natural and synthetic diamond crystals, Mater. Sci. Earth’s, Tokyo: Inter. TERRA Pub., 1984, pp. 303–330.

    Google Scholar 

  14. Sunagawa, I., Morphology of diamonds, Morphology and phase equilibrium of minerals (Materials of IMA, 1982), Sophia, 1986, pp. 195–207.

    Google Scholar 

  15. Sunagawa, I., Crystals: growth, morphology, and perfection, Cambridge, New York, Melbourne: Cambridge University Press, 2005.

    Book  Google Scholar 

  16. Hemley, R. J., Chen Yu-Ch, Yan Ch.–Sh., Growing diamond crystals by chemical vapor deposition, Elements, 2005, vol. 1, no. 2, pp. 105–108.

    Article  CAS  Google Scholar 

  17. Shermer, J.J., van Enckevort, W. J. P., Giling, L.J., Flame deposition and characterization of large type IIA diamond single crystals, Diam. Relat. Mater., 1994, vol. 3, pp. 408–416.

    Article  Google Scholar 

  18. Nanomineralogy: ultra-and microdisperse state of a mineral substance, Yushkin, N.P., Ashabov, A.M., Rakin, V.I., Eds., SPb: Nauka, 2005.

    Google Scholar 

  19. Ivanov, V.K., Fedorov, P.P., Baranchikov, A.E., Osiko, V.V., Oriented attachment of particles: 100 years of investigations of non-classical crystal growth, Rus. Chem. Rev., 2014, vol. 83, no. 12, pp. 1204–1222.

    Article  CAS  Google Scholar 

  20. Kvasnytsya, V., Wirth, R., Piazolo, S., Jacob, D. E., Trimby, P., Surface morphology and structural types of natural impact apographitic diamonds, J. Superhard Mater., 2016, vol. 38, no. 2, pp. 71–84.

    Article  Google Scholar 

  21. Val’ter, A.A., Erjomenko, G.K., Kvasnitsa, V.N., Polkanov, Yu.A., Shock metamorphogenetic carbon minerals, Kiev: Naukova Dumka, 1992.

    Google Scholar 

  22. Carlisle, D.V., Braman, D.R., Diamonds at the K/T boundary, Nature, 1991, vol. 352, p. 709.

    Article  Google Scholar 

  23. Gilmour, L., Russel, S.S., Arden J. W, Lee, M.R., Franchi, I.A., Pillinger G. T., Terrestrial carbon and nitrogen isotopic ratios from Cretaceous-Tertiary boundary Nanodiamonds, Science, 1992, vol. 258, pp. 1624–1626.

    Article  CAS  Google Scholar 

  24. Hough, R.M., Gilmour, I., Pillinger, S.T., Arden, J.W., Gilkes, K.W. R., Yuan, J., Milledge, H.J., Diamond and silicon carbide in impact melt rock from the Ries impact crater, Nature, 1995, vol. 378 (2), pp. 41–44.

    Article  CAS  Google Scholar 

  25. Hough, R.M., Gilmour, L., Pillinger, C.T., Diamonds from the iridium-rich K-T boundary layer at Arroyo el Mimbral, Tamaulipas, Mexico, Geology, 1997, vol. 25 (10), pp. 1019–1022.

    Article  CAS  Google Scholar 

  26. Hough, R.M., Gilmour, L., Pillinger, C.T., Carbon isotope study of impact diamonds in Chicxulub ejecta at Cretaceous-Tertiary boundary sites in Mexico and the Western Interior of the United States, Large Meteorite Impacts and Planetary Evolution II, Dressler, B.O., Sharpton, V.L., Eds., Geological Society of America, 1999. Special paper, 339, pp. 215–222.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. M. Kvasnytsya.

Additional information

Original Ukrainian Text © V.M. Kvasnytsya, 2018, published in Sverkhtverdye Materialy, 2018, Vol. 40, No. 4, pp. 3–10.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kvasnytsya, V.M. Unusual Nano-Microcrystals of Natural Diamond. J. Superhard Mater. 40, 229–235 (2018). https://doi.org/10.3103/S1063457618040019

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1063457618040019

Keywords

Navigation