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Solution-combustion synthesis of oxide nanoparticles from nitrate solutions containing glycine and urea: Thermodynamic aspects

  • Sh. M. Khaliullin
  • V. D. Zhuravlev
  • V. G. Bamburov
Article

Abstract

Solution-combustion synthesis (SCS) of nanoparticles was characterized by the temperature effect (ΔT ad) calculated upon neglect by the temperature dependence of heat capacity. Thus calculated ΔT ad values were found to be a linear function of the inverse radius of metal ions. Our calculations have shown that SCS reactions may yield not only oxides but also hydroxides and carbonates. Suggested was a simple formula for evaluating the ΔT ad values attained in SCS of complex oxides.

Keywords

solution-combustion synthesis (SCS) metal oxides temperature effect adiabatic reaction ionic radius glycine urea 

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Copyright information

© Allerton Press, Inc. 2016

Authors and Affiliations

  • Sh. M. Khaliullin
    • 1
  • V. D. Zhuravlev
    • 1
  • V. G. Bamburov
    • 1
  1. 1.Institute of Solid State Chemistry, Ural BranchRussian Academy of SciencesYekaterinburgRussia

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