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Moscow University Chemistry Bulletin

, Volume 74, Issue 3, pp 138–142 | Cite as

Synthesis and Crystal Structure of Nikel(II) and Zinc(II) Complexes with Benzoylacetic Aldehyde Derivatives

  • M. A. TursunovEmail author
  • B. B. Umarov
  • K. G. Avezov
Article
  • 3 Downloads

Abstract

Ni(II) and Zn(II) complexes of composition MLn ⋅ NH3 (n = 1–3) are synthesized based on condensation products of benzoylacetic aldehyde with aromatic acid hydrazides (H2L1–H2L3). The resulting complexes are studied by elemental analysis, as well as IR and NMR spectroscopy. The structure of complex NiL2 ⋅ Py is determined by the method of the XRD analysis (CIF file CCDC no. 1508698).

Keywords:

ketoaldehide acylhydrazine aroylhydrazone five- and six-membered pseudo-aromatic system of metallacycles X-ray diffraction analysis 

Notes

REFERENCES

  1. 1.
    Pakal’nis, V.A., Zerova, I.V., Yakimovich, S.I., and Alekseyev, V.V., Chem. Heterocycl. Compd., 2013, no. 3, p. 408.Google Scholar
  2. 2.
    Yakimovich, S.I. and Zerova, I.V., Zh. Org. Khim., 1991, vol. 27, no. 5, p. 959.Google Scholar
  3. 3.
    Umarov, B.B., Toshev, M.T., Saidov, S.O., et al., Koord. Khim., 1992, vol. 18, no. 9, p. 980.Google Scholar
  4. 4.
    Umarov, B.B., Extended Abstracts of Doctoral Dissertation, Tashkent: Inst. Fertilizers, Acad. Sci. Uzbekistan, 1996.Google Scholar
  5. 5.
    Parpiev, N.A., Umarov, B.B., and Avezov, K.G., Proizvodnye perftoralkil’nykh β-diketonov i ikh kompleksov (Derivatives of Perfluoroalkyl β-Diketones and Their Complexes), Tashkent: Dizayn-Press, 2013.Google Scholar
  6. 6.
    Zelenin, K.N. and Yakimovich, S.I., Targets Heterocycl. Syst., 1998, vol. 2, p. 207.Google Scholar
  7. 7.
    Toshev, M.T., Dustov, Kh.B., Saidov, S.O., et al., Koord. Khim., 1992, vol. 18, no. 12, p. 1184.Google Scholar
  8. 8.
    Toshev, M.T., Yusupov, V.G., Dustov, Kh.B., and Parpiev, N.A., Kristallokhimiya kompleksov metallov s gidrazidami i gidrazonami (Crystal Chemistry of Metal Complexes with Hydrazides and Hydrazones), Tashkent: Fan, 1994.Google Scholar
  9. 9.
    Umarov, B.B., Avezov, K.G., Abdurakhmonov, S.F., et al., Abstracts of Papers, III Mezhdunar. konf. po molekulyarnoi spektroskopii (III Int. Conf. on Molecular Spectroscopy), Samarkand: Samarkand. Gos. Univ., 2006, p. 29.Google Scholar
  10. 10.
    Parpiev, N.A., Yusupov, S.I., Yakimovich, S.I., and Sharipov, Kh.T., Atsilgidrazony i ikh kompleksy s perekhodnymi metallami (Acyl Hydrazones and Their Complexes with Transition Metals), Tashkent: Fan, 1988.Google Scholar
  11. 11.
    Umarov, B.B., Avezov, K.G., Tursunov, M.A., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 7, p. 473.CrossRefGoogle Scholar
  12. 12.
    Agrawal, A., Sharma, K.M., and Prasad, R.N., Pol. J. Chem., 2007, vol. 81, no. 12, p. 2081.Google Scholar
  13. 13.
    Avezov, K.G., Extended Abstracts of Doctoral Dissertation, Tashkent: Inst. Chem., Acad. Sci. Uzbekistan, 2018.Google Scholar
  14. 14.
    Tursunov, M.A., Avezov, K.G., Umarov, B.B., and Parpiev, N.A., Russ. J. Coord. Chem., 2017, vol. 43, no. 2, p. 93.CrossRefGoogle Scholar
  15. 15.
    Gaibullaev, Kh.S., Pumpor, K.B., Yakimovich, S., et al., Abstracts of Papers, III Natsl. konf. po primeneniyu rentgenovskogo, sinkhrotronnogo izluchenii neitronov i elektronov RSNE-2001 (III Natl. Conf. on the Use of X-Ray, Synchrotron Radiation of Neutrons and Electrons RSNE-2001), Moscow, 2001, p. 58.Google Scholar
  16. 16.
    Kogan, V.A., Zelentsov, V.V., Larin, G.M., and Lukov, V.V., Kompleksy perekhodnykh metallov s gidrazonami. Fiziko-khimicheskie svoistva i stroenie (Complexes of Transition Metals with Hydrazones: Physicochemical Properties and Structure), Moscow: Nauka, 1990.Google Scholar
  17. 17.
    Umarov, B.B., Tursunov, M.A., and Avezov, K.G., Nauchn. Vestn. Bukharsk. Gos. Univ., 2014, no. 1, p. 11.Google Scholar
  18. 18.
    Umarov, B.B., Tursunov, M.A., and Minin, V.V., Kompleksy s proizvodnymi ketoal’degidov i ketoefirov (Complexes with Derivatives of Ketoaldehydes and Ketoesters), Tashkent: Nishon Noshir, 2016.Google Scholar
  19. 19.
    Revenko, M.D., Simonov, Yu.A., Duka, G.G., Bourosh, P.N., et al., Russ. J. Inorg. Chem., 2009, vol. 54, no. 5, p. 698.CrossRefGoogle Scholar
  20. 20.
    Avezov, K.G., Yakimovich, S.I., Umarov, B.B., et al., Russ. J. Coord. Chem., 2011, vol. 37, no. 4, p. 275.CrossRefGoogle Scholar

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© Allerton Press, Inc. 2019

Authors and Affiliations

  1. 1.Bukhara State UniversityBukharaUzbekistan

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