Bulletin of the Russian Academy of Sciences: Physics

, Volume 79, Issue 9, pp 1180–1185 | Cite as

Pd hydride and carbide studied by means of Pd K-edge X-ray absorption near-edge structure analysis

  • A. L. Bugaev
  • A. A. Guda
  • K. A. Lomachenko
  • L. A. Bugaev
  • A. V. Soldatov
Proceedings of XX Conference “SR-2014”


A Pd K-edge X-ray absorption near edge structure (XANES) analysis for palladium hydride and carbide nanoparticles is presented. It is shown that the presence of H and C atoms changes the Pd unoccupied p-electronic states, affecting the near-edge fine structure. Quantitative XANES analysis is performed using a multidimensional interpolation approach. Theoretical models of PdH and PdC clusters are developed using Monte Carlo methods. The proposed technique allow us to determine hydrogen concentrations in palladium nanoparticles and correctly reproduce all experimental features of XANES spectra for palladium hydride and carbide nanoparticles.


Palladium Hydride Palladium Nanoparticles Hydride Phase Palladium Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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Copyright information

© Allerton Press, Inc. 2015

Authors and Affiliations

  • A. L. Bugaev
    • 1
  • A. A. Guda
    • 1
  • K. A. Lomachenko
    • 1
  • L. A. Bugaev
    • 1
  • A. V. Soldatov
    • 1
  1. 1.Faculty of PhysicsSouthern Federal UniversityRostov-on-DonRussia

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